LEADER 05197nam 2200697Ia 450 001 9910810642403321 005 20200520144314.0 010 $a1-280-27461-1 010 $a9786610274611 010 $a0-470-01206-4 010 $a0-470-01205-6 035 $a(CKB)1000000000356130 035 $a(EBL)228319 035 $a(OCoLC)559997279 035 $a(SSID)ssj0000097227 035 $a(PQKBManifestationID)11121524 035 $a(PQKBTitleCode)TC0000097227 035 $a(PQKBWorkID)10112103 035 $a(PQKB)11677890 035 $a(MiAaPQ)EBC228319 035 $a(Au-PeEL)EBL228319 035 $a(CaPaEBR)ebr10113947 035 $a(CaONFJC)MIL27461 035 $a(OCoLC)85820608 035 $a(OCoLC)55887464 035 $a(FINmELB)ELB177696 035 $a(EXLCZ)991000000000356130 100 $a20040701d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aAdditives in polymers $eindustrial analysis and applications /$fJan C.J. Bart 205 $a1st ed. 210 $aChichester $cJohn Wiley & Sons$dc2005 215 $a1 online resource (837 p.) 300 $aDescription based upon print version of record. 311 $a0-470-85062-0 320 $aIncludes bibliographical references and index. 327 $aADDITIVES IN POLYMERS Industrial Analysis and Applications; Contents; FOREWORD; PREFACE; ABOUT THE AUTHOR; ACKNOWLEDGEMENTS; CHAPTER 1 Introduction; 1.1 Additives; 1.1.1 Additive functionality; 1.2 Plastics formulations; 1.2.1 Supply forms; 1.2.2 Additive delivery; 1.3 Economic impact of polymer additives; 1.4 Analysis of plastics; 1.4.1 Regulations and standardisation; 1.4.2 Prior art; 1.4.3 Databases; 1.4.4 Scope; 1.4.5 Chapter overview; 1.5 Bibliography; 1.5.1 Plastics additives; 1.5.2 Processing technologies; 1.5.3 Instrumental analysis; 1.5.4 Polymer analysis 327 $a1.5.5 Polymer/additive analysis1.6 References; CHAPTER 2 Deformulation Principles; 2.1 Polymer identification; 2.2 Additive analysis of rubbers: 'Best Practice'; 2.3 Polymer extract analysis; 2.4 In situ polymer/additive analysis; 2.5 Class-specific polymer/additive analysis; 2.6 Bibliography; 2.6.1 Polymer identification; 2.6.2 Deformulation of rubbers; 2.6.3 Deformulation of polymers; 2.7 References; CHAPTER 3 Sample Preparation Perspectives; 3.1 Solvents; 3.1.1 Polymer solubility criteria; 3.1.2 Solubility parameters; 3.1.3 Polymer solutions; 3.2 Extraction strategy 327 $a3.3 Conventional extraction technologies3.3.1 Liquid-liquid extraction; 3.3.2 Liquid-solid extraction; 3.3.3 Classical solvent extractions of additives from polymers; 3.3.4 Sonication; 3.4 High-pressure solvent extraction methods; 3.4.1 Supercritical fluid technology; 3.4.2 Analytical SFE; 3.4.3 Subcritical water extraction; 3.4.4 Microwave technology; 3.4.5 Microwave-assisted extractions; 3.4.6 Pressurised fluid extraction; 3.5 Sorbent extraction; 3.5.1 Solid-phase extraction; 3.5.2 Solid-phase microextraction; 3.5.3 Stir bar sorptive extraction 327 $a3.6 Methodological comparison of extraction methods3.6.1 Experimental comparisons; 3.6.2 Extraction selectivity; 3.6.3 'Nonextractable' additive analysis; 3.7 Polymer/additive dissolution methods; 3.8 Hydrolysis; 3.9 Bibliography; 3.9.1 Sampling and sample preparation; 3.9.2 Solvents/solubility; 3.9.3 Extraction methods; 3.10 References; CHAPTER 4 Separation Techniques; 4.1 Analytical detectors; 4.2 Gas chromatography; 4.2.1 High-temperature gas chromatography; 4.2.2 Headspace gas chromatography; 4.3 Supercritical fluid chromatography; 4.4 Liquid chromatography techniques 327 $a4.4.1 Planar chromatographies4.4.2 Column chromatographies; 4.5 Capillary electrophoretic techniques; 4.6 Bibliography; 4.6.1 General texts; 4.6.2 Detectors; 4.6.3 Gas chromatography; 4.6.4 Supercritical fluid chromatography; 4.6.5 Thin-layer chromatography; 4.6.6 Liquid chromatography; 4.6.7 Size-exclusion chromatography; 4.6.8 Ion chromatography; 4.6.9 Capillary electrophoretic techniques; 4.7 References; CHAPTER 5 Polymer/Additive Analysis: The Spectroscopic Alternative; 5.1 Ultraviolet/visible spectrophotometry; 5.2 Infrared spectroscopy; 5.3 Luminescence spectroscopy 327 $a5.4 High-resolution nuclear magnetic resonance spectroscopy 330 $aThis industrially relevant resource covers all established and emerging analytical methods for the deformulation of polymeric materials, with emphasis on the non-polymeric components.Each technique is evaluated on its technical and industrial merits.Emphasis is on understanding (principles and characteristics) and industrial applicability.Extensively illustrated throughout with over 200 figures, 400 tables, and 3,000 references. 606 $aPolymers$xAdditives 606 $aPolymers$xAnalysis 615 0$aPolymers$xAdditives. 615 0$aPolymers$xAnalysis. 676 $a668.9 686 $aUV 2100$2rvk 700 $aBart$b Jan C. J$01662991 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910810642403321 996 $aAdditives in polymers$94062788 997 $aUNINA