LEADER 05057nam 2200721 450 001 9910809662703321 005 20230116163845.0 010 $a1-118-78824-9 010 $a1-118-78830-3 010 $a1-118-78844-3 035 $a(CKB)2550000001256705 035 $a(EBL)1662194 035 $a(SSID)ssj0001180140 035 $a(PQKBManifestationID)11634792 035 $a(PQKBTitleCode)TC0001180140 035 $a(PQKBWorkID)11186454 035 $a(PQKB)10274239 035 $a(DLC) 2013046295 035 $a(Au-PeEL)EBL1662194 035 $a(CaPaEBR)ebr10856817 035 $a(CaONFJC)MIL588428 035 $a(Au-PeEL)EBL7147552 035 $a(PPN)190552727 035 $a(OCoLC)863383849 035 $a(MiAaPQ)EBC1662194 035 $a(EXLCZ)992550000001256705 100 $a20140414h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 14$aThe organometallic chemistry of the transition metals /$fRobert H. Crabtree 205 $a6th edition. 210 1$aHoboken, New Jersey :$cWiley,$d2014. 210 4$dŠ2014 215 $a1 online resource (522 p.) 300 $aDescription based upon print version of record. 311 $a1-118-13807-4 311 $a1-306-57177-4 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aCover; Title page; Copyright page; Contents; Preface; List of Abbreviations; 1: Introduction; 1.1 Why Study Organometallic Chemistry?; 1.2 Coordination Chemistry; 1.3 Werner Complexes; Stereochemistry; Chelate Effect; Werner's Coordination Theory; 1.4 The Trans Effect; 1.5 Soft versus Hard Ligands; 1.6 The Crystal Field; High Spin versus Low Spin; Inert versus Labile Coordination; Jahn-Teller Distortion; Low- versus High-Field Ligands; Magnetism and Nuclearity; Other Geometries; Isoconfigurational Ions; 1.7 The Ligand Field; 1.8 The sdn Model and Hypervalency; 1.9 Back Bonding 327 $aFrontier Orbitals?-Donor Ligands; 1.10 Electroneutrality; Oxidation State Trends; Periodic Trends; 1.11 Types of Ligand; Ambidentate Ligands; Actor and Spectator Ligands; Multifunctional Ligands29; Organometallic versus Coordination Compounds; References; Problems; 2: Making Sense of Organometallic Complexes; 2.1 The 18-Electron Rule; Covalent Electron Counting Model; Ionic Electron Counting Model; Electron Counts for Common Ligands and Hapticity; Bridging Ligands; Zero-Electron Ligands; 2.2 Limitations of The 18-Electron Rule; Steric Stabilization of Reactive Species 327 $aKinetic Stability from Bulky SubstituentsPreparation of Metal Alkyls; Cyclometalation; Oxidative Addition; Insertion; Bridging Alkyls; Metalacycles; ?1 and ?2-Acyl and Vinyls; 3.2 Other ?-Bonded Ligands; Group 14 Elements; Groups 15-17; Oxophilicity and Functional Group Tolerance; 3.3 Metal Hydrides; Characterization; Synthesis; Reactions; Hydricity; Bridging Hydrides; 3.4 Sigma Complexes; Dihydrogen Complexes20; Characterization; Reactions; Agostic Species; 3.5 Bond Strengths; Supramolecular Interactions; References; Problems; 4: Carbonyls, Phosphines, and Substitution; 4.1 Metal Carbonyls 327 $aPreparation of CarbonylsReactions of Carbonyls; Bridging Carbonyls; Isonitriles; Thiocarbonyls; Nitrosyls; Cyanide; Other CO Analogs; 4.2 Phosphines; Structure and Bonding; Tolman Electronic Parameter and Cone Angle; Bite Angle; 4.3 N-Heterocyclic Carbenes (NHCs); 4.4 Dissociative Substitution; Kinetics; Stereochemistry and Trans Effect; Electronic and Steric Factors; 4.5 Associative Substitution; Kinetics; Trans Effect; Solvent Participation; Ligand Rearrangements; 4.6 Redox Effects and Interchange Substitution; 17e and 19e Species; The Interchange Mechanism; 4.7 Photochemical Substitution 327 $aCarbonyls 330 $aFully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features: New sections on Multifunctional Ligands, Oxidation Catalysis, and Green ChemistryExp 606 $aOrganometallic chemistry 606 $aOrganotransition metal compounds 606 $aCompostos organometālˇlics de transiciķ$2thub 608 $aLlibres electrōnics$2thub 615 0$aOrganometallic chemistry. 615 0$aOrganotransition metal compounds. 615 7$aCompostos organometālˇlics de transiciķ 676 $a547/.056 700 $aCrabtree$b Robert H.$f1948-$066039 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910809662703321 996 $aOrganometallic chemistry of the transition metals$978832 997 $aUNINA