LEADER 04610nam 2200457 450 001 9910809143003321 005 20230919202848.0 010 $a981-5040-64-2 035 $a(MiAaPQ)EBC29972816 035 $a(Au-PeEL)EBL29972816 035 $a(CKB)24819557600041 035 $a(NjHacI)9924819557600041 035 $a(EXLCZ)9924819557600041 100 $a20230919d2022 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 14$aThe synthetic methods, structures, and properties of the Ca-C ? bond organocalcium containing compounds /$fNejib Ben Hussein and Noureddine Raouafi 205 $a1st ed. 210 1$aSingapore :$cBentham Science Publishers Pte. Ltd.,$d[2022] 210 4$dİ2022 215 $a1 online resource (102 pages) 311 08$aPrint version: Hussein, Nejib Ben The Synthetic Methods Structures, and Properties of the Ca-C σ Bond Organocalcium Containing Compounds Carol Stream : Bentham Science Publishers,c2022 9789815040654 320 $aIncludes bibliographical references. 327 $aCover -- Title -- Copyright -- End User License Agreement -- Contents -- Preface -- CONSENT FOR PUBLICATION -- CONFLICT OF INTEREST -- ACKNOWLEDGEMENTS -- Acknowledgements -- General Introduction -- GENERAL INTRODUCTION -- CONCLUSION -- Calcium Element -- 1. CALCIUM ELEMENT -- 1.1. Introduction -- 1.2. Calcium Physical Properties -- 1.3. Calcium Chemical Properties -- 1.4. Calcium-Carbon Bonding in Organic Compounds -- 2. SHORT HISTORICAL VIEW ON CA-C?-BOND ORGANOCALCIUM CONTAINING COMPOUNDS -- 3. CHALLENGES FOR THE SYNTHESIS OF ORGANOCALCIUM CA-C CONTAINING COMPOUNDS -- CONCLUSION -- REFERENCES -- Organocalcium (Ca-C) ?-bond Containing Compounds -- 1. CA-C?-BOND ALKYLCALCIUM COMPOUNDS -- 1.1. Introduction -- 1.2. Silyl Substituted Methylcalcium Derivatives -- 1.3. Calcium Transmetalation of Dialkylzinc -- 1.4. Cycloalkylcalcium Derivatives -- 2. BENZYLCALCIUM COMPOUNDS -- 2.1. Introduction -- 2.2. Benzyl Ca-C Bond Formation -- 3. ALKENYL CALCIUM COMPOUNDS -- 4. ALKYNYL CALCIUM COMPOUNDS -- 5. REACTION OF DIENE AND DIYNECOMPOUNDS WITH CALCIUM -- 5.1. Reaction of Diene Compounds with Calcium -- 5.2. Reaction of Diynecompounds with Calcium -- 6. CA-C ARYL COMPOUNDS -- 6.1. PhenylCalcium Compounds -- 6.2. Biphenyl Naphthalene Anthracene Halo-Derivatives -- 6.3. Anthracene Reduction -- 7. HETEROAROMATIC CALCIUM COMPOUNDS -- 7.1. Halo-Thiophene Derivatives -- 7.2. Picoline Derivatives -- 7.2.1. Reaction of bis(allyl)calcium with 2-Picoline -- 7.2.2. Reaction of bis(allyl)calcium with 4-picoline -- 7.2.3. Reaction of bis(allyl)calcium with 4-t-Bu-pyridine -- 7.2.4. Reaction of bis(allyl)calcium with 2,6-Lutidine -- CONCLUSION -- REFERENCES -- Coordination, Degrading Agent, Catalyst Property and Spectroscopy of Organocalcium Compounds -- 1. CARBON-CARBON ?-BOND CALCIUM COORDINATION -- 2. ORGANOCALCIUM COMPOUNDS AND SOLVENT DEGRADATION. 327 $a2.1. Ether Degradation -- 2.2. Durability in Ethereal Solutions -- 3. ORGANOCALCIUM CA-C ?-BOND CONTAINING CATALYSTS -- 4. NMR SPECTROSCOPY OF ORGANOCALCIUM COMPOUNDS -- 4.1. 43Ca NMR Spectroscopy -- 4.2. 13C NMR Spectroscopy -- 4.3. 1H NMR Spectroscopy -- CONCLUSION -- REFERENCES -- Conclusion -- Subject Index -- Back Cover. 330 $aThis reference describes the chemistry of organocalcium compounds that contain a Ca-C ?-bond. It collects the information about this niche group of organometallic compounds into 4 easy-to-read chapters. It is intended for scholars in the field of organic chemistry, and researchers in industrial chemistry and chemical engineering departments. Key features: - Presents a comparison to homologous compounds of other alkaline earth metals. - Explains the main problems encountered in the synthesis of organocalcium compounds with reference to the reactivity of calcium, the low solubility in common solvents and the high reactivity of the formed intermediates and products - Highlights many concepts about the Ca-C bond such as the steric hindrance, degrading agent properties, organocalcium spectroscopy, and more. 606 $aOrganic compounds 615 0$aOrganic compounds. 676 $a547.2 700 $aHussein$b Nejib Ben$01670177 702 $aRaouafi$b Noureddine 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910809143003321 996 $aThe synthetic methods, structures, and properties of the Ca-C ? bond organocalcium containing compounds$94031867 997 $aUNINA