LEADER 04604nam 2200613 a 450 001 9910808862703321 005 20200520144314.0 010 $a1-118-01645-9 010 $a1-118-01646-7 010 $a1-283-17562-2 010 $a9786613175625 010 $a1-118-01644-0 035 $a(CKB)2550000000040725 035 $a(EBL)697669 035 $a(OCoLC)739116853 035 $a(SSID)ssj0000523315 035 $a(PQKBManifestationID)11322369 035 $a(PQKBTitleCode)TC0000523315 035 $a(PQKBWorkID)10542690 035 $a(PQKB)10151634 035 $a(MiAaPQ)EBC697669 035 $a(EXLCZ)992550000000040725 100 $a20101019d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aHypercarbon chemistry /$fGeorge A. Olah ... [et al.] 205 $a2nd ed. 210 $aHoboken, N.J. $cJ. WIley & Sons$dc2011 215 $a1 online resource (476 p.) 300 $aDescription based upon print version of record 311 $a0-470-93568-5 320 $aIncludes bibliographical references and index. 327 $aHYPERCARBON CHEMISTRY, Second Edition; CONTENTS; FOREWORD TO THE FIRST EDITION; PREFACE TO THE SECOND EDITION; PREFACE TO THE FIRST EDITION; 1: INTRODUCTION: GENERAL ASPECTS; 1.1. AIMS AND OBJECTIVES; 1.2. SOME DEFINITIONS; 1.3. STRUCTURES OF SOME TYPICAL HYPERCARBON SYSTEMS; 1.4. THE THREE-CENTER BOND CONCEPT: TYPES OF THREE-CENTER BONDS; 1.5. THE BONDING IN MORE HIGHLY DELOCALIZED SYSTEMS; 1.6. REACTIONS INVOLVING HYPERCARBON INTERMEDIATES; REFERENCES; 2: CARBON-BRIDGED (ASSOCIATED) METAL ALKYLS; 2.1. INTRODUCTION; 2.2. BRIDGED ORGANOALUMINUM COMPOUNDS 327 $a2.3. BERYLLIUM AND MAGNESIUM COMPOUNDS2.4. ORGANOLITHIUM COMPOUNDS; 2.5. ORGANOCOPPER, SILVER, AND GOLD COMPOUNDS; 2.6. SCANDIUM, YTTRIUM, AND LANTHANIDE COMPOUNDS; 2.7. TITANIUM, ZIRCONIUM, AND HAFNIUM COMPOUNDS; 2.8. MANGANESE COMPOUNDS; 2.9. OTHER METAL COMPOUNDS WITH BRIDGING ALKYL GROUPS; 2.10. AGOSTIC SYSTEMS CONTAINING CARBON-HYDROGEN-METAL 3c-2e BONDS; 2.11. CONCLUSIONS; REFERENCES; 3: CARBORANES AND METALLACARBORANES; 3.1. INTRODUCTION; 3.2. CARBORANE STRUCTURES AND SKELETAL ELECTRON NUMBERS; 3.2.1. Closo Carboranes; 3.2.2. Nido and Arachno Carboranes 327 $a3.2.3. Carbon Sites in Carboranes Skeletal Connectivities k; 3.2.4. Skeletal Bond Orders in Boranes and Carboranes; 3.3. LOCALIZED BOND SCHEMES FOR CLOSO BORANES AND CARBORANES; 3.3.1. Lipscomb's Styx Rules and Williams' Stx Rules; 3.3.2. Bond Orders and Skeletal Connectivities; 3.3.3. Bond Networks and Skeletal Connectivities; 3.3.4. Calculated Charge Distributions and Edge Bond Orders; 3.4. MO TREATMENTS OF CLOSO BORANES AND CARBORANES; 3.5. THE BONDING IN NIDO AND ARACHNO CARBORANES; 3.5.1. Localized Bond Schemes; 3.5.2. MO Treatments of Nido and Arachno Boranes and Carboranes 327 $a4: MIXED METAL-CARBON CLUSTERS AND METAL CARBIDES4.1. INTRODUCTION; 4.2. COMPLEXES OF CnHn RING SYSTEMS WITH A METAL ATOM: NIDO-SHAPED MCn CLUSTERS; 4.3. METAL COMPLEXES OF ACYCLIC UNSATURATED LIGANDS, CnHn+2; 4.4. COMPLEXES OF UNSATURATED ORGANIC LIGANDS WITH TWO OR MORE METAL ATOMS: MIXED METAL-CARBON CLUSTERS; 4.5. METAL CLUSTERS INCORPORATING CORE HYPERCARBON ATOMS; 4.6. BULK METAL CARBIDES; 4.7. METALLATED CARBOCATIONS; 4.8. CONCLUSIONS; REFERENCES; 5: HYPERCOORDINATE CARBOCATIONS AND THEIR BORANE ANALOGS; 5.1. GENERAL CONCEPT OF CARBOCATIONS: CARBENIUM VERSUS CARBONIUM IONS 327 $a5.1.1. Trivalent-Tricoordinate (Classical) Carbenium Ions 330 $aThe essential new edition of the book that put hypercarbon chemistry on the map A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultane 606 $aCarbonium ions 606 $aOrganometallic chemistry 615 0$aCarbonium ions. 615 0$aOrganometallic chemistry. 676 $a547.01 700 $aOlah$b George A$g(George Andrew),$f1927-$016147 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910808862703321 996 $aHypercarbon chemistry$94078506 997 $aUNINA