LEADER 05216nam 2200673 450 001 9910808307103321 005 20230807204613.0 010 $a3-527-67333-4 010 $a3-527-67331-8 010 $a3-527-67334-2 035 $a(CKB)2670000000583727 035 $a(EBL)1883961 035 $a(SSID)ssj0001435965 035 $a(PQKBManifestationID)11864021 035 $a(PQKBTitleCode)TC0001435965 035 $a(PQKBWorkID)11436163 035 $a(PQKB)11160344 035 $a(MiAaPQ)EBC1883961 035 $a(Au-PeEL)EBL1883961 035 $a(CaPaEBR)ebr10993870 035 $a(CaONFJC)MIL674987 035 $a(OCoLC)898103480 035 $a(EXLCZ)992670000000583727 100 $a20141219h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSemiconductor photocatalysis $eprinciples and applications /$fHorst Kisch 210 1$aWeinheim, Germany :$cWiley-VCH,$d2015. 210 4$dİ2015 215 $a1 online resource (266 p.) 300 $aDescription based upon print version of record. 311 $a3-527-33553-6 311 $a1-322-43705-X 320 $aIncludes bibliographical references and index. 327 $aSemiconductor Photocatalysis; Contents; Preface; Acknowledgments; Chapter 1 Introduction; 1.1 A Brief History of Photochemistry; 1.2 Catalysis, Photochemistry, and Photocatalysis; Chapter 2 Molecular Photochemistry; 2.1 Absorption and Emission; 2.2 Intensity of Electronic Transitions; 2.2.1 Contribution of Nuclei; 2.2.2 Contribution of Spin; 2.2.3 Contribution of Orbitals; 2.3 Excited States Radiative Lifetimes; 2.4 Energy and Electron Transfer; 2.4.1 Energy Transfer; 2.4.2 Electron Transfer; 2.5 Proton Transfer and Hydrogen Abstraction; 2.6 Photosensitization; 2.7 Rates and Quantum Yields 327 $a2.8 Quenching of Excited States2.8.1 Identification of the Reactive Excited State; 2.9 Absorption, Emission, and Excitation Spectra; 2.10 Classification and Reactivity of Excited States; 2.10.1 Organic Molecules; 2.10.1.1 ?,?* States; 2.10.1.2 n,?* States; 2.10.1.3 Charge-Transfer (CT) States; 2.10.1.4 Triplet and Singlet Oxygen Reactions; 2.10.2 Inorganic and Organometallic Complexes; 2.10.2.1 Metal-Centered (MC) states; 2.10.2.2 Ligand-Centered (LC) States; 2.10.2.3 Charge Transfer Metal to Ligand (CTML) States; 2.10.2.4 Charge Transfer Ligand to Metal (CTLM) States 327 $a2.10.2.5 Charge Transfer to Solvent (CTTS) States2.10.2.6 Intervalence Transfer (IT) States; Chapter 3 Molecular Photocatalysis; 3.1 Hydrogenation of 1,3-Dienes; 3.2 Co-Cyclization of Alkynes with Nitriles; 3.3 Enantioselective Trifluoromethylation of Aldehydes; 3.4 Photoinduced Electron Transfer Catalysis; 3.5 Reduction and Oxidation of Water; Chapter 4 Photoelectrochemistry; 4.1 Electronic Structure and Nature of Excited States; 4.1.1 The (Optical) Bandgap; 4.1.1.1 Measurement of the Bandgap Energy; 4.1.1.2 Influence of Crystal Size; 4.1.2 The Photonic Bandgap; 4.1.3 Emission Spectra 327 $a4.2 Photocorrosion4.3 Interfacial Electron Transfer; 4.3.1 Introduction; 4.3.2 Thermal Interfacial Electron Transfer (IFET); 4.3.2.1 IFET at the Metal/Liquid Interface; 4.3.2.2 IFET at the Semiconductor/Liquid Interface; 4.3.3 Photochemical Interfacial Electron Transfer; 4.3.3.1 IFET in Large Semiconductor Crystals; 4.3.3.2 IFET in Small Semiconductor Crystals; Chapter 5 Semiconductor Photocatalysis; 5.1 Mechanisms, Kinetics, and Adsorption; 5.1.1 General Classification of Reactions; 5.1.2 Rates, Quantum Yields, and Their Comparability; 5.1.2.1 Direct Semiconductor Photocatalysis 327 $a5.1.2.1.1 Factors Determining the Quantum Yield5.1.2.1.2 Kinetic Aspects; 5.1.2.1.3 Quantum Yield; 5.1.2.1.3 Role of Adsorption; 5.1.2.1.3 Indirect Semiconductor Photocatalysis; 5.1.3 Influence of Semiconductor Nature and Particle Size on Chemical Selectivity; 5.1.3.1 Control of Chemoselectivity by Surface States and Redox Amplification; 5.2 Characterization of Photocatalysts; 5.2.1 General Methods; 5.2.2 Flatband and Quasi-Fermi Potentials; 5.2.2.1 Measurements in Absence of Light; 5.3 Preparation and Properties of Photocatalysts; 5.3.1 Pristine Compounds and Solid Solutions; 5.3.1.1 TiO2 327 $a5.3.1.2 WO3 330 $aFocusing on the basic principles of semiconductor photocatalysis, this book also gives a brief introduction to photochemistry, photoelectrochemistry, and homogeneous photocatalysis. In addition, the author - one of the leading authorities in the field - presents important environmental and practical aspects. A valuable, one-stop source for all chemists, material scientists, and physicists working in this area, as well as novice researchers entering (semiconductor) photocatalysis.
606 $aCatalysts 606 $aNanoparticles 606 $aPhotocatalysis 615 0$aCatalysts. 615 0$aNanoparticles. 615 0$aPhotocatalysis. 676 $a660.2995 700 $aKisch$b Horst$0935228 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910808307103321 996 $aSemiconductor photocatalysis$93936244 997 $aUNINA