LEADER 05474nam 2200745Ia 450 001 9910807734003321 005 20200520144314.0 010 $a9783527654604 010 $a3527654607 010 $a9783527654581 010 $a3527654585 010 $a9783527654611 010 $a3527654615 035 $a(CKB)2550000001106849 035 $a(EBL)1325046 035 $a(OCoLC)854977506 035 $a(SSID)ssj0001034924 035 $a(PQKBManifestationID)11568827 035 $a(PQKBTitleCode)TC0001034924 035 $a(PQKBWorkID)11016108 035 $a(PQKB)10358828 035 $a(MiAaPQ)EBC1325046 035 $a(MiAaPQ)EBC4044371 035 $a(Au-PeEL)EBL1325046 035 $a(CaPaEBR)ebr10740155 035 $a(CaONFJC)MIL507219 035 $a(Perlego)1001862 035 $a(EXLCZ)992550000001106849 100 $a20130801d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMAX phases $eproperties of machinable ternary carbides and nitrides /$fMichel W. Barsoum 205 $a1st ed. 210 $aHoboken, NJ $cWiley$d2013 215 $a1 online resource (437 p.) 300 $aDescription based upon print version of record. 311 08$a9783527330119 311 08$a3527330119 311 08$a9781299759688 311 08$a1299759688 327 $aMAX Phases; Contents; Preface; 1 Introduction; 1.1 Introduction; 1.2 History of the MAX Phases; References; 2 Structure, Bonding, and Defects; 2.1 Introduction; 2.2 Atom Coordinates, Stacking Sequences, and Polymorphic Transformations; 2.3 Lattice Parameters, Bond Lengths, and Interlayer Thicknesses; 2.4 Theoretical Considerations; 2.5 To Be or Not to Be; 2.6 Distortion of Octahedra and Trigonal Prisms; 2.7 Solid Solutions; 2.8 Defects; 2.9 Summary and Conclusions; Appendix A: Bond distances and distortions in the M3AX2 and M4AX3 phases; References 327 $a3 Elastic Properties, Raman and Infrared Spectroscopy3.1 Introduction; 3.2 Elastic Constants; 3.3 Young's Moduli and Shear Moduli; 3.4 Poisson's Ratios; 3.5 Bulk Moduli; 3.6 Extrema in Elastic Properties; 3.7 Effect of Temperature on Elastic Properties; 3.8 Raman Spectroscopy; 3.9 Infrared Spectroscopy; 3.10 Summary and Conclusions; References; 4 Thermal Properties; 4.1 Introduction; 4.2 Thermal Conductivities; 4.3 Atomic Displacement Parameters; 4.4 Heat Capacities; 4.5 Thermal Expansion; 4.6 Thermal Stability; 4.7 Summary and Conclusions; 4.A Appendix; References 327 $a5 Electronic, Optical, and Magnetic Properties5.1 Introduction; 5.2 Electrical Resistivities, Hall Coefficients, and Magnetoresistances; 5.3 Seebeck Coefficients, ?; 5.4 Optical Properties; 5.5 Magnetic Properties; 5.6 Superconducting Properties; 5.7 Summary and Conclusions; References; 6 Oxidation and Reactivity with Other Gases; 6.1 Introduction; 6.2 Ti3SiC2; 6.3 Tin+1AlXn; 6.4 Solid Solutions between Ti3AlC2 and Ti3SiC2; 6.5 Cr2AlC; 6.6 Nb2AlC and (Ti0.5,Nb0.5)2AlC; 6.7 Ti2SC; 6.8 V2AlC and (Ti0.5,V0.5)2AlC; 6.9 Ti3GeC2 and Ti3(Si,Ge)C2; 6.10 Ta2AlC; 6.11 Ti2SnC, Nb2SnC, and Hf2SnC 327 $a6.12 Ti2InC, Zr2InC, (Ti0.5,Hf0.5)2InC, and (Ti0.5,Zr0.5)2InC6.13 Sulfur Dioxide, SO2; 6.14 Anhydrous Hydrofluoric, HF, Gas; 6.15 Chlorine Gas; 6.16 Summary and Conclusions; Appendix A: Oxidation of Tin+1AlXn When Alumina Does Not Form a Protective Layer; References; 7 Chemical Reactivity; 7.1 Introduction; 7.2 Diffusivity of the M and A Atoms; 7.3 Reactions with Si, C, Metals, and Intermetallics; 7.4 Reactions with Molten Salts; 7.5 Reactions with Common Acids and Bases; 7.6 Summary and Conclusions; 7.A Appendix; References; 8 Dislocations, Kinking Nonlinear Elasticity, and Damping 327 $a8.1 Introduction8.2 Dislocations and Their Arrangements; 8.3 Kink Band Formation in Crystalline Solids; 8.4 Incipient Kink Bands; 8.5 Microscale Model for Kinking Nonlinear Elasticity; 8.6 Experimental Verification of the IKB Model; 8.7 Effect of Porosity; 8.8 Experimental Evidence for IKBs; 8.9 Why Microcracking Cannot Explain Kinking Nonlinear Elasticity; 8.10 The Preisach-Mayergoyz Model; 8.11 Damping; 8.12 Nonlinear Dynamic Effects; 8.13 Summary and Conclusions; References; 9 Mechanical Properties: Ambient Temperature; 9.1 Introduction 327 $a9.2 Response of Quasi-Single Crystals to Compressive Loads 330 $aIn this comprehensive yet compact monograph, Michel Barsoum, one of the pioneers in the field and the leading figure in MAX phase research, summarizes and explains, from both an experimental and a theoretical viewpoint, all the features that are necessary to understand and apply these new materials. In so doing, he covers elastic, electrical, thermal, chemical and mechanical properties in different temperature regimes, concluding with a treatment of MAX phase composites and potential as well as current applications. By bringing together, in a unified, self-contained manner, all the informa 606 $aPhase rule and equilibrium 606 $aTransition metal carbides 606 $aTransition metal nitrides 615 0$aPhase rule and equilibrium. 615 0$aTransition metal carbides. 615 0$aTransition metal nitrides. 676 $a669 700 $aBarsoum$b M. W$0622679 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910807734003321 996 $aMAX phases$94064573 997 $aUNINA