LEADER 04676nam 22007215 450 001 9910799218003321 005 20240313102637.0 010 $a981-9970-62-8 024 7 $a10.1007/978-981-99-7062-9 035 $a(CKB)29526890400041 035 $a(DE-He213)978-981-99-7062-9 035 $a(MiAaPQ)EBC31094203 035 $a(Au-PeEL)EBL31094203 035 $a(EXLCZ)9929526890400041 100 $a20240103d2024 u| 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aDesign of Crystal Structures Using Hydrogen Bonds on Molecular-Layered Cocrystals and Proton?Electron Mixed Conductor /$fby Masaki Donoshita 205 $a1st ed. 2024. 210 1$aSingapore :$cSpringer Nature Singapore :$cImprint: Springer,$d2024. 215 $a1 online resource (XII, 79 p. 57 illus., 49 illus. in color.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 311 08$a9789819970612 320 $aIncludes bibliographical references. 327 $aGeneral Introduction -- Rational Construction of Molecular Electron-conducting Nanowires Encapsulated in Proton-conducting Matrix in a Charge Transfer Salt -- Drastic Rearrangement of Self-assembled Hydrogen-bonded Tapes in a Molecular Crystal -- Various Stacking Patterns of Two-Dimensional Molecular Assemblies in Hydrogen-Bonded Cocrystals: Insight into Competitive Intermolecular Interactions and Control of Stacking Patterns -- General Conclusion. 330 $aThis thesis addresses the design of crystal structures using hydrogen bonds. In particular, it focuses on the design of functionalities and the control over the packing of molecular assemblies, based on molecular designs. Firstly, the synthesis and evaluation of a proton?electron mixed conducting charge transfer salt is reported. Focusing on the difference in the strength of hydrogen bonds and weaker intermolecular interactions, a system was rationally designed and constructed where electron-conducting molecular wires were encapsulated within a proton-conducting matrix. Next, the investigation of structural phase transitions in a cocrystal consisting of hydrogen-bonded two-dimensional molecular assemblies is reported. Drastic rearrangements of hydrogen-bonded molecular assemblies in the cocrystal led to single-crystal-to-single-crystal phase transitions, resulting in anisotropic changes in the crystal shape. Furthermore, chemical modification ofa component molecule in the cocrystal is reported. The modification afforded control over the stacking patterns of the two-dimensional molecular assemblies, i.e., sheets, and the mechanism was discussed considering the intersheet intermolecular interactions and molecular motion. It is suggested that hydrogen bonds are beneficial to construct molecular assemblies in molecular crystals because of their strength and well-defined directionality, and the consideration of coexisting weaker intermolecular interactions can lead to the design of whole crystal structures and, hence, functionalities. This thesis benefits students and researchers working on solid-state chemistry by presenting various methods for characterizing and evaluating the properties of molecular solids. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 606 $aChemistry, Inorganic 606 $aSolid state chemistry 606 $aChemical bonds 606 $aSupramolecular chemistry 606 $aMaterials$xAnalysis 606 $aCondensed matter 606 $aInorganic Chemistry 606 $aSolid-State Chemistry 606 $aChemical Bonding 606 $aSupramolecular Chemistry 606 $aMaterials Characterization Technique 606 $aPhase Transition and Critical Phenomena 615 0$aChemistry, Inorganic. 615 0$aSolid state chemistry. 615 0$aChemical bonds. 615 0$aSupramolecular chemistry. 615 0$aMaterials$xAnalysis. 615 0$aCondensed matter. 615 14$aInorganic Chemistry. 615 24$aSolid-State Chemistry. 615 24$aChemical Bonding. 615 24$aSupramolecular Chemistry. 615 24$aMaterials Characterization Technique. 615 24$aPhase Transition and Critical Phenomena. 676 $a548 700 $aDonoshita$b Masaki$01586769 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910799218003321 996 $aDesign of Crystal Structures Using Hydrogen Bonds on Molecular-Layered Cocrystals and Proton?Electron Mixed Conductor$93873741 997 $aUNINA