LEADER 03919nam 2200553 450 001 9910797548603321 005 20220504231203.0 010 $a0-12-803669-9 035 $a(CKB)3710000000468061 035 $a(EBL)2197347 035 $a(Au-PeEL)EBL2197347 035 $a(CaPaEBR)ebr11093403 035 $a(CaONFJC)MIL825605 035 $a(OCoLC)929143684 035 $a(MiAaPQ)EBC2197347 035 $a(PPN)200269364 035 $a(EXLCZ)993710000000468061 100 $a20150901h20162016 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aPericyclic reactions $ea mechanistic and problem-solving approach /$fSunil Kumar ; Vinod Kumar, ; S.P. Singh 210 1$aLondon, UK :$cElsevier Science,$d[2016] 210 4$dİ2016 215 $a1 online resource (383 p.) 300 $aDescription based upon print version of record. 311 $a0-12-803640-0 320 $aIncludes bibliographical references and index. 327 $aFront Cover; Pericyclic Reactions; Copyright; To Our Families; Contents; Preface; Chapter 1 - Pericyclic Reactions and Molecular Orbital Symmetry; 1.1 CLASSIFICATION OF PERICYCLIC REACTIONS; 1.2 MOLECULAR ORBITALS OF ALKENES AND CONJUGATED POLYENE SYSTEMS; 1.3 MOLECULAR ORBITALS OF CONJUGATED IONS OR RADICALS; 1.4 SYMMETRY PROPERTIES OF ? OR ?-MOLECULAR ORBITALS; 1.5 ANALYSIS OF PERICYCLIC REACTIONS; FURTHER READING; Chapter 2 - Electrocyclic Reactions; 2.1 CONROTATORY AND DISROTATORY MODES; 2.2 STEREOCHEMISTRY OF ELECTROCYCLIC REACTIONS; 2.3 SELECTION RULES FOR ELECTROCYCLIC REACTIONS 327 $a2.4 ANALYSIS OF ELECTROCYCLIC REACTIONS2.5 ELECTROCYCLIC REACTIONS OF IONIC SPECIES; Chapter 3 - Sigmatropic Rearrangements; 3.1 SUPRAFACIAL AND ANTARAFACIAL PROCESSES; 3.2 ANALYSIS OF SIGMATROPIC REARRANGEMENTS OF HYDROGEN; 3.3 ANALYSIS OF SIGMATROPIC REARRANGEMENTS OF ALKYL GROUP; 3.4 [3,3] SIGMATROPIC REARRANGEMENTS; 3.5 [5,5] SIGMATROPIC SHIFT; 3.6 [2,3] SIGMATROPIC REARRANGEMENTS; 3.7 PERIPATETIC CYCLOPROPANE BRIDGE: WALK REARRANGEMENTS; 3.8 SIGMATROPIC REARRANGEMENTS INVOLVING IONIC TRANSITION STATES; Chapter 4 - Cycloaddition Reactions; 4.1 STEREOCHEMICAL MODES OF CYCLOADDITION 327 $a4.2 FEASIBILITY OF CYCLOADDITION REACTIONS4.3 [2+2] CYCLOADDITIONS; 4.4 [4+2] CYCLOADDITIONS; 4.5 HIGHER CYCLOADDITIONS; 4.6 CYCLOADDITION OF MULTIPLE COMPONENTS; Chapter 5 - Cheletropic Reactions and 1,3-Dipolar Cycloadditions; 5.1 CHELETROPIC REACTIONS; 5.2 1,3-DIPOLAR CYCLOADDITIONS; Chapter 6 - Group Transfer, Elimination, and Related Reactions; 6.1 GROUP TRANSFER REACTIONS; 6.2 ELIMINATION REACTIONS; 6.3 DYOTROPIC REARRANGEMENTS; 6.4 ENE REACTIONS; 6.5 ?-ELIMINATIONS INVOLVING CYCLIC TRANSITION STRUCTURES; Chapter 7 - Unsolved Problems; Appendix - Solution Manual; Index 330 $aPericyclic Reactions: A Mechanistic and Problem-Solving Approach provides complete and systematic coverage of pericyclic reactions for researchers and graduate students in organic chemistry and pharmacy programs. Drawing from their cumulative years of teaching in the area, the authors use a clear, problem-solving approach, supplemented with colorful figures and illustrative examples. Written in an accessible and engaging manner, this book covers electrocyclic reactions, sigmatropic reactions, cycloaddition reactions, 1,3-dipolar reactions, group transfer, and ene reactions. It offers an in 606 $aRing formation (Chemistry) 606 $aChemical reactions 615 0$aRing formation (Chemistry) 615 0$aChemical reactions. 676 $a547.2 700 $aKumar$b Sunil$0868762 702 $aKumar$b Vinod 702 $aSingh$b S. P. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910797548603321 996 $aPericyclic reactions$93835840 997 $aUNINA