LEADER 05459nam 2200697 a 450 001 9910791943903321 005 20230802012640.0 010 $a3-527-64408-3 010 $a3-527-64407-5 010 $a1-280-66310-3 010 $a9786613640031 010 $a3-527-64409-1 035 $a(CKB)2560000000082663 035 $a(EBL)918626 035 $a(OCoLC)793996825 035 $a(SSID)ssj0000664740 035 $a(PQKBManifestationID)12301923 035 $a(PQKBTitleCode)TC0000664740 035 $a(PQKBWorkID)10631039 035 $a(PQKB)10668970 035 $a(MiAaPQ)EBC918626 035 $a(Au-PeEL)EBL918626 035 $a(CaPaEBR)ebr10580212 035 $a(CaONFJC)MIL364003 035 $a(EXLCZ)992560000000082663 100 $a20120731d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSynthesis of polymers$b[electronic resource] $enew structures and methods. volume 1 /$fedited by A. Dieter Schlu?ter, Craig J. Hawker, and Junji Sakamoto 210 $aWeinheim, Germany $cWiley-VCH$d2012 215 $a1 online resource (1203 p.) 225 0 $aSynthesis of polymers : new structures and methods ;$vv. 1 300 $aDescription based upon print version of record. 311 $a3-527-32757-6 320 $aIncludes bibliographical references and index. 327 $aSynthesis of Polymers; Contents; List of Contributors; 1 Foreword; References; 2 Polymer Synthesis: An Industrial Perspective; 2.1 About this Chapter; 2.2 Why?; 2.3 Thesis: There Are No Limits to the Fantasy of a Synthetic Polymer Chemist; 2.4 Antithesis: We May Be Able to Synthesize Millions of New Polymers-But Why Should We Do So?; 2.5 Synthesis; 2.5.1 Polymer Chemistry in Two Dimensions: Coatings; 2.5.2 Polymer Chemistry Going Broad: Effects of Molar Mass Distribution; 2.5.3 Polymer Chemistry Meets The Life Sciences: Polymeric Drug-Delivery Systems; 2.6 Conclusions; Acknowledgments 327 $a3 From Heterogeneous Ziegler-Natta to Homogeneous Single-Center Group 4 Organometallic Catalysts: A Primer on the Coordination Polymerization of Olefins3.1 Introduction; 3.2 Chapter Prospectus; 3.3 Fundamentals of Coordination Polymerization; 3.3.1 Ziegler-Natta Catalysts; 3.3.1.1 First-Generation ZN Catalysts; 3.3.1.2 Second-Generation ZN Catalysts; 3.3.1.3 Third-Generation ZN Catalysts; 3.3.1.4 Fourth-Generation ZN Catalysts; 3.3.1.5 Fifth-Generation ZN Catalysts; 3.3.2 Cossee-Arlman Mechanism; 3.3.3 Stereocontrol; 3.3.4 Regiocontrol; 3.3.5 Chain Termination 327 $a3.3.6 Molecular Weight Distributions and Branching3.4 Homogeneous Single-Center Coordination Polymerization; 3.4.1 Molecular Catalysts; 3.4.2 Metallocenes; 3.4.3 Stereocontrol; 3.4.4 Stereochemical Microstructure Analysis; 3.4.5 Cocatalysts; 3.5 Conclusions; Acknowledgments; References; 4 Cobalt-Mediated Radical Polymerization; 4.1 Introduction; 4.2 Mechanistic Considerations; 4.3 Key Parameters of CMRP; 4.3.1 The Cobalt Complex Structure; 4.3.2 Polymerization Conditions; 4.4 Macromolecular Engineering; 4.5 Cobalt-Mediated Radical Coupling (CMRC); 4.6 Summary and Outlook; Acknowledgments 327 $aReferences5 Anionic Polymerization: Recent Advances; 5.1 Background; 5.2 Living Anionic Polymerization of Various Monomers; 5.2.1 Styrene Derivatives; 5.2.2 1,3-Diene Monomers; 5.2.3 2- and 4-Vinylpyridines; 5.3 (Meth)acrylate Derivatives; 5.4 Acrylamide Derivatives; 5.5 Cyclic Monomers; 5.6 Other Monomers; 5.7 Reaction of Living Anionic Polymers with Electrophiles: Synthesis of Chain-Functionalized Polymers; 5.8 Synthesis of Architectural Polymers via Living Anionic Polymerization; 5.8.1 Block Copolymers; 5.8.2 Graft Copolymers; 5.8.3 Star-Branched Polymers 327 $a5.8.4 Complex Architectural Polymers5.9 Anionic Polymerization: Practical Aspects; 5.10 Concluding Remarks; References; 6 Alkyne Metathesis Polymerization (ADIMET) and Macrocyclization (ADIMAC); 6.1 Introduction; 6.2 Catalyst Development; 6.3 Poly(Phenylene Ethynylene)s via ADIMET; 6.4 ADIMAC-Acyclic Diyne Metathesis Macrocyclization; 6.5 Conclusions; References; 7 The Synthesis of Conjugated Polythiophenes by Kumada Cross-Coupling; 7.1 Introduction to Polythiophene; 7.2 Kumada Cross-Coupling; 7.3 Polythiophenes by Kumada Cross-Coupling; 7.3.1 Initiation and Catalyst Transfer Propagation 327 $a7.3.2 Summary of Mechanistic Studies 330 $aEdited and written by the ""Who's who"" in polymer science and technology, this two-volume handbook and ready reference is a must-have compilation on the topic. At once comprehensive and trendy, all relevant topics are covered, with the chapters focusing either on the different types of polymerization reactions, or on the important classes of polymers, or on their applications.The result is an overview that equally provides a generous amount of information on the latest research developments. 410 0$aMaterials Science and Technology: A Comprehensive Treatment 606 $aPolymerization 615 0$aPolymerization. 676 $a547.7 676 $a547/.7 676 $a668.9 701 $aSchlu?ter$b A.-Dieter$0959256 701 $aHawker$b Craig J$01584341 701 $aSakamoto$b Junji$01584342 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910791943903321 996 $aSynthesis of polymers$93868047 997 $aUNINA