LEADER 05132nam 2200625Ia 450 001 9910788622203321 005 20230803033456.0 010 $a1-283-89995-7 010 $a981-4322-85-7 035 $a(CKB)3280000000002150 035 $a(EBL)1109699 035 $a(OCoLC)826853964 035 $a(SSID)ssj0000789186 035 $a(PQKBManifestationID)11407337 035 $a(PQKBTitleCode)TC0000789186 035 $a(PQKBWorkID)10726049 035 $a(PQKB)11293962 035 $a(MiAaPQ)EBC1109699 035 $a(WSP)00002859 035 $a(Au-PeEL)EBL1109699 035 $a(CaPaEBR)ebr10640592 035 $a(CaONFJC)MIL421245 035 $a(EXLCZ)993280000000002150 100 $a20121218d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFundamentals of polymerization$b[electronic resource] /$fBroja M. Mandal 210 $aSingapore ;$aLondon $cWorld Scientific$dc2013 215 $a1 online resource (468 p.) 300 $aIncludes index. 311 $a981-4322-46-6 320 $aIncludes bibliographical references and index. 327 $aPreface; Contents; List of Abbreviations; Chapter 1. Introduction; 1.1 Nomenclature; 1.2 Structural and Repeating (or Repeat) Units; 1.3 Classification; 1.3.1 Condensation and addition polymers and polymerizations; 1.3.2 Step-growth and chain-growth polymers and polymerizations; 1.4 Functionality; 1.5 Designed Branched Polymers; 1.5.1 Star polymers; 1.5.2 Hyperbranched polymers; 1.5.3 Dendrimers; 1.6 Physical State; 1.7 Structure-Property Relationship; 1.7.1 Nonconjugated polymers; Rubbers; Fibers and plastics; 1.7.1.1 Stereoregularity in vinyl polymers 327 $a1.7.1.2 Regioregularity in vinyl polymers1.7.2 Conjugated polymers; 1.8 Thermodynamics of Polymerization; 1.9 Polymerizability of Internal Olefins; 1.10 Molecular Weights and Molecular Weight Distributions; References; Problems; Chapter 2. Step Polymerization; 2.1 Principle of Equal Reactivity of Functional Groups and Kinetics of Polymerization; 2.2 Ring vs. Chain Formation; 2.3 Intermolecular Interchange Reactions; 2.4 Degree of Polymerization; 2.4.1 Carothers equation; 2.4.1.1 Bifunctional polycondensation; 2.4.1.2 Control of degree of polymerization 327 $a2.4.1.2.1 Polymerization of nonequivalent monomer mixtures2.4.1.2.2 Departure from Carothers equation in interfacial polycondensation; 2.5 Molecular Weight Distribution; 2.5.1 Molecular weight distribution in bifunctional polycondensation; 2.5.2 Average degree of polymerization for most probable distribution; 2.6 Prediction of Gel Point in Polyfunctional Polycondensation; 2.6.1 Prediction based on Carothers equation; 2.6.2 Prediction based on statistical method of Flory; 2.6.2.1 Gel-forming range of monomer proportions; 2.6.2.1.1 Polycondensation of Af and B-B monomers 327 $a2.6.2.1.2 Polymerization of a ternary mixture of A-A, B-B, and A3 monomers2.7 Thermosetting Resins; 2.7.1 Phenolic resins; 2.7.2 Amino resins; 2.7.3 Unsaturated polyesters and alkyd resins; 2.7.4 Polyurethanes and polyureas; 2.7.5 Epoxy resins; 2.7.6 Polysiloxanes; 2.7.7 Aliphatic polysulfides; 2.8 Engineering Plastics; 2.8.1 Polyamides; 2.8.1.1 Aliphatic polyamides; 2.8.1.2 Aromatic polyamides; 2.8.2 Polyesters; 2.8.2.1 Aliphatic-aromatic polyesters; 2.8.2.2 Aromatic polyesters; 2.8.3 Polycarbonates; 2.8.4 Poly(phenylene oxide)s; 2.9 High Performance Polymers 327 $a2.9.1 Liquid crystalline polymers (LCPs)2.9.2 Poly(p-phenylene sulfide); 2.9.3 Poly(arylene ether)s; 2.9.4 Polyimides; 2.9.4.1 Thermoplastic polyimides; Polyetherimides and Polyamide imides; 2.9.4.2 Thermosetting polyimides; 2.9.5 Polybenzimidazoles; 2.9.6 Polybenzoxazoles and polybenzothiazoles; 2.10 Nonconventional Step Polymerization; References; Problems; Chapter 3. Radical Polymerization; 3.1 General Features; 3.1.1 Monomer types; 3.1.2 Reactivity of monomers and radicals; 3.2 Kinetics of Homogeneous Radical Polymerization; 3.3 Reaction Orders in Initiator and Monomer; 3.4 Initiators 327 $a3.4.1 Thermal initiators 330 $aOver the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and di 606 $aPolymerization 606 $aChemical reactions 615 0$aPolymerization. 615 0$aChemical reactions. 676 $a547.28 700 $aMandal$b Broja Mohan$01510456 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910788622203321 996 $aFundamentals of polymerization$93743143 997 $aUNINA