LEADER 05854nam 2200673 450 001 9910787868303321 005 20200520144314.0 010 $a1-118-83728-2 010 $a1-118-83721-5 010 $a1-118-83726-6 035 $a(CKB)2670000000530882 035 $a(EBL)1641074 035 $a(SSID)ssj0001131848 035 $a(PQKBManifestationID)11749934 035 $a(PQKBTitleCode)TC0001131848 035 $a(PQKBWorkID)11146319 035 $a(PQKB)10383312 035 $a(OCoLC)878139197 035 $a(MiAaPQ)EBC1641074 035 $a(DLC) 2013048403 035 $a(Au-PeEL)EBL1641074 035 $a(CaPaEBR)ebr10845591 035 $a(CaONFJC)MIL580367 035 $a(OCoLC)864753087 035 $a(PPN)18857459X 035 $a(EXLCZ)992670000000530882 100 $a20140318h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 14$aThe chemistry of bio-based polymers /$fJohannes Karl Fink ; cover design by Russell Richardson 210 1$aHoboken, New Jersey ;$aSalem, Massachusetts :$cScrivener Publishing :$cJohn Wiley & Sons,$d2014. 210 4$dİ2014 215 $a1 online resource (358 p.) 300 $aDescription based upon print version of record. 311 $a1-118-83725-8 320 $aIncludes bibliographical references and index. 327 $aCover; Title Page; Copyright Page; Contents; Preface; 1 An Overview of Methods and Standards; 1.1 History of Biodegradable Plastics; 1.2 Green Chemistry; 1.2.1 Genetic Engineering; 1.3 Commercial Situation; 1.4 Environmental Situation; 1.4.1 Problems with Biobased Composites; 1.4.2 Biodegradation; 1.5 Properties of Biodegradable Polymers; 1.6 Special Methods of Synthesis; 1.6.1 Conventional Methods; 1.6.2 Click Chemistry; 1.6.3 Enzymatic Polymerization; 1.6.4 Chemoenzymatic Polymerization; 1.6.5 Vine-twining Polymerization; 1.6.6 Bacterial Synthesis; 1.7 Biodegradability Standards 327 $a1.7.1 Guidelines for the Development of Standards1.7.2 Specifications for Compostable Plastics; 1.7.3 Ultimate Anaerobic Biodegradability; 1.7.4 Aerobic Biodegradability; 1.7.5 Biodegradability of Plastics in Sea water; 1.8 Test of the Biological Origin; References; Part I Bio-based Polymers Degradation and Chemistry; 2 Vinyl Based Polymers; 2.1 Polyolefins; 2.1.1 Degradability; 2.1.2 Degradation Mechanism; 2.1.3 Pro-degradants; 2.2 Poly(styrene) Elastomers; 2.3 Poly(vinyl alcohol); 2.3.1 Plasticized Compositions; 2.3.2 Hydrogels; 2.4 Poly(vinyl butyral) 327 $a2.4.1 Blends with Poly(3-hydroxybutyrate)2.4.2 Blends with Poly(lactic acid); 2.4.3 Paper coatings; 2.4.4 Fibers; 2.4.5 Membranes; 2.4.6 Solar Cells; 2.4.7 Adhesive for Safety Glass; References; 3 Acid and Lactone Polymers; 3.1 Poly(lactic acid); 3.1.1 Production Processes for Poly(lactic acid); 3.1.2 Surface Modification of Fibers; 3.1.3 Influence of Fabrication Methods and Kenaf Fiber Length; 3.1.4 Kenaf fibers for Reinforcement of PP; 3.1.5 Reinforced Composites; 3.1.6 Laminated Composites from Kenaf Fiber; 3.1.7 Copolyesters; 3.1.8 Transparent Crystalline Poly(lactic acid) 327 $a3.1.9 Laminated Biocomposites3.2 Poly(glycolic acid)s; 3.2.1 Glycolic acid; 3.2.2 Polymers, Copolymers, and Blends; 3.2.3 Condensation Polymer of Glycerol; 3.3 Butyrolactone-based Vinyl Monomers; 3.3.1 Tulipalin A; 3.3.2 ?-Methylene-?-valerolactone; 3.4 Poly(caprolactone); References; 4 Ester and Amide Polymers; 4.1 Poly(ester)s; 4.1.1 Methyl-10-undecenoate; 4.1.2 Poly(butylene adipate) Copolyesters; 4.1.3 Poly(hydroxyalkanoate)s; 4.1.4 Poly(hydroxybutyrate); 4.1.5 Poly(hydroxyvalerate); 4.1.6 Poly(3-hydroxyhexanoic acid); 4.1.7 Poly(?-hydroxyoctanoate); 4.1.8 Poly(?-glutamic acid) 327 $a4.1.9 Poly(butylene succinate)4.1.10 Dianhydrohexitols based Polymers; 4.1.11 Aliphatic-Aromatic Copolyesters; 4.1.12 Succinate Based Polyesters; 4.1.13 Sebacate Based Polyesters; 4.1.14 Unsaturated Polyesters; 4.1.15 Sulfonated Polyesters; 4.2 Plant oil-based Biopolymers; 4.2.1 Plant Oils with Acrylic Moities; 4.2.2 Plant Oils with Phosphorus Moities; 4.2.3 Vanillin Based Monomers; 4.2.4 Vegetable oil Thermosets; 4.3 Poly(amide)s; 4.3.1 Soy Based Bio-plastic and Chopped Industrial Hemp; 4.3.2 Soy bean based Composites; References; 5 Carbohydrate Related Polymers; 5.1 Starch 327 $a5.1.1 Starch Modification 330 $a"Because of the recent explosion of interdisciplinary research in renewable polymers, the knowledge base is scattered and it is now timely to have an overview from a respected chemist and successful author. The book focuses on biopolymers as well as low molecular compounds that can be synthesized from renewable polymers. After introducing general aspects of the field, the subsequent chapters then look at the chemistry of biodegradable polymeric types sorted by their chemical compounds, including the synthesis of low molecular compounds. The factors influencing degradation and biodegradation of polymers for food packaging in various environments is detailed at length. The medical applications covered concentrate on controlled drug delivery, temporary prostheses, and scaffolds for tissue engineering. The author then turns his attention to renewable resources for fabricating biofuels and argues for localized biorefineries as biomass feedstocks are more efficiently handled locally"--$cProvided by publisher. 606 $aBiodegradable plastics 615 0$aBiodegradable plastics. 676 $a620.1/92323 686 $aTEC009010$2bisacsh 700 $aFink$b Johannes Karl$0626425 702 $aRichardson$b Russell 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910787868303321 996 $aThe chemistry of bio-based polymers$92144025 997 $aUNINA