LEADER 01136nam^a2200277 i 4500 001 991001166679707536 008 050721s2004 sw a b 010 0 eng d 020 $a9197409472 035 $ab13330500-39ule_inst 040 $aDip.to Filologia Class. e Scienze Filosofiche$bita 245 00$aDais phil?sistephanos :$bstudies in honour of professor Staffan Fogelmark, presented on the occasion of his 65th birthday, 12 April 2004 /$cedited by Pär Sandin and Marianne Wifstrand Schiebe 260 $aUppsala :$bDahlia Books,$c2004 300 $a447 p. :$bill. ;$c21 cm 600 14$aFogelmark, Staffan$xStudi in onore 650 4$aLetteratura greca 650 4$aLetteratura latina 650 4$aFilologia classica 700 1 $aSandin, Pär 700 1 $aWifstrand Schiebe, Marianne 700 1 $aFogelmark, Staffan 907 $a.b13330500$b02-04-14$c21-07-05 912 $a991001166679707536 945 $aLE007 00 SAN 01.01$g1$i2007000094228$lle007$op$pE0.00$q-$rl$s- $t0$u0$v0$w0$x0$y.i14111329$z21-07-05 996 $aDais phil?sistephanos$91105579 997 $aUNISALENTO 998 $ale007$b21-07-05$cm$da $e-$feng$gsw $h0$i0 LEADER 04794nam 2200661 450 001 9910784566903321 005 20200520144314.0 010 $a1-281-03728-1 010 $a9786611037284 010 $a0-08-052133-9 035 $a(CKB)1000000000363806 035 $a(EBL)299474 035 $a(OCoLC)437182708 035 $a(SSID)ssj0000275342 035 $a(PQKBManifestationID)11221357 035 $a(PQKBTitleCode)TC0000275342 035 $a(PQKBWorkID)10350358 035 $a(PQKB)11047050 035 $a(Au-PeEL)EBL299474 035 $a(CaPaEBR)ebr10186737 035 $a(CaONFJC)MIL103728 035 $a(MiAaPQ)EBC299474 035 $a(PPN)182569063 035 $a(EXLCZ)991000000000363806 100 $a20170814h20002000 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aWriting reaction mechanisms in organic chemistry /$fAudrey Miller, Philippa H. Solomon 205 $aSecond edition. 210 1$aSan Diego, California :$cAcademic Press,$d2000. 210 4$d©2000 215 $a1 online resource (487 p.) 225 1 $aAdvanced Organic Chemistry Series 300 $aIncludes index. 311 $a0-12-410509-2 311 $a0-12-496712-4 320 $aIncludes bibliographical references and index. 327 $aFront Cover; Writing Reaction Mechanisms in Organic Chemistry; Copyright Page; Contents; Preface to the Second Edition; Preface to First Edition; Chapter 1. Introduction-Molecular Structure and Reactivity; 1. How to Write Lewis Structures and Calculate Formal Charges; 2. Representations of Organic Compounds; 3. Geometry and Hybridization; 4. Electronegativities and Dipoles; 5. Resonance Structures; 6. Aromaticity and Antiaromaticity; 7. Tautomers and Equilibrium; 8. Acidity and Basicity; 9. Nucleophiles and Electrophiles; Chapter 2. General Principles for Writing Reaction Mechanisms 327 $a1. Balancing Equations2. Using Arrows to Show Moving Electrons; 3. Mechanisms in Acidic and Basic Media; 4. Electron-Rich Species: Bases or Nucleophiles?; 5. Trimolecular Steps; 6. Stability of Intermediates; 7. Driving Forces for Reactions; 8. Structural Relationships between Starting Materials and Products; 9. Solvent Effects; 10. A Last Word; Chapter 3. Reactions of Nucleophiles and Bases; 1. Nucleophilic Substitution; 2. Eliminations at Saturated Carbon; 3. Nucleophilic Addition to Carbonyl Compounds; 4. Base-Promoted Rearrangements; 5. Additional Mechanisms in Basic Media 327 $aChapter 4. Reactions Involving Acids and Other Electrophiles1. Stability of Carbocations; 2. Formation of Carbocations; 3. The Fate of Carbocations; 4. Rearrangement of Carbocations; 5. Electrophilic Addition; 6. Acid-Catalyzed Reactions of Carbonyl Compounds; 7. Electrophilic Aromatic Substitution; 8. Carbenes; 9. Electrophilic Heteroatoms; Chapter 5. Radicals and Radical Anions; 1. Introduction; 2. Formation of Radicals; 3. Radical Chain Processes; 4. Radical Inhibitors; 5. Determining the Thermodynamic Feasibility of Radical Reactions; 6. Addition of Radicals; 7. Fragmentation Reactions 327 $a8. Rearrangement of Radicals9. The Srnl Reaction; 10. The Birch Reduction; 11. A Radical Mechanism for the Rearrangement of Some Anions; Chapter 6. Pericyclic Reactions; 1. Introduction; 2. Electrocyclic Reactions; 3. Cycloadditions; 4. Sigmatropic Rearrangements; 5. The Ene Reaction; 6. A Molecular Orbital View of Pericyclic Processes; Chapter 7. Additional Problems; Appendix A: Lewis Structures of Common Functional Groups; Appendix B: Symbols and Abbreviations Used in Chemical Notation; Appendix C: Relative Acidities of Common Organic and Inorganic Substances; Index 330 $aWriting Reaction Mechanisms in Organic Chemistry, Second Edition, is an invaluable guide to charting the movements of atoms and electrons in the reactions of organic molecules. Miller and Solomon illustrate that understanding organic reactions is based on applying general principles rather than the rote memorization of unrelated processes, and, in turn, emphasize that writing mechanisms is a practical method of applying knowledge of previously encountered reactions and reaction conditions to new reactions. Students and research chemists alike will find this book useful in providing a me 410 0$aAdvanced organic chemistry series. 606 $aOrganic reaction mechanisms 615 0$aOrganic reaction mechanisms. 676 $a547/.139 700 $aMiller$b Audrey$0440363 702 $aSolomon$b Philippa H. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910784566903321 996 $aWriting reaction mechanisms in organic chemistry$91502625 997 $aUNINA