LEADER 05221nam 2200661 a 450 001 9910783105503321 005 20200520144314.0 010 $a1-280-34603-5 010 $a9786610346035 010 $a0-471-67055-3 010 $a0-471-67056-1 035 $a(CKB)1000000000019099 035 $a(EBL)214305 035 $a(OCoLC)605512099 035 $a(SSID)ssj0000254019 035 $a(PQKBManifestationID)11227828 035 $a(PQKBTitleCode)TC0000254019 035 $a(PQKBWorkID)10226882 035 $a(PQKB)10181981 035 $a(MiAaPQ)EBC214305 035 $a(Au-PeEL)EBL214305 035 $a(CaPaEBR)ebr10114133 035 $a(CaONFJC)MIL34603 035 $a(PPN)243287917 035 $a(EXLCZ)991000000000019099 100 $a20040412d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSurfactants and interfacial phenomena$b[electronic resource] /$fMilton J. Rosen 205 $a3rd ed. 210 $aHoboken, N.J. $cWiley-Interscience$dc2004 215 $a1 online resource (460 p.) 300 $aDescription based upon print version of record. 311 $a0-471-47818-0 320 $aIncludes bibliographical references and index. 327 $aSURFACTANTS AND INTERFACIAL PHENOMENA; Contents; Preface; 1 Characteristic Features of Surfactants; A Conditions Under Which Interfacial Phenomena and Surfactants Become Significant; B General Structural Features and Behavior of Surfactants; 1 General Use of Charge Types; 2 General Effects of the Nature of the Hydrophobic Group; I Characteristic Features and Uses of Commercially Available Surfactants; I.A Anionics; 1 Carboxylic Acid Salts; 2 Sulfonic Acid Salts; 3 Sulfuric Acid Ester Salts; 4 Phosphoric and Polyphosphoric Acid Esters; 5 Fluorinated Anionics; I.B Cationics 327 $a1 Long-Chain Amines and Their Salts2 Acylated Diamines and Polyamines and Their Salts; 3 Quaternary Ammonium Salts; 4 Polyoxyethylenated (POE) Long-Chain Amines; 5 Quaternized POE Long-Chain Amines; 6 Amine Oxides; I.C Nonionics; 1 POE Alkylphenols, Alkylphenol ''Ethoxylates''; 2 POE Straight-Chain Alcohols, Alcohol ''Ethoxylates''; 3 POE Polyoxypropylene glycols; 4 POE Mercaptans; 5 Long-Chain Carboxylic Acid Esters; 6 Alkanolamine ''Condensates,'' Alkanolamides; 7 Tertiary Acetylenic Glycols and Their ''Ethoxylates''; 8 POE Silicones; 9 N-Alkylpyrrolidones; 10 Alkylpolyglycosides 327 $aI.D Zwitterionics1 pH-Sensitive Zwitterionics; 2 pH-Insensitive Zwitterionics; I.E Newer Surfactants Based Upon Renewable Raw Materials; 1 a-Sulfofatty Acid Methyl Esters (SME); 2 Acylated Aminoacids; 3 N-Acyl L-Glutamates (AG); 4 N-Acyl Glycinates; 5 N-Acyl DL-Alaninates; 6 Other Acylated Aminoacids; 7 Nopol Alkoxylates; II Environmental Effects of Surfactants; II.A Surfactant Biodegradability; II.B Surfactant Toxicity To and Bioconcentration in Marine Organisms; III Some Useful Generalizations; References; Problems 327 $a2 Adsorption of Surface-Active Agents at Interfaces: The Electrical Double LayerI The Electrical Double Layer; II Adsorption at the Solid-Liquid Interface; II.A Mechanisms of Adsorption and Aggregation; II.B Adsorption Isotherms; 1 The Langmuir Adsorption Isotherm; II.C Adsorption from Aqueous Solution Onto Adsorbents with Strongly Charged Sites; 1 Ionic Surfactants; 2 Nonionic Surfactants; 3 pH Change; 4 Ionic Strength; 5 Temperature; II.D Adsorption from Aqueous Solution Onto Nonpolar, Hydrophobic Adsorbents 327 $aII.E Adsorption from Aqueous Solution Onto Polar Adsorbents without Strongly Charged SitesII.F Effects of Adsorption from Aqueous Solution on the Surface Properties of the Solid Adsorbent; 1 Substrates with Strongly Charged Sites; 2 Nonpolar Adsorbents; II.G Adsorption from Nonaqueous Solution; II.H Determination of the Specific Surface Areas of Solids; III Adsorption at the Liquid-Gas (L/G) and Liquid-Liquid (L/L) Interfaces; III.A The Gibbs Adsorption Equation; III.B Calculation of Surface Concentrations and Area per Molecule at the Interface By Use of the Gibbs Equation 327 $aIII.C Effectiveness of Adsorption at the L/G and L/L Interfaces 330 $aThis book is the premier text on the properties and applications of surfactants. The third edition is completely updated and revised, including new information on gemini surfactants (a new type of powerful surfactant), superspreading (or superwetting) by aqueous surfactant solutions of highly hydrophobic surfaces (important in agricultural applications), and dynamic surface tension (an important interfacial property not covered in the first two editions).* Clearly explains the mechanisms by which surfactants operate in interfacial processes* Uses a minimum of mathematics in explanation 606 $aSurface active agents 606 $aSurface chemistry 615 0$aSurface active agents. 615 0$aSurface chemistry. 676 $a668/.1 700 $aRosen$b Milton J$0460061 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910783105503321 996 $aSurfactants and Interfacial Phenomena$9779874 997 $aUNINA