LEADER 03745nam 22005775 450 001 9910768197603321 005 20231201120534.0 010 $a3-031-45960-1 024 7 $a10.1007/978-3-031-45960-3 035 $a(MiAaPQ)EBC30983257 035 $a(Au-PeEL)EBL30983257 035 $a(DE-He213)978-3-031-45960-3 035 $a(CKB)29181431300041 035 $a(EXLCZ)9929181431300041 100 $a20231201d2023 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aPerspectives of Hydrosilylation Reactions /$fedited by Bogdan Marciniec, Hieronim Maciejewski 205 $a1st ed. 2023. 210 1$aCham :$cSpringer Nature Switzerland :$cImprint: Springer,$d2023. 215 $a1 online resource (332 pages) 225 1 $aTopics in Organometallic Chemistry,$x1616-8534 ;$v72 311 08$aPrint version: Marciniec, Bogdan Perspectives of Hydrosilylation Reactions Cham : Springer,c2024 9783031459597 327 $aSilicometallics vs. Organometallics and Catalysis ? General Guidelines -- Recent Advances and Applications of Group 10 Transition Metal Hydrosilylation Catalysts -- State of the Art in Rhodium and Iridium Catalyzed Hydrosilylation Reactions -- Recent Development of Cobalt-Catalyzed Hydrosilylation Reactions: New Catalysts, Mechanistic Understandings and Future Trends -- Iron and Manganese Catalysed Hydrosilylation Reactions -- Catalysis of Hydrosilylation Processes with the Participation of Ionic Liquids -- Hydrosilylation Catalysis for One-pot Synthesis -- Hydrosilylation of Carbon?Carbon Multiple Bonds in Organic Synthesis. 330 $aThis volume describes the latest advances and perspectives in hydrosilylation, with a focus on new organometallic catalysts and their mechanistic aspects. Hydrosilylation is the reaction of ?SiH with carbon-carbon, carbon-heteroatom or heteroatom-heteroatom bonds and is the most fundamental and elegant method for laboratory and industrial synthesis of organosilicon molecular and macromolecular compounds. Yet these reactions do require a catalyst, for which initially homogeneous noble metal catalyst, mainly platinum, rhodium, iridium or ruthenium were used. However the high prices, metallic residues of these valuable catalysts as well as issues with product purification, did increase the interest in developing new catalysts. Noteworthy in this regard are the recently developed hydrosilylation reactions using catalysts based on earth-abundant transition metals (for example Mn, Fe, Co, Ni) and heterogeneous catalysts presented here. This volume of Topics in Organometallic Chemistry is written for scientists interested in silicon chemistry and its catalytic aspects, but can also be used as valuable handbook for postgraduate and advanced undergraduate students working with organometallic chemistry, catalysis as well as synthesis of fine chemicals. 410 0$aTopics in Organometallic Chemistry,$x1616-8534 ;$v72 606 $aOrganometallic chemistry 606 $aChemistry, Organic 606 $aChemistry 606 $aOrganometallic Chemistry 606 $aOrganic Chemistry 606 $aChemistry 615 0$aOrganometallic chemistry. 615 0$aChemistry, Organic. 615 0$aChemistry. 615 14$aOrganometallic Chemistry. 615 24$aOrganic Chemistry. 615 24$aChemistry. 676 $a547.05 700 $aMarciniec$b Bogdan$01453503 701 $aMaciejewski$b Hieronim$01334189 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910768197603321 996 $aPerspectives of Hydrosilylation Reactions$93656149 997 $aUNINA