LEADER 04464nam 22006375 450 001 9910767572303321 005 20251116212047.0 010 $a3-030-10955-0 024 7 $a10.1007/978-3-030-10955-4 035 $a(CKB)4100000007702186 035 $a(DE-He213)978-3-030-10955-4 035 $a(MiAaPQ)EBC5926130 035 $a(PPN)235004189 035 $a(EXLCZ)994100000007702186 100 $a20190225d2019 u| 0 101 0 $aeng 135 $aurnn#008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aOrganometallics for Green Catalysis /$fedited by Pierre H. Dixneuf, Jean-François Soulé 205 $a1st ed. 2019. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2019. 215 $a1 online resource (X, 301 p.) 225 1 $aTopics in Organometallic Chemistry,$x1436-6002 ;$v63 311 08$a3-030-10954-2 327 $aMetal-Catalysed Hydrogenation of CO2 into Methanol -- Catalytic C-C Bond Formations from CO2 with Alkenes -- Recent advances on CO2 utilization as C1 building block in C-N and C-O bond formation -- ?Alkene Metathesis for Transformation of Renewables? -- Metal-Catalyzed Aromatic C-O Bond Activation/Transformation -- Hydrogenation/Dehydrogenation of Unsaturated Bonds with Iron Pincer Catalysis -- Conversion of Alcohols to Carboxylates Using Water and Base with H2 Liberation -- Selective Transfer-hydrogenation of ?,?-Unsaturated Carbonyl Compounds -- Functionalization of C(sp2)?H Bonds of Arenes and Heteroarenes Assisted by Photoredox-Catalysts for the C?C Bond Formation -- Green Cross-Coupling using Visible-light for C-O and C-N Bond Formation. 330 $aThis volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol ?an eco-friendly energy storage strategy? and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C?O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C?H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C?H bond oxidation using visible light leads mainly to the formation of C?O and C?N bonds, whereas cross-coupled C?C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism. 410 0$aTopics in Organometallic Chemistry,$x1436-6002 ;$v63 606 $aCatalysis 606 $aGreen chemistry 606 $aOrganometallic chemistry 606 $aChemical engineering 606 $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000 606 $aGreen Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C35000 606 $aOrganometallic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19020 606 $aIndustrial Chemistry/Chemical Engineering$3https://scigraph.springernature.com/ontologies/product-market-codes/C27000 615 0$aCatalysis. 615 0$aGreen chemistry. 615 0$aOrganometallic chemistry. 615 0$aChemical engineering. 615 14$aCatalysis. 615 24$aGreen Chemistry. 615 24$aOrganometallic Chemistry. 615 24$aIndustrial Chemistry/Chemical Engineering. 676 $a547.05 676 $a661.895 702 $aDixneuf$b P. H$g(Pierre H.),$4edt$4http://id.loc.gov/vocabulary/relators/edt 702 $aSoulé$b Jean-François$4edt$4http://id.loc.gov/vocabulary/relators/edt 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910767572303321 996 $aOrganometallics for Green Catalysis$91570110 997 $aUNINA