LEADER 00975nam--2200349---450- 001 990001659100203316 005 20051017085237.0 035 $a000165910 035 $aUSA01000165910 035 $a(ALEPH)000165910USA01 035 $a000165910 100 $a20040513d1941----km-y0itay0103----ba 101 0 $alat 102 $aIT 105 $a||||||||001yy 200 1 $a<> Opere$fQuinto Orazio Flacco$gtesto latino e versione poetica di Umberto Moricca 210 $aNapoli$cPironti$d1941 215 $a758 p.$d23 cm. 410 0$12001 454 1$12001 461 1$1001-------$12001 700 1$aHORATIUS FLACCUS,$bQuintus$075513 702 1$aMORICCA,$bUmberto 801 0$aIT$bsalbc$gISBD 912 $a990001659100203316 951 $aV.3.A. 204(VIII A 584)$b50075 L.M.$cVIII A 959 $aBK 969 $aUMA 979 $aSIAV8$b10$c20040513$lUSA01$h1311 979 $aCOPAT6$b90$c20051017$lUSA01$h0852 996 $aOpere$953774 997 $aUNISA LEADER 04435nam 22007695 450 001 9910760268703321 005 20240312132844.0 010 $a3-031-40534-X 024 7 $a10.1007/978-3-031-40534-1 035 $a(MiAaPQ)EBC30826735 035 $a(Au-PeEL)EBL30826735 035 $a(DE-He213)978-3-031-40534-1 035 $a(PPN)272915564 035 $a(CKB)28552912100041 035 $a(EXLCZ)9928552912100041 100 $a20231026d2024 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aEfficient Control and Spontaneous Transitions /$fby Miranda Louwerse 205 $a1st ed. 2024. 210 1$aCham :$cSpringer Nature Switzerland :$cImprint: Springer,$d2024. 215 $a1 online resource (123 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 311 08$aPrint version: Louwerse, Miranda Efficient Control and Spontaneous Transitions Cham : Springer International Publishing AG,c2023 9783031405334 327 $aChapter 1: Introduction -- Chapter 2: Theoretical Background -- Chapter 3: Information Thermodynamics of Transition Paths -- Chapter 4: Multidimensional Minimum-Work Protocols -- Chapter 5: Connections between Minimum-Work Protocols and Transition Paths -- Chapter 6 Conclusions. 330 $aThis thesis addresses deep questions that cut to the physical and informational essence of central chemical quantities such as transition paths and reaction mechanisms and proposes fundamental new connections between transition-path theory, linear-response theory, nonequilibrium thermodynamics, and information theory. The author investigates slow, energetically efficient driving protocols that drive a system between conformations corresponding to endpoints of a reaction, aiming to find connections between principles of efficient driving and the spontaneous transition mechanism in the absence of driving. First, an alternative perspective of transition-path theory is developed that unifies it with stochastic thermodynamics to describe flows of entropy, energy, and information during the reaction. This also provides an optimization criterion for selecting collective variables. Next, protocols are designed which invert the magnetization of a 3×3 Ising model with minimal energetic cost,and it is determined that using multiple control parameters allows the system to be driven along a fast-relaxing pathway between reaction endpoints. Finally, the author compares these protocols with the spontaneous transition mechanism for magnetization inversion in the same Ising model, finding that designed protocols capture general features of the spontaneous mechanism and energetics given the constraints on the control parameters. This work represents a major step forward in our understanding of rare events and provides a basis for investigating the connection between efficient protocols and spontaneous transition mechanisms which can be further probed in a wider variety of systems. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 606 $aThermodynamics 606 $aBiophysics 606 $aBiomolecules 606 $aBiochemistry 606 $aReaction mechanisms (Chemistry) 606 $aCoding theory 606 $aInformation theory 606 $aCondensed matter 606 $aThermodynamics 606 $aMolecular Biophysics 606 $aBiochemistry 606 $aReaction Mechanisms 606 $aCoding and Information Theory 606 $aPhase Transitions and Multiphase Systems 615 0$aThermodynamics. 615 0$aBiophysics. 615 0$aBiomolecules. 615 0$aBiochemistry. 615 0$aReaction mechanisms (Chemistry) 615 0$aCoding theory. 615 0$aInformation theory. 615 0$aCondensed matter. 615 14$aThermodynamics. 615 24$aMolecular Biophysics. 615 24$aBiochemistry. 615 24$aReaction Mechanisms. 615 24$aCoding and Information Theory. 615 24$aPhase Transitions and Multiphase Systems. 676 $a547.2 700 $aLouwerse$b Miranda$01438303 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910760268703321 996 $aEfficient Control and Spontaneous Transitions$93599594 997 $aUNINA