LEADER 03884nam 22006255 450 001 9910741147903321 005 20230821181950.0 010 $a981-9945-10-0 024 7 $a10.1007/978-981-99-4510-8 035 $a(MiAaPQ)EBC30717197 035 $a(Au-PeEL)EBL30717197 035 $a(DE-He213)978-981-99-4510-8 035 $a(PPN)272262994 035 $a(CKB)28011015900041 035 $a(EXLCZ)9928011015900041 100 $a20230821d2023 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aInvestigations into the Combustion Kinetics of Several Novel Oxygenated Fuels /$fby Wenyu Sun 205 $a1st ed. 2023. 210 1$aSingapore :$cSpringer Nature Singapore :$cImprint: Springer,$d2023. 215 $a1 online resource (178 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 311 08$aPrint version: Sun, Wenyu Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels Singapore : Springer,c2023 9789819945092 327 $aIntroduction -- Experimental and kinetic modeling methods -- High-temperature kinetics of carbonate and ketone fuels -- Low-temperature oxidation kinetics of polyether fuels -- Addition effects of oxygenated fuels on hydrocarbon premixed flames -- Conclusions and perspective. 330 $aIn this thesis, attention was paid to several novel oxygenated fuels?carbonates, polyethers and ketones. Combustion kinetic investigations were performed for typical representative compounds, including dimethyl carbonate, diethyl carbonate, cyclopentanone, 3-pentanone, 1,2-dimethoxyethane and dimethoxymethane. For experiments, suitable diagnostic techniques were used to measure the detailed speciation information of the target fuels under different conditions. For kinetic modeling, rate coefficients for crucial elementary reactions were obtained through high-level theoretical calculations. Based on that, validated kinetic models with good predictive performances were developed. On the basis of experimental measurements and model interpretations, this work highlighted two important combustion characteristics regarding the practical use: the pollutant formation and the ignition performance. Besides, the correlation between oxygen-containing functional groups and the aforementioned combustion characteristics was revealed. To reveal the potential interactions between the reaction networks of oxygenated additives and the hydrocarbon base fuels during combustion. Chemical structures of laminar premixed flames fueled by binary fuels were measured, and by changing the initial fuel compositions, the addition effects of the oxygenates on the fuel consumption and pollutant formation behaviors were explored. It was found that complicated chemical interactions do not exist in the reaction networks under the investigated conditions. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 606 $aMaterials 606 $aCatalysis 606 $aForce and energy 606 $aMass spectroscopy 606 $aChemical kinetics 606 $aMaterials for Energy and Catalysis 606 $aMass Spectrometry 606 $aReaction Kinetics 615 0$aMaterials. 615 0$aCatalysis. 615 0$aForce and energy. 615 0$aMass spectroscopy. 615 0$aChemical kinetics. 615 14$aMaterials for Energy and Catalysis. 615 24$aMass Spectrometry. 615 24$aReaction Kinetics. 676 $a620.1 700 $aSun$b Wenyu$01424482 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910741147903321 996 $aInvestigations into the Combustion Kinetics of Several Novel Oxygenated Fuels$93553664 997 $aUNINA