LEADER 05033nam 2200661 450 001 9910132344203321 005 20200520144314.0 010 $a3-527-66418-1 010 $a3-527-66416-5 010 $a3-527-66419-X 035 $a(CKB)3710000000222911 035 $a(EBL)1767040 035 $a(SSID)ssj0001400180 035 $a(PQKBManifestationID)11833582 035 $a(PQKBTitleCode)TC0001400180 035 $a(PQKBWorkID)11459040 035 $a(PQKB)11671108 035 $a(OCoLC)891398199 035 $a(MiAaPQ)EBC1767040 035 $a(Au-PeEL)EBL1767040 035 $a(CaPaEBR)ebr10909194 035 $a(CaONFJC)MIL637256 035 $a(OCoLC)888352800 035 $a(PPN)184618444 035 $a(EXLCZ)993710000000222911 100 $a20140901h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aBioinspired catalysis $emetal-sulfur complexes /$fedited by Wolfgang Weigand and Philippe Schollhammer ; contributors Ulf-Peter Apfel [and thirty three others] 210 1$aWeinheim, Germany :$cWiley-VCH,$d2015. 210 4$d©2015 215 $a1 online resource (438 p.) 300 $aDescription based upon print version of record. 311 $a3-527-33308-8 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aBioinspired Catalysis; Contents; List of Contributors; Preface; Part I Primordial Metal-Sulfur-Mediated Reactions; Chapter 1 From Chemical Invariance to Genetic Variability; 1.1 Heuristic of Biochemical Retrodiction; 1.2 Retrodicting the Elements of Life; 1.3 Retrodicting Pioneer Catalysis; 1.4 Retrodicting Metabolic Reproduction and Evolution; 1.5 Retrodicting Pioneer-Metabolic Reactions; 1.6 Early Evolution in a Spatiotemporal Flow Context; Acknowledgments; References; Chapter 2 Fe-S Clusters: Biogenesis and Redox, Catalytic, and Regulatory Properties; 2.1 Introduction 327 $a2.2 Fe-S Cluster Biogenesis and Trafficking2.3 Redox Properties of Fe-S Clusters; 2.4 Fe-S Clusters and Catalysis; 2.4.1 Redox Catalysis; 2.4.2 Nonredox Fe-S Cluster-Based Catalysis; 2.5 Fe-S Clusters and Oxidative Stress; 2.6 Regulation of Protein Expression by Fe-S Clusters; 2.6.1 Eukaryotic Iron Regulatory Protein 1 (IRP1); 2.6.1.1 IRP1 and Fe-S Cluster Biogenesis; 2.6.1.2 Reactive Oxygen Species and IRP1 Fe-S Cluster Stability; 2.6.1.3 X-Ray Structural Studies of IRP1-IRE Complexes; 2.6.2 Bacterial Fumarate Nitrate Reduction Regulator (FNR); 2.6.3 The ISC Assembly Machinery Regulator IscR 327 $a2.7 ConclusionReferences; Part II Model Complexes of the Active Site of Hydrogenases - Proton and Dihydrogen Activation; Chapter 3 [NiFe] Hydrogenases; 3.1 Introduction; 3.2 Introduction to [NiFe] Hydrogenases; 3.3 Nickel Thiolate Complexes as Analogs of [NiFe] Hydrogenase; 3.4 [NiFe] Hydrogenase Model Complexes; 3.4.1 Amine [N2Ni(?-S2)Fe] Complexes; 3.4.2 Phosphine [P2Ni(?-S2)Fe] Complexes; 3.4.3 Thiolate [SxNi(?-Sy)Fe] Complexes; 3.4.4 Polymetallic [Ni(?-S)zFey] Complexes; 3.5 Analogs of [NiFe] Hydrogenase Incorporating Proton Relays; 3.5.1 Nickel Complexes Incorporating Protonation Sites 327 $a3.5.2 [NiFe] Complexes Incorporating Protonation Sites3.6 Perspectives and Future Challenges; Acknowledgments; References; Chapter 4 [FeFe] Hydrogenase Models: an Overview; 4.1 Introduction; 4.2 Synthetic Strategies toward [FeFe] Hydrogenase Model Complexes; 4.3 Properties of Model Complexes; 4.3.1 Biomimetic Models of the ""Rotated State""; 4.3.2 Electron Transfer in [FeFe] Hydrogenase Models; 4.3.3 Protonation Chemistry of [FeFe] Hydrogenase Models; 4.3.3.1 Hydride Formation; 4.3.3.2 Ligand Protonation and Proton Relays; 4.3.4 Water-Soluble Hydrogenase Mimics; 4.4 Conclusion; References 327 $aChapter 5 The Third Hydrogenase5.1 Introduction; 5.2 Initial Studies of Hmd; 5.3 Discovery that Hmd Contains a Bound Cofactor; 5.4 Discovery that Hmd is a Metalloenzyme; 5.5 Crystal Structure Studies of [Fe] Hydrogenase; 5.6 Mechanistic Models of [Fe] Hydrogenase; 5.6.1 Studies Before the Most Recent Assignment of the FeGP Cofactor; 5.6.2 Studies After the Most Recent Assignment of the FeGP Cofactor; 5.6.3 Synthesized Model Complexes of the FeGP Cofactor; References; Chapter 6 DFT Investigation of Models Related to the Active Site of Hydrogenases; 6.1 Introduction 327 $a6.2 QM Studies of Hydrogenases 330 $aThis book provides an overview of bioinspired metal-sulfur catalysis by covering structures, activities and model complexes of enzymes exhibiting metal sulphur moieties in their active center. 606 $aMetal complexes 615 0$aMetal complexes. 676 $a541.2242 702 $aWeigand$b Wolfgang 702 $aSchollhammer$b Philippe 702 $aApfel$b Ulf-Peter 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910132344203321 996 $aBioinspired catalysis$92113792 997 $aUNINA LEADER 03678nam 22006375 450 001 9910735776203321 005 20251008140652.0 010 $a9783031268410 010 $a3031268415 024 7 $a10.1007/978-3-031-26841-0 035 $a(MiAaPQ)EBC30666735 035 $a(Au-PeEL)EBL30666735 035 $a(DE-He213)978-3-031-26841-0 035 $a(PPN)27225553X 035 $a(CKB)27861150000041 035 $a(OCoLC)1392346870 035 $a(MiFhGG)9783031268410 035 $a(EXLCZ)9927861150000041 100 $a20230725d2023 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 12$aA Brief History of Mathematics $eA Promenade through the Civilizations of Our World /$fby Tianxin Cai 205 $a1st ed. 2023. 210 1$aCham :$cSpringer International Publishing :$cImprint: Birkhäuser,$d2023. 215 $a1 online resource (353 pages) 311 08$aPrint version: Cai, Tianxin A Brief History of Mathematics Cham : Springer International Publishing AG,c2023 9783031268403 327 $a1. The Middle East, or the Beginning -- 2. The Sages of Ancient Greece -- 3. The Chinese Middle Ages -- 4. India and Persia -- 5. From the Renaissance to the Birth of Calculus -- 6. The Age of Analysis and the French Revolution -- 7. Modern Mathematics, Modern Art -- 8. Abstraction: Mathematics Since the Twentieth Century. 330 $aThis volume, originally published in China and translated into four other languages, presents a fascinating and unique account of the history of mathematics, divided into eight chronologically organized chapters. Tracing the development of mathematics across disparate regions and peoples, with particular emphasis on the relationship between mathematics and civilization, it examines mathematical sources and inspirations leading from Egypt, Babylon and ancient Greece and expanding to include Chinese, Indian and Arabic mathematics, the European Renaissance and the French revolution up through the Nineteenth and Twentieth Centuries. Each chapter explores connections among mathematics and cultural elements of the time and place treated, accompanying the reader in a varied and exciting journey through human civilizations. The book contemplates the intersections of mathematics with other disciplines, including the relationship between modern mathematics and modern art, and the resultingapplications, with the aid of images and photographs, often taken by the author, which further enhance the enjoyment for the reader. Written for a general audience, this book will be of interest to anyone who's studied mathematics in university or even high school, while also benefiting researchers in mathematics and the humanities. . 606 $aMathematics 606 $aHistory 606 $aSocial sciences 606 $aArts 606 $aArchitecture$xMathematics 606 $aHistory of Mathematical Sciences 606 $aMathematics in the Humanities and Social Sciences 606 $aMathematics in Art and Architecture 615 0$aMathematics. 615 0$aHistory. 615 0$aSocial sciences. 615 0$aArts. 615 0$aArchitecture$xMathematics. 615 14$aHistory of Mathematical Sciences. 615 24$aMathematics in the Humanities and Social Sciences. 615 24$aMathematics in Art and Architecture. 676 $a510.9 700 $aCai$b Tianxin$01378519 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910735776203321 996 $aA Brief History of Mathematics$93417124 997 $aUNINA