LEADER 03085nam 2200409 450 001 9910688182703321 005 20230704075121.0 035 $a(CKB)5580000000514557 035 $a(NjHacI)995580000000514557 035 $a(EXLCZ)995580000000514557 100 $a20230704d2022 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aPhase equilibria with supercritical carbon dioxide $eapplication to the components of a biocatalytic process /$fedited by Mercedes G. Montalba?n, Gloria Vi?llora 210 1$aLondon :$cIntechOpen,$d2022. 215 $a1 online resource (74 pages) 311 $a1-80356-505-5 327 $aTable of Contents -- OPEN ACCESS -- CHAPTERS 1. Supercritical Fluids: Properties and Applications By Mercedes G. Montalba?n and Gloria Vi?llora 53 VIEW ABSTRACT -- 2. High-Pressure Fluid Phase Equilibria By Mercedes G. Montalba?n and Gloria Vi?llora 17 VIEW ABSTRACT -- 3. Application of Supercritical Phase Equilibria to the Components of the Transesterification Reaction of rac-2-Pentanol with a Vinyl Ester By Mercedes G. Montalba?n and Gloria Vi?llora 9 VIEW ABSTRACT. 330 $aWe are living in a critical time, both for humanity and the planet, which has led us to look for more sustainable formulas to interact with the environment. One of the important changes in the design and operation of chemical processes is the search for environmentally friendly technologies. Supercritical carbon dioxide has been revealed as a promising environmentally friendly solvent that is energy efficient, selective and capable of reducing waste, making it a promising alternative to conventional organic solvents. However, reliable and versatile mathematical models of phase equilibrium thermodynamics are needed for the use of supercritical carbon dioxide in process design and viability studies. This book reviews experimental procedures for obtaining high-pressure phase equilibria data and describes the phase diagrams of binary mixtures and some thermodynamic models capable of determining the conditions of phase equilibria at high pressures. These concepts are applied to the components of the transesterification reaction of rac-2-pentanol with a vinyl ester, which is important in the pharmaceutical industry because (S)-2-pentanol can be obtained as a reaction product. This product is a key intermediate in the synthesis of drugs against Alzheimer's disease. 606 $aLiquid carbon dioxide 606 $aPhase transformations (Statistical physics) 606 $aSupercritical fluid extraction 615 0$aLiquid carbon dioxide. 615 0$aPhase transformations (Statistical physics) 615 0$aSupercritical fluid extraction. 676 $a660.284248 702 $aMontalba?n$b Mercedes G. 702 $aVi?llora$b Gloria 801 0$bNjHacI 801 1$bNjHacl 906 $aBOOK 912 $a9910688182703321 996 $aPhase Equilibria With Supercritical Carbon Dioxide$93136013 997 $aUNINA