LEADER 05316nam 2200649Ia 450 001 9910672322703321 005 20170810191303.0 010 $a1-281-04754-6 010 $a9786611047542 010 $a0-08-053565-8 035 $a(CKB)1000000000357578 035 $a(EBL)313990 035 $a(OCoLC)476104750 035 $a(SSID)ssj0000194724 035 $a(PQKBManifestationID)12028978 035 $a(PQKBTitleCode)TC0000194724 035 $a(PQKBWorkID)10232898 035 $a(PQKB)10718480 035 $a(MiAaPQ)EBC313990 035 $a(PPN)182569594 035 $a(EXLCZ)991000000000357578 100 $a19971010d1997 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aLow-temperature combustion and autoignition$b[electronic resource] /$fM.J. Pilling (editor) 210 $aAmsterdam ;$aNew York $cElsevier$d1997 215 $a1 online resource (823 p.) 225 1 $aComprehensive chemical kinetics ;$vv. 35 300 $aDescription based upon print version of record. 311 $a0-444-82485-5 320 $aIncludes bibliographical references and indexes. 327 $aFront Cover; LOW-TEMPERATURE COMBUSTION AND AUTOIGNITION; Copyright Page; Contents; Introduction; Chapter 1. Basic chemistry of combustion; 1.1 Historical perspective; 1.2 Characteristics of low-temperature combustion; 1.3 Computer modelling and associated problems; 1.4 Overview of alkane oxidation; 1.5 Review of experimental methods for establishing mechanisms and determining rate constants; 1.6 Primary initiation reactions; 1.7 Propagation reaction X + RH -> XH + R (2); 1.8 Homolysis of alkyl radicals; 1.9 The reaction of alkyl radicals with O2; 1.10 Reactions of RO2 radicals 327 $a1.11 Reactions of QOOH and QOOHO2 radicals1.12 Oxidation chemistry of CH3 radicals; 1.13 Reactions of alkoxy radicals; 1.14 Branching reactions; 1.15 Oxidation of cyclic alkanes; 1.16 Oxidation of alkenes; 1.17 Atom and radical addition to alkenes; 1.18 Oxidation of oxygenated compounds; 1.19 Oxidation of aromatic compounds; 1.20 Conclusions; References; Chapter 2. Elementary reactions; 2.1 Introduction; 2.2 Reaction initiation; 2.3 Abstraction reactions; 2.4 Radical decomposition reactions; 2.5 Radical recombination and association reactions; 2.6 R + O2 - RO2 327 $a2.7 Peroxy radical isomerization2.8 Theoretical and dynamical studies of the hydrogen/oxygen system; References; Chapter 3. Kinetics databases; 3.1 Data for combustion modelling; 3.2 Primary sources of kinetic data: the need for evaluation; 3.3 Evaluation of kinetic data; 3.4 Interpolation, extrapolation and estimation procedures; 3.5 Data sources for modelling; References; Chapter 4. Mathematical tools for the construction, investigation and reduction of combustion mechanisms; 4.1 Introduction; 4.2 Notation; 4.3 The construction of combustion mechanisms 327 $a4.4 Numerical investigation of complex models4.5 Sensitivity and uncertainty analysis; 4.6 Mechanism reduction without time-scale analysis; 4.7 Formal lumping procedures; 4.8 Reduction based on the investigation of time-scales; 4.9 Approximate lumping in systems with time-scale separation; 4.10 Fitted kinetic models; 4.11 Conclusions and future directions; Chapter 5. Global behaviour in the oxidation of hydrogen, carbon monoxide and simple hydrocarbons; 5.1 Introduction; 5.2 Notation; 5.3 Non-linearity and feedback in chemical kinetics: stoichiometry and elementary steps 327 $a5.4 Chemical feedback: branched-chain ignition5.5 Thermal feedback: ignition, extinction and singularity theory; 5.6 Thermokinetic feedback: oscillations and local stability analysis; 5.7 The H2 + O2 reaction: p-Ta ignition limits in closed vessels; 5.8 Flow reactor studies of the H2 + O2 reaction; 5.9 Complexity in the oscillatory ignition region; 5.10 Mechanistic modelling of complexity in the H2 + O2 reaction; 5.11 The CO + O2 reaction; 5.12 Hydrocarbon oxidation; 5.13 Conclusions and future directions; References 327 $aChapter 6. Experimental and numerical studies of oxidation chemistry and spontaneous ignition phenomena 330 $aCombustion has played a central role in the development of our civilization which it maintains today as its predominant source of energy. The aim of this book is to provide an understanding of both fundamental and applied aspects of low-temperature combustion chemistry and autoignition. The topic is rooted in classical observational science and has grown, through an increasing understanding of the linkage of the phenomenology to coupled chemical reactions, to quite profound advances in the chemical kinetics of both complex and elementary reactions. The driving force has been both the intrinsic 410 0$aComprehensive chemical kinetics ;$vv. 35. 606 $aCombustion 606 $aThermochemistry 615 0$aCombustion. 615 0$aThermochemistry. 676 $a541.3/94 s 541.3/61 21 676 $a541.3686 676 $a541.394 s541.361 701 $aPilling$b M. J$01336698 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910672322703321 996 $aLow-temperature combustion and autoignition$93054134 997 $aUNINA