LEADER 05404nam 2200601 a 450 001 9910643190103321 005 20230213214446.0 010 $a1-282-81745-0 010 $a9786612817458 010 $a0-470-93841-2 010 $a0-470-93840-4 035 $a(CKB)2670000000048470 035 $a(EBL)624392 035 $a(OCoLC)670429737 035 $a(SSID)ssj0000419149 035 $a(PQKBManifestationID)11299202 035 $a(PQKBTitleCode)TC0000419149 035 $a(PQKBWorkID)10382102 035 $a(PQKB)11270984 035 $a(MiAaPQ)EBC624392 035 $a(EXLCZ)992670000000048470 100 $a19860220d1986 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aHandbook of aqueous electrolyte thermodynamics$b[electronic resource] $etheory & application /$fJoseph F. Zemaitis, Jr. ... [et al.] 210 $aNew York, N.Y. $cDesign Institute for Physical Property Data sponsored by the American Institute of Chemical Engineers$dc1986 215 $a1 online resource (876 p.) 300 $aDescription based upon print version of record. 311 $a0-8169-0350-6 320 $aIncludes bibliographical references and index. 327 $aHandbook of Aqueous Electrolyte Thermodynamics Theory & Application; TABLE OF CONTENTS; I INTRODUCTION; II THERMODYNAMICS OF SOLUTIONS; Basic Thermodynamic Functions; Solutions - Basic Definitions and Concepts; Equilibrium - Necessary Conditions; Activities, Activity Coefficients and Standard States; III EQUILIBRIUM CONSTANTS; Ionic and/or Reaction Equilibrium in Aqueous Solutions; Solubility Equilibria Between Crystals and Saturated Solutions; Vapor-Liquid Equilibria in Aqueous Solutions; Temperature Effects on the Equilibrium Constant 327 $aEstimating Temperature Effects on Heat Capacity and Other Thermodynamic PropertiesEquilibrium Constants from Tabulated Data; Pressure Effects on the Equilibrium Constant; Appendix 3.1 - Criss and Cobble Parameters; IV ACTIVITY COEFFICIENTS OF SINGLE STRONG ELECTROLYTES; History; Limitations and Improvements to the Debye-Huckel Limiting Law; Further Refinements; Bromley's Method; Meissner's Method; Pitzer's Method; Chen's Method; Short Range Interaction Model; Long Range Interaction Model; Temperature Effects; Bromley's Method; Meissner's Method; Pitzer's Method; Chen's Method; Application 327 $aBromley's MethodMeissner's Method; Pitzer's Method; Chen's Method; NBS Smoothed Experimental Data; Test Cases:; HCl; KCl; KOH; NaCl; NaOH; CaCl2; Na2SO4; MgSO4; Bromley's Extended Equation; MgSO4 Test Case; Comparison of Temperature Effect Methods; Bromley; Meissner; Pitzer and Chen; Experimental Data; Test Cases:; HCl at 50° Celsius; KCl at 80° Celsius; KOH at 80° Celsius; NaCl at 100 and 300° Celsius; NaOH at 35° Celsius; CaCl2 at 108.85 and 201.85° Celsius; Na2SO4 at 80° Celsius; MgSO4 at 80° Celsius; Appendix 4.1 - Values for Guggenheim's ? Parameter 327 $aTable 1: ? Values for Uni-univalent ElectrolytesTable 2: ? and B Values of Bi-univalent and Uni-bivalent Electrolytes from Freezing Points; Methods for Calculating ?; Appendix 4.2 - Bromley Interaction Parameters; Table 1: B Values at 25°C Determined by the Method of Least Squares on Log ? to I=6.0 (or less if limited data); Table 2: Individual Ion Values of B and ? in Aqueous Solutions at 25°C; Table 3: Bivalent Metal Sulfates at 25°C; Appendix 4.3 - Meissner Parameters; Table: Average Values of Parameter q in Equation (4.46) for Selected Electrolytes; Appendix 4.4 - Pitzer Parameters 327 $aTable 1: Inorganic Acids, Bases and Salts of 1-1 TypeTable 2: Salts of Carboxylic Acids (1-1 Type); Table 3: Tetraalkylammonium Halides; Table 4: Sulfonic Acids and Salts (1-1 Type); Table 5: Additional 1-1 Type Organic Salts; Table 6: Inorganic Compounds of 2-1 Type; Table 7: Organic Electrolytes of 2-1 Type; Table 8: 3-1 Electrolytes; Table 9: 4-1 Electrolytes; Table 10: 5-1 Electrolytes; Table 11: 2-2 Electrolytes; Appendix 4.5 - Pitzer Parameter Derivatives; Table 1: Temperature Derivatives of Parameters for 1-1 Electrolytes Evaluated from Calorimetric Data 327 $aTable 2: Temperature Derivatives of Parameters for 2-1 and 1-2 Electrolytes Evaluated from Calorimetric Data 330 $aExpertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable ""do-it-yourself"" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful resea 606 $aElectrolytes$xThermal properties 615 0$aElectrolytes$xThermal properties. 676 $a541.3/746 676 $a541.3746 701 $aZemaitis$b Joseph F.$fb. 1940.$0986789 712 02$aAmerican Institute of Chemical Engineers. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910643190103321 996 $aHandbook of aqueous electrolyte thermodynamics$92255234 997 $aUNINA