LEADER 04873nam 2200457 450 001 9910583094403321 005 20180603084525.0 010 $a0-12-813835-1 010 $a0-12-813834-3 035 $a(CKB)4100000000449568 035 $a(MiAaPQ)EBC5041614 035 $a(PPN)226416194 035 $a(EXLCZ)994100000000449568 100 $a20171012h20182018 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aReactivity of P-H group of phosphorus based compounds /$fKolio D. Troev 210 1$aLondon, [England] :$cAcademic Press,$d2018. 210 4$d©2018 215 $a1 online resource (465 pages) 311 08$aOnline version: Troev, Kolio D., author. Reactivity of P-H group of phosphorus based compounds. London, United Kingdom : Academic Press, [2018] 9780128138359 (OCoLC)1003284632 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aFront Cover; Reactivity of P-H Group of Phosphorus Based Compounds; Copyright Page; Contents; About the Author; Preface; 1 Acidity and Tautomerization of P-H Group; 1.1 Acidity; 1.2 Tautomerization; 1.2.1 Tautomerization of Phosphine Oxides; 1.2.2 Tautomerization of Hypophosphorous Acid; 1.2.3 Tautomerization of H-Phosphinic Acid; 1.2.4 Tautomerization of H-Phosphonic Acid; References; 2 Reactivity of P-H Group of Phosphines; 2.1 Phosphine; 2.1.1 Methods for Preparation; 2.1.2 Reactivity of P-H Group; 2.1.2.1 Reaction with Metals; 2.1.2.2 Addition Reactions 327 $a2.1.2.2.1 Addition to Carbon-Carbon Multiple BondsRadical Addition; Nucleophilic Addition; Catalyzed Hydrophosphination; 2.1.2.2.2 Addition to Carbonyl Group; 2.1.2.3 Nucleophilic Substitution Reactions; 2.2 Primary Phosphines (RPH2); 2.2.1 Methods for Preparation; 2.2.2 Reactivity of P-H Group; 2.2.2.1 Addition Reactions; 2.2.2.1.1 Addition to Carbon-Carbon Multiple Bonds; 2.2.2.1.2 Addition to Carbonyl Group; 2.2.2.2 Cross-Coupling Reactions; 2.2.2.3 Cross-Dehydrogenative Coupling; 2.3 Primary Diphosphines; 2.3.1 Methods for Preparation; 2.3.2 Reactivity of P-H Group; 2.3.2.1 Metalation 327 $a2.5.2 Reactivity of P-H Group2.5.2.1 Condensation Reactions; 2.5.2.2 Cross-Coupling Reactions; 2.5.2.2.1 Diphenyldiphosphine PhHP-PHPh; 2.5.2.2.2 Tetraphenyldiphosphane; 2.6 Phosphine-Borane Complexes; 2.6.1 Phosphine-Borane; 2.6.1.1 Methods for Preparation; 2.6.2 Primary Phosphine-Boranes; 2.6.2.1 Methods for Preparation; 2.6.2.2 Reactivity of P-H Group; 2.6.2.2.1 Hydrophosphination; 2.6.2.2.2 Oxidative Addition; 2.6.2.2.3 Cross-Dehydrogenative Coupling; 2.6.2.2.4 Alkylation; 2.6.3 Secondary Phosphine-Boranes; 2.6.3.1 Methods for Preparation; 2.6.3.2 Reactivity of P-H Group 327 $a2.6.3.2.1 Alkylation2.6.3.2.2 Hydrophosphination; 2.6.3.2.3 Nucleophilic Substitutions; 2.6.3.2.4 Cross-Coupling Reactions; 2.6.3.2.5 Cross-Dehydrogenative Coupling; Poly(phosphinoborane)s; 2.7 Conclusion; References; 3 Reactivity of P-H Group of Phosphine Oxides; 3.1 Phosphine Oxide; 3.1.1 Methods for Preparation; 3.1.2 Reactivity of P-H Group; 3.2 Primary Phosphine Oxides; 3.2.1 Methods for Preparation; 3.2.2 Reactivity of P-H Group; 3.2.2.1 Dehydration; 3.2.2.2 Addition Reactions; 3.2.2.2.1 Addition to Carbon-Carbon Multiple Bonds; 3.3 Secondary Phosphine Oxides 330 $aReactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate). This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification. 606 $aPhosphorus compounds 615 0$aPhosphorus compounds. 676 $a546.712 700 $aTroev$b Kolio D.$0897328 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910583094403321 996 $aReactivity of P-H group of phosphorus based compounds$92004735 997 $aUNINA LEADER 00695nam 2200253zu 450 001 9911023998103321 005 20250911150752.0 024 7 $a10.35985/9786287501614 035 $a(CKB)40916411500041 035 $a(EXLCZ)9940916411500041 100 $a20250911|2021uuuu || | 101 0 $aspa 135 $aur||||||||||| 200 10$aHablando de Marketing 210 $cUniversidad Santiago de Cali$d2021 215 $a1 electronic resource (364 p.) 311 08$a9786287501614 606 $aEconomía 615 7$aEconomía. 700 $aBurbano Cerón$b José María$01847384 906 $aBOOK 912 $a9911023998103321 996 $aHablando de Marketing$94432956 997 $aUNINA