LEADER 04279nam 2201069z- 450 001 9910557556003321 005 20210501 035 $a(CKB)5400000000044046 035 $a(oapen)https://directory.doabooks.org/handle/20.500.12854/69132 035 $a(oapen)doab69132 035 $a(EXLCZ)995400000000044046 100 $a20202105d2020 |y 0 101 0 $aeng 135 $aurmn|---annan 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aRecent Advances in Iron Catalysis 210 $aBasel, Switzerland$cMDPI - Multidisciplinary Digital Publishing Institute$d2020 215 $a1 online resource (224 p.) 311 08$a3-03943-118-8 311 08$a3-03943-119-6 330 $aTransition metal-catalyzed reactions play a key role in many transformations of synthetic organic chemistry. For most of these reactions, noble metals, for example, palladium, have been used as catalysts. Over the last two decades, more and more first row transition metals have been applied as catalysts for organic reactions, with iron taking the center stage. The driving forces behind this development are not only the high costs for the noble metals but also their toxicity. Iron is the most abundant transition metal in the Earth's crust, and thus, it is considerably cheaper than the precious noble metals. Moreover, iron compounds are involved in many biological processes, and thus, iron exhibits a low toxicity. Because of this low toxicity, iron-catalyzed reactions are important for an environmentally benign sustainable chemistry. However, iron catalysts are not only investigated to replace noble metals; they offer many applications in synthesis beyond those of classical noble metal catalysts. Several articles of the present book emphasize the complementarity of iron-catalyzed reactions as compared to reactions catalyzed by noble metals. The book shows intriguing recent developments and the current standing of iron-catalyzed reactions as well as applications to organic synthesis. 606 $aResearch & information: general$2bicssc 610 $aalcohols 610 $aaldehyde 610 $aalkenyl halides 610 $aalkylation 610 $aamidation 610 $aamides 610 $aamines 610 $aaryl esters 610 $aasymmetric catalysis 610 $aasymmetric transfer hydrogenation 610 $aate iron(II) complex 610 $aATRP 610 $abifunctional catalyst 610 $aBINOL synthesis 610 $abis-(aryl)manganese 610 $aborylation 610 $aC-C coupling 610 $aC-H activation 610 $aC-H functionalisation 610 $aC-H functionalization 610 $aC-O activation 610 $acarbene 610 $acarboazidation 610 $acatalysis 610 $acinnamamide 610 $acontrolled radical polymerization 610 $across-coupling 610 $adecarbonylation 610 $adehydrogenative coupling 610 $adensity functional theory 610 $aDFT 610 $adiazoalkane 610 $aesters 610 $aexternal stimuli 610 $aFe-catalysis 610 $aFeI/FeII/FeIII mechanism 610 $afluorescence 610 $aGrignard reagent 610 $ahaloalkane coupling 610 $ahydrogen transfer 610 $airon 610 $aIron 610 $airon catalysis 610 $airon catalyst 610 $airon complexes 610 $airon-catalysis 610 $airon(III) chloride 610 $aKumada cross-coupling 610 $anaphthidines 610 $anitrogen ligand 610 $aorganic synthesis 610 $aoxidative coupling 610 $aphotochemistry 610 $apinacolborane 610 $aradical 610 $areductive amination 610 $asolvent-free 610 $aspirocyclization 610 $asustainability 610 $a?-alkenylation 610 $a?-methyl scission 615 7$aResearch & information: general 700 $aKnölker$b Hans-Joachim$4edt$01312711 702 $aKnölker$b Hans-Joachim$4oth 906 $aBOOK 912 $a9910557556003321 996 $aRecent Advances in Iron Catalysis$93030943 997 $aUNINA