LEADER 03515nam 2200793z- 450 001 9910557344803321 005 20231214133502.0 035 $a(CKB)5400000000042443 035 $a(oapen)https://directory.doabooks.org/handle/20.500.12854/76576 035 $a(EXLCZ)995400000000042443 100 $a20202201d2021 |y 0 101 0 $aeng 135 $aurmn|---annan 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aNanoscale Thermodynamics 210 $aBasel, Switzerland$cMDPI - Multidisciplinary Digital Publishing Institute$d2021 215 $a1 electronic resource (168 p.) 311 $a3-0365-1168-7 311 $a3-0365-1169-5 330 $aThis Special Issue concerns the development of a theory for energy conversion on the nanoscale, namely, nanothermodynamics. The theory has been applied to porous media, small surfaces, clusters or fluids under confinement. The number of unsolved issues in these contexts is numerous and the present efforts are only painting part of the broader picture. We attempt to answer the following: How far down in scale does the Gibbs equation apply? Which theory can replace it beyond the thermodynamic limit? It is well known that confinement changes the equation of state of a fluid, but how does confinement change the equilibrium conditions themselves? This Special Issue explores some of the roads that were opened up for us by Hill with the idea of nanothermodynamics. The experimental progress in nanotechnology is advancing rapidly. It is our ambition with this book to inspire an increased effort in the development of suitable theoretical tools and methods to help further progress in nanoscience. All ten contributions to this Special Issue can be seen as efforts to support, enhance and validate the theoretical foundation of Hill. 606 $aTechnology: general issues$2bicssc 610 $ananothermodynamics 610 $aporous systems 610 $amolecular simulation 610 $adifferential pressure 610 $aintegral pressure 610 $apressure 610 $aconfinement 610 $aequilibrium 610 $athermodynamic 610 $asmall-system 610 $ahills-thermodynamics 610 $apore 610 $ananopore 610 $ainterface 610 $aKirkwood-Buff integrals 610 $asurface effects 610 $amolecular dynamics 610 $aactivated carbon 610 $ahigh-pressure methane adsorption 610 $athermodynamics of adsorption systems 610 $asmall system method 610 $athermodynamics of small systems 610 $ahydration shell thermodynamics 610 $afinite size correction 610 $aadsorption 610 $athin film 610 $asize-dependent 610 $athermodynamics 610 $aspreading pressure 610 $aentropy of adsorption 610 $apolymers 610 $asingle-molecule stretching 610 $athermodynamics at strong coupling 610 $atemperature-dependent energy levels 610 $aHill's thermodynamics of small systems 610 $aporous media 610 $astatistical mechanics 610 $aideal gas 610 $ananoparticles 615 7$aTechnology: general issues 700 $aKjelstrup$b Signe$4edt$01117446 702 $aKjelstrup$b Signe$4oth 906 $aBOOK 912 $a9910557344803321 996 $aNanoscale Thermodynamics$93021103 997 $aUNINA