LEADER 03413nam 2200433z- 450 001 9910557221203321 005 20211118 035 $a(CKB)5400000000041732 035 $a(oapen)https://directory.doabooks.org/handle/20.500.12854/73729 035 $a(oapen)doab73729 035 $a(EXLCZ)995400000000041732 100 $a20202111d2020 |y 0 101 0 $aeng 135 $aurmn|---annan 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aFrom Glycerol to Value-Added Products 210 $cFrontiers Media SA$d2020 215 $a1 online resource (171 p.) 311 08$a2-88963-577-5 330 $aIn a context where the role of biofuels will continue to grow, it is necessary to take into account the current state of their various manufacturing processes and to anticipate the expansion of the market. Thus, current biodiesel production processes generate a significant amount of glycerol as a by-product (about 100 kg per ton of processed vegetable oil). An explosion of the biodiesel market must integrate the valorization of glycerol whose current market of distribution (cosmetics, drugs, polymers, etc.) is not guaranteed such an expansion. This valuation will contribute effectively to the profitability and sustainability of the processes from which it derives. Glycerol physicochemical and toxicological properties give it the potential to be used as solvent, biolubricant, dispersant, and surfactant, among others. It is also widely used in the food industry as a preservative and sweetener. Beyond these applications, glycerol can also be used as a raw material for a wide range of chemicals. Glycerol is a highly functionalized molecule with specific physico-chemical properties, which can be used in different reactions as a reactant or a building block. For example, glycerol can be used as a starting material for antibiotic production, biosurfactants, organic acid production (lactic, propionic, succinic, citric acid, glyoxylic acid, glyoxalic acid, amino acids, etc.), alcohols (propanediols), glycerol esters, acrolein production, etc. These products can be obtained either through chemical reactions such as acetalization, dehydration, glycerolysis, esterification, etherification, aqueous phase reforming, oxidation, carboxylation, electrochemical routes, or through enzymatic reactions. However, it must be kept in mind that the development of industrial processes relies on the use of crude glycerol from biodiesel production. For that purpose, robust processes involving impurities-insensitive catalysts or pre-purification have to be developed. Finally, the separation of the chemical products obtained after glycerol conversion is also a key step toward the development of viable glycerol-based processes. 606 $aScience: general issues$2bicssc 610 $aactivation 610 $aadded value bio-based products 610 $acatalysis 610 $aelectrochemical conversions 610 $aglycerol 610 $agreen chemistry 610 $aprocess 615 7$aScience: general issues 700 $aCognet$b Patrick$4edt$01280601 702 $aKheireddine Aroua$b Mohamed$4edt 702 $aCognet$b Patrick$4oth 702 $aKheireddine Aroua$b Mohamed$4oth 906 $aBOOK 912 $a9910557221203321 996 $aFrom Glycerol to Value-Added Products$93017276 997 $aUNINA