LEADER 09530nam 2200469 450 001 9910555108803321 005 20220819174237.0 010 $a3-527-83065-0 010 $a3-527-83064-2 010 $a3-527-83066-9 035 $a(MiAaPQ)EBC6817950 035 $a(Au-PeEL)EBL6817950 035 $a(CKB)19935013000041 035 $a(EXLCZ)9919935013000041 100 $a20220819d2022 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aAnion-binding catalysis /$fedited by Olga Garci?a Manchen?o 210 1$aWeinheim, Germany :$cWiley-VCH,$d[2022] 210 4$d©2022 215 $a1 online resource (416 pages) 311 08$aPrint version: Garcia-Mancheno, Olga Anion-Binding Catalysis Newark : John Wiley & Sons, Incorporated,c2022 9783527348572 327 $aCover -- Title Page -- Copyright -- Contents -- Preface -- List of Abbreviations -- Chapter 1 From Anion Recognition to Organocatalytic Chemical Reactions -- 1.1 Introduction and Background -- 1.1.1 Evolution of Thiourea?Based Catalysts -- 1.1.2 Evolution of Triazole?Based Catalysts -- 1.1.3 Progress on Halogen?Binding?Based Catalysts -- 1.1.4 Miscellaneous Anion?Binding Catalysts -- 1.2 Concepts in Anion?Binding Catalysis -- 1.2.1 Introduction -- 1.2.2 Anion?Binding Catalysis in Addition Reactions -- 1.2.3 Anion?Binding Catalysis in Substitution Reactions -- 1.2.4 Anion Binding in Cooperative Catalysis -- 1.2.5 Anion?Binding in Lewis Acid Enhancement Catalysis -- 1.2.6 Anion?Binding in Phase Transfer Catalysis -- 1.3 Summary and Outlook -- Acknowledgment -- References -- Chapter 2 Anion Recognition and Binding Constant Determination -- 2.1 Introduction to Supramolecular Chemistry and Binding Constant Determination -- 2.1.1 Chapter Overview -- 2.1.2 Supramolecular Chemistry and Its Connection to Anion?Assisted Catalysis -- 2.1.3 Brief History of Advances in Supramolecular Anion Binding -- 2.1.4 Predicting the Model of Association and Simulating the Expected Species Distribution Profiles and Binding Curves -- 2.2 Equilibrium Constants, Binding Curves, Titration Conditions, and Errors -- 2.2.1 Physical Origins of Equilibrium Binding Constants -- 2.2.2 Explanation of the Basis for Titration Techniques and Binding Curves -- 2.2.3 Hirose's Rule and Picking the Right Concentration, Solvent, and Technique -- 2.2.4 Error Determination -- 2.3 Experimental Techniques: NMR Spectroscopy -- 2.3.1 When to Use -- 2.3.2 Slow Exchange vs. Fast Exchange -- 2.3.3 Determination of the Underlying Equilibria -- 2.3.4 Software for Non?linear Regression Fitting -- 2.3.5 Common Issues -- 2.4 Experimental Techniques: UV-Vis Spectroscopy -- 2.4.1 When to Use. 327 $a2.4.2 Physical Origins of Optical Phenomena -- 2.4.3 Software for Non?linear Regression Analysis of UV-Vis Titrations -- 2.4.4 Common Issues -- 2.5 Underappreciated Concerns in Binding Constant Determination: Multiple Binding Equilibria -- 2.5.1 When to Expect Additional Equilibria -- 2.5.2 How to Diagnose Additional Equilibria -- 2.5.3 How to Account for Additional Equilibria -- 2.6 Underappreciated Concerns in Binding Constant Determination: Ion Pairing -- 2.6.1 When to Expect Ion Pairing -- 2.6.2 Role of Solvent and Concentration in Ion Pairing -- 2.6.3 How to Diagnose Ion Pairing -- 2.7 Underappreciated Concerns in Binding Constant Determination: Kinetic Processes -- 2.8 Connecting Equilibrium Constants to Structures and Catalysis -- 2.9 Conclusion -- Acknowledgment -- References -- Chapter 3 (Thio)urea and Squaramide?Catalyzed Anion?Binding Catalysis with Halogen Anions -- 3.1 Introduction -- 3.2 History and Background -- 3.3 Asymmetric Catalysis by Catalyst Association with the Electrophile -- 3.3.1 Examples Utilizing the N?Acyliminium Chloride Ion Pair -- 3.3.1.1 Pictet-Spengler Reaction and Variants -- 3.3.1.2 Intramolecular Cyclizations with Other (Hetero)aromatic Nucleophiles -- 3.3.1.3 Intramolecular and Intermolecular aza?Sakurai Reaction -- 3.3.1.4 Mannich Reaction and Variants -- 3.3.1.5 Petasis?Type Reactions -- 3.3.2 Examples Utilizing Electrophiles Other than N?Acyliminium Ion Precursors -- 3.3.2.1 Utilization of Oxocarbenium and Pyrone Intermediates -- 3.3.2.2 Glycosylation Reactions Utilizing HBD-Halide Binding -- 3.3.2.3 Utilization of Non?heteroatom?Stabilized Carbocations as Electrophiles -- 3.4 Asymmetric Catalysis by Catalyst Association with the Nucleophile -- 3.4.1 Catalyst?Nucleophile Association in Phase?Transfer Catalysis -- 3.4.1.1 Investigation of Hydrogen?Bonded Fluoride: Structure and Reactivity. 327 $a3.4.1.2 Development of Hydrogen?Bonding Phase?Transfer Catalysis (HBPTC) -- 3.4.1.3 Development of Acyl?Transfer Catalysis with Hydrogen?Bonded Fluoride -- 3.4.2 Catalyst-Nucleophile Association in Homogeneous Catalysis -- 3.5 Conclusions and Outlook -- Acknowledgments -- References -- Chapter 4 Chiral Ureas, Thioureas, and Squaramides in Anion?Binding Catalysis with Co?catalytic Brønsted/Lewis Acids -- 4.1 Introduction -- 4.2 Carboxylic Acid Co?catalysts -- 4.3 Sulfonic Acid Co?catalysts -- 4.4 Mineral Acid Co?catalysts -- 4.5 Lewis Acid Co?catalysts -- 4.6 Conclusions and Outlook -- References -- Chapter 5 Anion?Binding Catalysis with Other Anions -- 5.1 Introduction -- 5.2 Cyanide Anion -- 5.2.1 Strecker Reaction -- 5.2.2 Acylcyanation of Imines -- 5.3 Oxygen?Based Anions -- 5.3.1 Alkoxides and Enolates -- 5.3.2 Enolates of Lactones, Cyclic Anhydrides, and Imides -- 5.3.3 Carboxylates -- 5.4 Conclusions and Outlook -- References -- Chapter 6 Silanediols, Phosphoramides, and Other OH? and NH?Based H?Donor Catalysts -- 6.1 Introduction -- 6.2 Silanediols -- 6.2.1 Introduction -- 6.2.2 Overview of Silanols in Anion Binding and Catalysis -- 6.2.3 Silanediol Anion?Binding Catalysis -- 6.2.4 Alkoxysilanediol Anion Binding Catalysis -- 6.3 Siloxanes -- 6.4 Thiophosphoramides -- 6.5 Cyclodiphosphazanes -- 6.6 Other Examples -- 6.6.1 Xanthene-Diamine Scaffold -- 6.6.2 Croconamides -- 6.6.3 Pyrrole?Based Anion?Binding Catalyst -- 6.6.4 Bisamidine Catalysts -- 6.7 Conclusions -- References -- Chapter 7 1,2,3?Triazoles and 1,2,3?Triazolium Ions as Catalysts -- 7.1 Introduction -- 7.2 Triazole?Based Anion?Binding Molecular Catalysts -- 7.3 Triazolium Ions as Organic Molecular Catalysts with Anion?Binding Ability -- 7.4 Triazolium Ions in Dual Functional Catalysts -- 7.5 Conclusion -- References. 327 $aChapter 8 Quaternary Ammonium, Phosphonium, and Tertiary Sulfonium Salts as Hydrogen?Bonding Catalysts -- 8.1 Introduction -- 8.2 Hydrogen?Bonding Ability of Quaternary Ammonium Salts -- 8.3 Hydrogen?Bonding Catalysis of Quaternary Ammonium Salts -- 8.4 Hydrogen?Bonding Catalysis of Quaternary Phosphonium Salts -- 8.5 Hydrogen?Bonding Catalysis of Tertiary Sulfonium Salts -- 8.6 Conclusion -- References -- Chapter 9 Assisted and Dual Anion Binding in Amino and Nucleophilic Catalysis -- 9.1 Dual Amino/H?Bond Donor Catalysis -- 9.1.1 Enamine Activation -- 9.1.2 Dienamine Activation -- 9.1.3 Iminium Ion Activation -- 9.1.4 Vinylogous Iminium Ion Activation -- 9.2 Thiourea - Pyridine?Based Nucleophilic Dual Catalysis -- 9.2.1 Kinetic Resolution and Desymmetrization of Amines -- 9.2.2 Asymmetric Steglich Rearrangement -- 9.2.3 Other Acylation Reactions -- 9.2.4 Anion?Binding?Assisted Polymerization Reactions -- 9.3 Conclusions -- References -- Chapter 10 Anion?Binding Catalysis by Halogen, Chalcogen, Pnictogen, and Tetrel Bonding -- 10.1 History of Halogen Bonding -- 10.2 History of Chalcogen Bonding -- 10.3 History of Pnictogen and Tetrel Bonding -- 10.4 Differences Between Hydrogen Bonding and Other Secondary Interactions -- 10.5 Secondary Bonding in Anion Recognition -- 10.6 Halogen Bonding in Anion?Binding Catalysis -- 10.7 Chalcogen Bonding in Anion?Binding Catalysis -- 10.8 Pnictogen and Tetrel Bonding in Anion?Binding Catalysis -- 10.9 Conclusion -- References -- Chapter 11 New Trends and Supramolecular Approaches in Anion?Binding Catalysis -- 11.1 General Introduction -- 11.2 Dual Photoredox and Anion?Binding Catalysis -- 11.3 Combination of Metal and Anion?Binding Catalysis -- 11.3.1 Anion?Binding Assisted Hydrogenation Reactions -- 11.3.2 Hydroformylation Reactions -- 11.3.3 Anion?Binding - Metal?Catalyzed C-C Forming Reactions. 327 $a11.4 Supramolecular Approaches Involving Anion?Binding Catalysis -- 11.4.1 Mechanically Interlocked Molecules in Anion?Binding Catalysis -- 11.4.1.1 Molecular Knots as Anion?Binding Catalysts -- 11.4.1.2 Rotaxanes as Anion?Binding Catalysts -- 11.4.2 Molecular Motors in Anion?Binding Catalysis -- 11.4.3 Macrocycles in Anion?Binding Catalysis -- 11.5 Anion-? Catalysis -- 11.5.1 Anion-??Catalyzed Kemp Elimination Reaction -- 11.5.2 Anion-? Interactions in Enolate Chemistry -- 11.5.3 Epoxide?Opening - Ether Cyclization Reactions -- 11.5.4 Enantioselective Anion-? Catalysis -- 11.5.5 Miscellaneous -- 11.6 Conclusion and Outlook -- References -- Index -- EULA. 606 $aBioorganic chemistry 608 $aElectronic books. 615 0$aBioorganic chemistry. 676 $a572 702 $aGarci?a Manchen?o$b Olga 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910555108803321 996 $aAnion-Binding Catalysis$92818980 997 $aUNINA LEADER 08212nam 22008415 450 001 9910143613103321 005 20250724095003.0 010 $a3-540-45600-7 024 7 $a10.1007/3-540-45600-7 035 $a(CKB)1000000000211625 035 $a(SSID)ssj0000323964 035 $a(PQKBManifestationID)11246668 035 $a(PQKBTitleCode)TC0000323964 035 $a(PQKBWorkID)10303979 035 $a(PQKB)11582798 035 $a(DE-He213)978-3-540-45600-1 035 $a(MiAaPQ)EBC3072044 035 $a(PPN)155203746 035 $a(EXLCZ)991000000000211625 100 $a20121227d2001 u| 0 101 0 $aeng 135 $aurnn#008mamaa 181 $ctxt 182 $cc 183 $acr 200 10$aInformation and Communications Security $eThird International Conference, ICICS 2001, Xian, China, November 13-16, 2001. Proceedings /$fedited by Tatsuaki Okamoto, Jianying Zhou 205 $a1st ed. 2001. 210 1$aBerlin, Heidelberg :$cSpringer Berlin Heidelberg :$cImprint: Springer,$d2001. 215 $a1 online resource (XIV, 510 p.) 225 1 $aLecture Notes in Computer Science,$x1611-3349 ;$v2229 300 $aBibliographic Level Mode of Issuance: Monograph 311 08$a3-540-42880-1 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aSecurity of Blind Discrete Log Signatures against Interactive Attacks -- An Intelligent Intruder Model for Security Protocol Analysis -- Primitive Polynomials over GF(2) ? A Cryptologic Approach -- Unconditionally-Secure Oblivious Transfer -- Cryptanalysis of the Improved User Efficient Blind Signatures -- Towards the Forgery of a Group Signature without Knowing the Group Center's Secret -- Evaluation of the Image Degradation for a Typical Watermarking Algorithm in the Block-DCT Domain -- A Cyclic Window Algorithm for ECC Defined over Extension Fields -- Fast Scalar Multiplication on the Jacobian of a Family of Hyperelliptic Curves -- Attacks on Two Digital Signature Schemes Based on Error Correcting Codes -- A Derivative of Digital Objects and Estimation of Default Risks in Electronic Commerce -- A New Approach for Secure Multicast Routing in a Large Scale Network -- A Transaction Length-Sensitive Protocol Based on Altruistic Locking for Multilevel Secure Database Systems -- Dealing with Uncertainties in Risk Analysis Using Belief Functions -- RBAC for XML Document Stores -- Cheating Immune Secret Sharing -- Encryption Sticks (Randomats) -- Applying NCP Logic to the Analysis of SSL 3.0 -- Performance of WTLS and Its Impact on an M-commerce Transaction -- Enforcing Obligation with Security Monitors -- Efficient Software Implementation for Finite Field Multiplication in Normal Basis -- Playing Lottery on the Internet -- Privacy Protection for Transactions of Digital Goods -- Equivalent Characterizations and Applications of Multi-output Correlation-Immune Boolean Functions -- Threshold Undeniable RSA Signature Scheme -- Two Simple Batch Verifying Multiple Digital Signatures -- Square Attack on Reduced Camellia Cipher -- Generalization of Elliptic Curve Digital Signature Schemes -- Reasoning aboutAccountability within Delegation -- A Novel Data Hiding Method for Two-Color Images -- An Identification Scheme Provably Secure against Reset Attack -- Estimating the Scalability of the Internet Key Exchange -- An Efficient Information Flow Analysis of Recursive Programs Based on a Lattice Model of Security Classes -- Defeating Denial-of-Service Attacks on the Internet -- A Role-Based Access Control Model and Implementation for Data-Centric Enterprise Applications -- A Unified Methodology for Verification and Synthesis of Firewall Configurations -- Quantifying Network Denial of Service: A Location Service Case Study -- A Public Key Cryptosystem Based on the Subgroup Membership Problem -- On a Network Security Model for the Secure Information Flow on Multilevel Secure Network -- NIDS Research Based on Artificial Immunology -- AMBAR Protocol: Access Management Based on Authorization Reduction -- Chinese Remainder Theorem Based Hierarchical Access Control for Secure Group Communication -- Dispatching Mobile Agents with Secure Routes in Parallel -- TH-SMS: Security Management System in Advanced Computational Infrastructure -- Cryptography and Middleware Security -- Cryptanalysis of the Hwang-Rao Secret Error-Correcting Code Schemes -- A Role-Based Model for Access Control in Database Federations -- A Useful Intrusion Detection System Prototype to Monitor Multi-processes Based on System Calls -- A Digital Nominative Proxy Signature Scheme for Mobile Communication -- Hierarchical Simulation Model with Animation for Large Network Security -- Fair Electronic Cash Based on a Group Signature Scheme -- Fair Exchange of Digital Signatures with Offline Trusted Third Party -- SECUSIM: A Tool for the Cyber-Attack Simulation -- A New Semantics of Authentication Logic -- Robust and Fragile Watermarking Techniques for Documents Using Bi-directional Diagonal Profiles -- Redundancy, Obscurity, Self-Containment & Independence. 330 $aICICS 2001, the Third International Conference on Information and Commu- cations Security, was held in Xi?an, China, 13-16 November 2001. Among the preceding conferences, ICICS?97 was held in Beijing, China, 11-14 November 1997 and ICICS?99 in Sydney, Australia, 9-11 November 1999. The ICICS?97 and ICICS?99 proceedings were released as volumes 1334 and 1726 of Springer- Verlag?s Lecture Notes in Computer Science series. ICICS 2001 was sponsored by the Chinese Academy of Sciences (CAS), the - tional Natural Science Foundation of China, and the China Computer Fe- ration. The conference was organized by the Engineering Research Center for Information Security Technology of the Chinese Academy of Sciences (ERCIST, CAS) in co-operation with the International Association for Cryptologic Re- arch (IACR), the International Communications and Information Security - sociation (ICISA), and the Asiacrypt Steering Committee. The format of ICICS 2001 was selected to cover the complete spectrum of - formation and communications security, and to promote participant interaction. The sessions were designed to promote interaction between the major topics of the conference: theoretical foundations of security, secret sharing, network - curity, authentication and identi?cation, boolean functions and stream ciphers, security evaluation, signatures, block ciphers and public-key systems, infor- tion hiding, protocols and their analysis, and cryptanalysis. The 29-member Program Committee considered 134 submissions from 23 di- rent countries and regions, among them 56 papers were accepted for presentation. 410 0$aLecture Notes in Computer Science,$x1611-3349 ;$v2229 606 $aCryptography 606 $aData encryption (Computer science) 606 $aComputer networks 606 $aOperating systems (Computers) 606 $aAlgorithms 606 $aElectronic data processing$xManagement 606 $aBusiness information services 606 $aCryptology 606 $aComputer Communication Networks 606 $aOperating Systems 606 $aAlgorithms 606 $aIT Operations 606 $aIT in Business 615 0$aCryptography. 615 0$aData encryption (Computer science) 615 0$aComputer networks. 615 0$aOperating systems (Computers) 615 0$aAlgorithms. 615 0$aElectronic data processing$xManagement. 615 0$aBusiness information services. 615 14$aCryptology. 615 24$aComputer Communication Networks. 615 24$aOperating Systems. 615 24$aAlgorithms. 615 24$aIT Operations. 615 24$aIT in Business. 676 $a005.8 702 $aOkamoto$b Tatsuaki$4edt$4http://id.loc.gov/vocabulary/relators/edt 702 $aZhou$b Jianying$4edt$4http://id.loc.gov/vocabulary/relators/edt 712 12$aICICS (Conference) 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910143613103321 996 $aInformation and Communications Security$9771899 997 $aUNINA