LEADER 00973nas 2200349- 450 001 9910503223203321 005 20220125001812.0 011 $a2770-5749 035 $a(OCoLC)732734522 035 $a(CKB)2550000000020660 035 $a(CONSER)--2021220556 035 $a(EXLCZ)992550000000020660 100 $a19860930b18901956 --- a 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 04$aThe Greenville morning herald 210 1$aGreenville, Tex. :$cE.W. Harris & Son 215 $a1 online resource (volumes) 311 $a2159-3906 517 1 $aMorning herald 531 $aGREENVILLE MORNING HERALD 607 $aGreenville (Tex.)$vNewspapers 607 $aTexas$zGreenville$2fast 608 $aNewspapers$2fast 676 $a071/.3 906 $aJOURNAL 912 $a9910503223203321 996 $aThe Greenville morning herald$91903204 997 $aUNINA LEADER 04033nam 22006855 450 001 9910847071703321 005 20250807140323.0 010 $a981-9989-94-9 024 7 $a10.1007/978-981-99-8994-2 035 $a(CKB)31253113500041 035 $a(MiAaPQ)EBC31267017 035 $a(Au-PeEL)EBL31267017 035 $a(MiAaPQ)EBC31233454 035 $a(Au-PeEL)EBL31233454 035 $a(DE-He213)978-981-99-8994-2 035 $a(EXLCZ)9931253113500041 100 $a20240328d2024 u| 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aPhotochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis /$fby Su Yong Go 205 $a1st ed. 2024. 210 1$aSingapore :$cSpringer Nature Singapore :$cImprint: Springer,$d2024. 215 $a1 online resource (185 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 311 08$a981-9989-93-0 320 $aIncludes bibliographical references. 327 $aPart I. C(sp2)-C(sp3) Bond Formation Reactions Enabled by Photoredox/Nickel Dual Catalysis -- Chapter 1. The Key Concepts and Strategy in Photoredox/Nickel Dual Catalysis and Application to C-C Bond Formation Reactions -- Chapter 2. Highl Regioselective and E/Z Selective Hydroalkylation of Alkyne via Photoredox Mediated Ni/Ir Dual Catalysis -- Part II. Development of C(sp3)-Heteroatom Bond-Forming Reactions via Electrochemical Activation of C(sp3)-B Bonds and Follow-up Projects -- Chapter 3. Recent Achievements of C(sp3)-Heteroatom Bond Formation in Electroorganic Synthesis and History of C(sp3)-B Bond Activation -- Chapter 4. Introduction of Heteroatoms to Alkyl Carbocations Generated from Alkylboron Reagents via Electrochemical Activation -- Chapter 5. Functionalization of Alkylboron Compounds Under Other Reaction Conditions. 330 $aThis book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization. The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, although the backbone structure of organic compounds comprises carbon fragments. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061 606 $aElectrochemistry 606 $aPhotochemistry 606 $aCatalysts 606 $aCatalysis 606 $aMaterials 606 $aElectrochemistry 606 $aPhotochemistry 606 $aCatalyst Synthesis 606 $aCatalytic Materials 615 0$aElectrochemistry. 615 0$aPhotochemistry. 615 0$aCatalysts. 615 0$aCatalysis. 615 0$aMaterials. 615 14$aElectrochemistry. 615 24$aPhotochemistry. 615 24$aCatalyst Synthesis. 615 24$aCatalytic Materials. 676 $a541.37 700 $aGo$b Su Yong$01735361 702 $aGeun Lee$b Hong 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910847071703321 996 $aPhotochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis$94154557 997 $aUNINA