LEADER 09761nam 22004333 450 001 9910842399903321 005 20240307080220.0 010 $a1-119-71684-5 010 $a1-119-71685-3 035 $a(MiAaPQ)EBC31199669 035 $a(Au-PeEL)EBL31199669 035 $a(EXLCZ)9930753004900041 100 $a20240307d2024 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aOrganic Reaction Mechanisms 2020 205 $a1st ed. 210 1$aNewark :$cJohn Wiley & Sons, Incorporated,$d2024. 210 4$d©2024. 215 $a1 online resource (623 pages) 225 1 $aOrganic Reaction Mechanisms Series 311 $a1-119-71683-7 327 $aCover -- Title Page -- Copyright -- List of Contributors -- Preface -- Contents -- Chapter 1 Reactions of Aldehydes and Ketones and Their Derivatives -- Formation and Reactions of Acetals and Related Species -- Reactions of Glucosides -- Reactions of Ketenes and Related Cumulenes -- Formation and Reactions of Nitrogen Derivatives -- Imines: Synthesis and General and Iminium Chemistry -- Mannich and Mannich?Type Reactions -- Stereoselective Hydrogenation of Imines, and Other Redox Processes -- Cyclizations of Imines -- Other Reactions of Imines -- Oximes, Oxime Ethers, and Oxime Esters -- Hydrazones and Related Species -- Iminium Ion Chemistry -- C C Bond Formation and Fission: Aldol and Related Reactions -- The Asymmetric Aldol -- The Morita-Baylis-Hilman Reaction and Its Aza?Variants -- Other Aldol and Aldol?Type Reactions -- The Michael Addition -- The Wittig and Other Olefinations -- Miscellaneous Additions -- Reactions of Enolates and Related Reactions -- Oxidation of Carbonyl Compounds -- Reduction of Carbonyl Compounds -- Miscellaneous Reactions -- References -- Chapter 2 Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and Their Derivatives -- Intermolecular Catalysis and Reactions -- Carboxylic Acids and their Derivatives -- Phosphoric Acids and their Derivatives -- Sulfonic Acids and their Derivatives -- Intramolecular Catalysis and Neighboring Group Participation -- Biologically Significant Reactions -- Carboxylic Acids and their Derivatives -- References -- Chapter 3 Oxidation and Reduction -- Oxidation by Metal Ions and Related Species -- Chromium, Manganese, Nickel, and Cobalt -- Copper, Silver, and Gold -- Rhenium, Bismuth, and Tungsten -- Palladium, Iridium, Rhodium, and Platinum -- Group VIII Metals -- Cerium -- Oxidation by Compounds of Nonmetallic Elements -- Nitrogen, Sulfur, and Selenium -- Halogens. 327 $aOzonolysis and Ozonation -- Peracids and Peroxides -- Photochemical Oxidation and Singlet Oxygen -- Triplet Oxygen and Autoxidation -- Electrochemical Oxidations -- Other Oxidations -- Reduction by Metal Hydrides -- Hydrogenation -- Transfer Hydrogenation -- Other Reductions -- References -- Chapter 4a Nucleophilic Aromatic Substitution -- General -- Reactions of Arenediazonium Salts -- The SNAr Mechanism -- Meisenheimer and Related Complexes -- Benzyne and Related Intermediates -- Transition Metal?Catalyzed Carbon-Carbon Bond Formation -- References -- Chapter 4b Electrophilic Aromatic Substitution -- General Introduction -- Computational Studies -- Protonation and Deuteration -- Halogenation -- Chlorination -- Bromination -- Nitration -- Amidation, Amination, and Azidation -- Oxylation -- Sulfanylation and Sulfonation -- Metallation -- C C Bond?Forming Reactions -- Friedel-Crafts Alkylation -- Friedel-Crafts Acylation -- Arylation -- Miscellaneous FGIs -- References -- Chapter 5 Carbocations -- General -- Vinyl, Allyl, and Propargyl Cations -- Benzyl, Benzhydryl, and Trityl Cations -- Arenium Ions -- Chloronium, Iminium, Oxonium, Phosphirenium, Silylium, and Thionium Cations -- New Cations and Synthetic Methods -- Nonclassical Carbocations -- Carbocation Rearrangements -- Carbocations in Biosynthesis -- References -- Chapter 6 Nucleophilic Aliphatic Substitution 2020 -- Introduction -- General -- Computational Studies -- Nucleophiles -- Leaving Groups -- Substrates -- Alkylation -- Allylic and Propargylic Substitution -- Glycosyl Substitution -- Decarboxylative Substitution -- Cross?Coupling with Alkyl Halides -- C-H Activation Processes -- Reactions -- References -- Chapter 7 Carbanions and Electrophilic Aliphatic Substitution -- Carbanion Reactions -- Enolates and Related Species -- Organometallic Species -- Miscellaneous. 327 $aElectrophilic Aliphatic Substitution -- References -- Chapter 8 Elimination Reactions -- E2 Mechanisms -- Solvolytic Reactions -- Pyrolytic Reactions -- Elimination Reactions in Synthesis -- Other Reactions -- References -- Chapter 9 Addition Reactions: Polar Addition -- Reviews -- Electrophilic Additions -- Halogenation and Related Reactions -- Additions of ArSX, ArSeX, and Related Reagents -- Additions of Hydrogen Halides and Other Brønsted Acids -- Additions Mediated by Lewis Acids -- Additions of Electrophilic Carbon -- Additions of Electrophilic Nitrogen -- Additions of Electrophilic Oxygen -- Additions Initiated by Metals and Metal Ions as Electrophiles -- Additions Initiated by Light -- Miscellaneous Electrophilic Additions -- Nucleophilic Additions -- Additions to Multiple Bonds Conjugated with C O -- Additions to Multiple Bonds Activated by Other Electron?Withdrawing Groups -- Additions of Organometallics to Activated Double Bonds -- Additions Initiated by Light -- Miscellaneous Nucleophilic Additions -- Acronyms -- References -- Chapter 10 Addition Reactions: Cycloaddition -- [2?+?2]?Cycloaddition -- [2?+?3]?Cycloaddition -- [2?+?4]?Cycloaddition -- Miscellaneous -- References -- Chapter 11 Molecular Rearrangements -- Pericyclic and Addition Reactions -- [2,3]?Sigmatropic Rearrangement -- [3,3]?Sigmatropic, Cope, and Claisen Rearrangement -- [2?+?2] Cycloaddition -- Ene Diyne -- 1,3?Dipolar Rearrangement and Addition -- [3?+?2] Annulation -- [4?+?1] Annulation -- [5?+?4] Annulation -- Migration Reactions -- 1,2?H Migration -- 1,3?H Transfer -- 1,3?Rearrangement -- O to C Migration -- H Atom Transfer -- Skeletal Rearrangement -- Ring Opening and Closing Reactions -- Carbocations -- Cyclization -- Ring Opening -- Ring Contraction -- Ring Expansion -- Reaction Types -- Acid Induced -- Addition -- Pinacol -- CH Insertion. 327 $aBenzyl-Benzylic Rearrangement -- Azo?coupling -- Condensation -- Dimerization -- Trimerization -- Polymerization -- Isomerization -- Oxidation -- Reduction -- Functional Group -- Cyclopropane -- Aziridine -- Enolate -- Alkyne -- Allene -- Nitrone -- Azide -- Ylide -- Mass Spectra -- Reactive Species -- Photolysis -- Thermal and Pyrolysis -- Radical -- Carbene and Nitrene -- Radical Anion -- Named Reactions -- Banert Cascade -- Baeyer-Villiger Oxidation -- Beckman Rearrangement -- Bolton-Katritzky Rearrangement -- Carroll Rearrangement -- Curtius Rearrangement -- Dimroth Rearrangement -- Friedel-Craft -- Hofmann-Martius Rearrangement -- Knoevenagel?[1,5]?hydride Shift -- Michael Reaction -- Mannich -- Mallard -- Mumm Rearrangement -- Mallory Reaction -- Morita-Baylis-Hillman -- Nazarov Cyclization -- Negishi Cross?coupling -- Newman-Kwart Rearrangement -- Pechmann Condensation -- Pummerer -- Pictet-Spengler Reaction -- Sommelet-Hauser -- Stevens Rearrangement -- Smiles Rearrangement -- Truce-Smiles Rearrangement -- Wagner?Jauregg Reaction -- Wagner-Meerwein Rearrangement -- Wolff Rearrangement -- Wittig -- Boron, Fluorine, and Phosphorous -- B -- F -- P -- Metal Catalysts -- Ag -- Au -- Co -- Cu -- Fe -- Mg -- Si -- Pd -- In -- Ni -- Pd -- Rh -- Ir -- Biological -- Enzyme -- Steroid -- Sugar -- Miscellaneous -- References -- Chapter 12 Ligand?Promoted Catalyzed Reactions -- REACTIONS NOT INVOLVING C H BOND ACTIVATION -- Cross?Coupling Reactions with C C Bond Formation -- Cross?Coupling Reactions with C N Bond Formation -- Cross?Coupling Reactions with Other C X Bond Formation -- Cross?Coupling Reactions with Simultaneous C-C and C-C/C X Bond Formations -- Annulation Reactions and Others -- REACTIONS INVOLVING C H BOND ACTIVATION -- C-H Alkylation Reactions -- C-H Arylation Reactions -- Cross?Dehydrogenative Coupling (CDC) Reactions. 327 $aAnnulation Reactions -- C X Bond Formation via C-H Activation -- Other C-H Functionalizations -- References -- Chapter 13 Radical Reactions -- Generation and Trapping -- Probing Radical Reaction Mechanisms -- Biological Applications -- Functional Group Interconversions -- Organoboron Compounds -- Alkylbenzenes -- Nitrogen?containing Functional Groups -- Oxygen?Containing Functional Groups -- Sulfur?Containing Functional Groups -- Phosphorus?containing Functional Groups -- Allenes (Forming C-Heteroatom Bonds) -- Alkenes (Forming C-Heteroatom Bonds) -- Alkynes (Forming C-Heteroatom Bonds) -- Addition to Arenes and Heteroarenes (Forming C-Heteroatom Bonds) -- Cyclizations -- Three?Membered Ring Formation -- Five?Membered Ring Formation -- Six?Membered Ring Formation -- Intermolecular Additions -- Addition to Alkenes (Forming C C Bonds) -- Addition to Alkynes (Forming C C Bonds) -- Addition to Arenes and Heteroarenes (Forming C C Bonds) -- Cascade Reactions -- Initial Fragmentation -- Initial Intermolecular Addition -- Initial Cyclization -- Radical Cations -- References -- Subject Index -- EULA. 410 0$aOrganic Reaction Mechanisms Series 700 $aMoloney$b Mark G$0887051 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910842399903321 996 $aOrganic Reaction Mechanisms 2020$94145655 997 $aUNINA LEADER 04188nam 22008775 450 001 9910483087203321 005 20251226202433.0 010 $a3-319-14977-6 024 7 $a10.1007/978-3-319-14977-6 035 $a(CKB)2560000000326190 035 $a(Springer)9783319149776 035 $a(MH)014293526-3 035 $a(SSID)ssj0001424447 035 $a(PQKBManifestationID)11766580 035 $a(PQKBTitleCode)TC0001424447 035 $a(PQKBWorkID)11362959 035 $a(PQKB)11529815 035 $a(DE-He213)978-3-319-14977-6 035 $a(MiAaPQ)EBC6280971 035 $a(MiAaPQ)EBC5586895 035 $a(Au-PeEL)EBL5586895 035 $a(OCoLC)902725720 035 $a(PPN)183520033 035 $a(EXLCZ)992560000000326190 100 $a20150128d2015 u| 0 101 0 $aeng 135 $aurnn#008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aDistributed Computing and Internet Technology $e11th International Conference, ICDCIT 2015, Bhubaneswar, India, February 5-8, 2015. Proceedings /$fedited by Raja Natarajan, Gautam Barua, Manas Ranjan Patra 205 $a1st ed. 2015. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2015. 215 $a1 online resource (XIV, 462 p. 156 illus.)$conline resource 225 1 $aInformation Systems and Applications, incl. Internet/Web, and HCI,$x2946-1642 ;$v8956 300 $aBibliographic Level Mode of Issuance: Monograph 311 08$a3-319-14976-8 327 $aDistributed computing and algorithms -- Internet technologies and Web services -- Secure computing and communication -- Cloud computing -- Information retrieval and recommender systems -- Societal applications. 330 $aThis book constitutes the refereed proceedings of the 11th International Conference on Distributed Computing and Internet Technology, ICDCIT 2015, held in Bhubaneswar, India, in February 2015. The 12 revised full papers presented together with 30 short papers and 9 invited talks in this volume were carefully reviewed and selected from 221 submissions. The papers cover topics such as distributed computing and algorithms; internet technologies and Web services; secure computing and communication; cloud computing; information retrieval and recommender systems; and societal applications. 410 0$aInformation Systems and Applications, incl. Internet/Web, and HCI,$x2946-1642 ;$v8956 606 $aComputer networks 606 $aAlgorithms 606 $aInformation storage and retrieval systems 606 $aApplication software 606 $aDatabase management 606 $aData protection 606 $aComputer Communication Networks 606 $aAlgorithms 606 $aInformation Storage and Retrieval 606 $aComputer and Information Systems Applications 606 $aDatabase Management 606 $aData and Information Security 615 0$aComputer networks. 615 0$aAlgorithms. 615 0$aInformation storage and retrieval systems. 615 0$aApplication software. 615 0$aDatabase management. 615 0$aData protection. 615 14$aComputer Communication Networks. 615 24$aAlgorithms. 615 24$aInformation Storage and Retrieval. 615 24$aComputer and Information Systems Applications. 615 24$aDatabase Management. 615 24$aData and Information Security. 676 $a004.36 702 $aNatarajan$b Raja$4edt$4http://id.loc.gov/vocabulary/relators/edt 702 $aBarua$b Gautam$4edt$4http://id.loc.gov/vocabulary/relators/edt 702 $aPatra$b Manas Ranjan$4edt$4http://id.loc.gov/vocabulary/relators/edt 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910483087203321 996 $aDistributed Computing and Internet Technology$9772254 997 $aUNINA 999 $aThis Record contains information from the Harvard Library Bibliographic Dataset, which is provided by the Harvard Library under its Bibliographic Dataset Use Terms and includes data made available by, among others the Library of Congress