LEADER 02850nam 2200445 450 001 9910483028303321 005 20211020071116.0 010 $a981-16-1163-7 035 $a(CKB)4100000011867244 035 $a(MiAaPQ)EBC6533406 035 $a(Au-PeEL)EBL6533406 035 $a(OCoLC)1245674790 035 $a(PPN)255291078 035 $a(EXLCZ)994100000011867244 100 $a20211020d2021 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aKinetically controlled stepwise syntheses of a heterometallic complex and a tetrahedral chiral-at-metal complex /$fKenichi Endo 210 1$aSingapore :$cSpringer,$d[2021] 210 4$d©2021 215 $a1 online resource (xv, 80 pages) 225 1 $aSpringer theses 311 $a981-16-1162-9 320 $aIncludes bibliographical references. 327 $aIntro -- Supervisor's Foreword -- Acknowledgments -- Contents -- Abbreviations -- 1 General Introduction -- 1.1 Selective Synthesis of Metal Complexes -- 1.2 Target Scope of Kinetically Controlled Stepwise Synthesis -- 1.3 Overview of This Study -- References -- 2 Heterometallic CoIINi3II Complex -- 2.1 Introduction -- 2.2 Step 1: Complexation with a Redox-Active Metal -- 2.3 Step 2: Site-Selective Oxidation -- 2.4 Step 3: Site-Selective Transmetalation -- 2.5 Step 4: Reduction -- 2.6 Comparison with Other Strategies -- 2.7 Conclusions -- 2.8 Experimental Section -- 2.8.1 Materials and Methods -- 2.8.2 Synthesis of Compounds -- 2.8.3 Miscellaneous Experiments -- 2.8.4 Single-Crystal XRD Analyses -- References -- 3 Tetrahedral Chiral-at-Metal ZnII Complex -- 3.1 Introduction -- 3.2 Molecular Design -- 3.3 Strategy for Enantioselective Synthesis -- 3.4 Step 1: Racemic Complexation -- 3.5 Step 2: Asymmetric Induction with a Chiral Ligand -- 3.6 Step 3: Replacement of the Chiral Ligand -- 3.7 Configurational Stability -- 3.8 Enantioselective Catalysis -- 3.9 Conclusions -- 3.10 Experimental Section -- 3.10.1 Materials and Methods -- 3.10.2 Synthesis of the Ligand -- 3.10.3 Syntheses of the Metal Complexes -- 3.10.4 Single-Crystal X-Ray Diffraction Analyses -- 3.10.5 Miscellaneous Experiments -- References -- 4 Conclusions -- 4.1 Conclusions -- Curriculum Vitae -- Education -- Appointment -- Research Interest -- Major Awards -- Fellowship. 410 0$aSpringer theses. 606 $aMetal complexes 615 0$aMetal complexes. 676 $a541.2242 700 $aEndo?$b Ken'ichi$f1961-$01228304 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910483028303321 996 $aKinetically controlled stepwise syntheses of a heterometallic complex and a tetrahedral chiral-at-metal complex$92851588 997 $aUNINA