LEADER 05596nam 2200697Ia 450 001 9910464000503321 005 20200520144314.0 010 $a1-283-97146-1 010 $a981-4390-46-1 035 $a(CKB)3280000000004182 035 $a(EBL)1113169 035 $a(OCoLC)827210184 035 $a(SSID)ssj0000913942 035 $a(PQKBManifestationID)11512081 035 $a(PQKBTitleCode)TC0000913942 035 $a(PQKBWorkID)10862263 035 $a(PQKB)11594469 035 $a(MiAaPQ)EBC1113169 035 $a(WSP)00002867 035 $a(Au-PeEL)EBL1113169 035 $a(CaPaEBR)ebr10648625 035 $a(CaONFJC)MIL428396 035 $a(EXLCZ)993280000000004182 100 $a20111102d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aEngineering of chemical complexity$b[electronic resource] /$feditors, Alexander S. Mikhailov, Gerhard Ertl 210 $aSingapore ;$aHackensack, NJ $cWorld Scientific$dc2013 215 $a1 online resource (413 p.) 225 0 $aWorld Scientific lecture notes in complex systems ;$v111 300 $aDescription based upon print version of record. 311 $a981-4390-45-3 320 $aIncludes bibliographical references and index. 327 $aCONTENTS; Preface; PART I INTRODUCTION; 1. Analysis, Design and Control of Complex Chemical Systems Alexander S. Mikhailov and Gerhard Ertl; 1. Introduction; 2. A Brief Historical Overview; 3. Recent Developments and Open Perspectives; References; PART II SINGLE MOLECULES, NANOSCALE PHENOMENA AND ACTIVE PARTICLES; 2. Imaging and Manipulation of Single Molecules by Scanning Tunneling Microscopy Leonhard Grill; 1. Introduction; 2. Imaging and Spectroscopy of Single Molecules; 2.1. Imaging single molecules; 2.2. Chemical identification by spectroscopy; 2.3. Imaging of diffusion processes 327 $a3. Manipulation of Single Molecules3.1. Manipulation without bias voltage; 3.2. Electron-induced manipulation; 3.3. Electric-field induced manipulation; 3.4. Lateral manipulation: Hopping vs rolling; 3.5. Vertical manipulation: Pulling single molecules from a surface; Acknowledgments; References; 3. Self-Organization at the Nanoscale in Far-From- Equilibrium Surface Reactions and Copolymerizations Pierre Gaspard; 1. Introduction; 2. Fundamental Aspects of Nonequilibrium Nanosystems; 2.1. Structure and function of nanosystems; 2.2. Out-of-equilibrium directionality of fluctuating currents 327 $a2.3. Thermodynamic origins of dynamical order3. Heterogeneous Catalytic Reactions in High Electric Fields; 3.1. Surface conditions in FEM and FIM; 3.2. Adsorption-desorption kinetics; 3.3. Surface oxides of rhodium; 3.4. The H2-O2/Rh system; 3.4.1. Kinetic equations; 3.4.2. Bistability; 3.4.3. Oscillations; 3.5. Self-organization at the nanoscale; 4. Copolymerization processes; 4.1. Information processing at the molecular scale; 4.2. Thermodynamics of free copolymerization; 4.3. Thermodynamics of copolymerization with a template; 4.4. The case of DNA replication 327 $a5. Conclusions and PerspectivesAcknowledgments; References; 4. Single Molecule and Collective Dynamics of Motor Protein Coupled with Mechano-Sensitive Chemical Reaction Mitsuhiro Iwaki, Lorenzo Marcucci, Yuichi Togashi and Toshio Yanagida; 1. What is a Motor Protein?; 2. Measurement of Myosin at the Single Molecule Level; 3. Mechanosensitivity of ATP Hydrolysis during the Unidirectional Motion of Dimeric Myosin; 3.1. Mechanosensitive detachment of myosin-V from actin; 3.2. Mechanosensitive attachment of myosin-VI to actin 327 $a4. Modeling and Simulating Mechanochemical Coupling and Motor Protein Motion4.1. Molecular dynamics simulations; 4.2. Coarse-grained models and dynamics; 4.3. Quantum mechanics for chemical processes; 5. Modeling and Simulations of the Collective Behaviour of Motor Proteins; 5.1. Huxley's 1957 model; 5.2. Huxley and Simmons' 1971 model; 5.3. Diffusional model; References; 5. Nanomotors Propelled by Chemical Reactions Raymond Kapral; 1. Introduction; 2. Propulsion by Phoretic Mechanisms; 3. Microscopic and Mesoscopic Dynamics of Nanomotors; 4. Sphere Dimer Motors; Motor efficiency 327 $aMotor dynamics in chemically active media 330 $aThis review volume, co-edited by Nobel laureate G Ertl, provides a broad overview on current studies in the understanding of design and control of complex chemical systems of various origins, on scales ranging from single molecules and nano-phenomena to macroscopic chemical reactors. Self-organizational behavior and the emergence of coherent collective dynamics in reaction-diffusion systems, reactive soft matter and chemical networks are covered. Special attention is paid to the applications in molecular cell biology and to the problems of biological evolution, synthetic biology and design of 410 0$aWorld Scientific Lecture Notes in Complex Systems 606 $aChemistry$xMathematics 606 $aChaotic behavior in systems 608 $aElectronic books. 615 0$aChemistry$xMathematics. 615 0$aChaotic behavior in systems. 676 $a658.00952 676 $a660 701 $aMikhailov$b A. S$g(Alexander S.),$f1950-$0622611 701 $aErtl$b G$g(Gerhard)$022159 712 12$aEngineering of Chemical Complexity (Conference) 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910464000503321 996 $aEngineering of chemical complexity$92208173 997 $aUNINA