LEADER 05316nam 2200637 a 450 001 9910459106203321 005 20200520144314.0 010 $a0-12-394832-0 035 $a(CKB)2660000000011255 035 $a(EBL)1192230 035 $a(SSID)ssj0000968793 035 $a(PQKBManifestationID)11563880 035 $a(PQKBTitleCode)TC0000968793 035 $a(PQKBWorkID)10985514 035 $a(PQKB)10753682 035 $a(MiAaPQ)EBC1192230 035 $a(PPN)176625003 035 $a(Au-PeEL)EBL1192230 035 $a(CaPaEBR)ebr10716854 035 $a(CaONFJC)MIL493387 035 $a(OCoLC)850162073 035 $a(EXLCZ)992660000000011255 100 $a20130613d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 04$aThe science and technology of rubber$b[electronic resource]$fedited by Burak Erman, James E. Mark, C. Michael Roland 205 $a4th ed. 210 $aOxford, England $cAcademic Press$dc2013 215 $a1 online resource (816 p.) 300 $aDescription based upon print version of record. 311 $a0-12-394584-4 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aHalf Title; Title Page; Copyright; Contents; Rubber Elasticity: Basic Concepts and Behavior; 1.1 Introduction; 1.2 Elasticity of a Single Molecule; 1.3 Elasticity of a Three-Dimensional Network of Polymer Molecules; 1.4 Comparison with Experiment; 1.5 Continuum Theory of Rubber Elasticity; 1.5.1 Stress-Strain Relations; (i) Strain-Hardening at Large Strains; (ii) Inflation of a Thin-Walled Tube; (iii) Inflation of a Thin-Walled Spherical Balloon; (iv) Inflation of a Thick-Walled Spherical Shell; (v) Surface Instability of Compressed or Bent Blocks 327 $a(vi) Resistance of a Compressed Block to Indentation(vii) Torsional Instability of Stretched Rubber Rods (Gent and Hua 2004); 1.6 Second-Order Stresses; 1.7 Elastic Behavior Under Small Deformations; 1.8 Some Unsolved Problems in Rubber Elasticity; Acknowledgments; References; Further Reading; Polymerization: Elastomer Synthesis; 2.1 Introduction; 2.2 Classification of Polymerization Reactions and Kinetic Considerations; 2.2.1 Polyaddition/Polycondensation; 2.2.2 Chain Polymerization; 2.3 Polyaddition/Polycondensation; 2.4 Chain Polymerization by Free Radical Mechanism; 2.4.1 General Kinetics 327 $a2.4.2 Molecular Weight Distribution2.4.3 Special Case of Diene Polymerization; 2.4.4 Controlled Radical Polymerization; 2.5 Emulsion Polymerization; 2.5.1 Mechanism and Kinetics; 2.5.2 Styrene-Butadiene Rubber; (i) Kinetics and Molecular Weights; (ii) Chain Microstructure; 2.5.3 Emulsion Polymerization of Chloroprene; (i) Kinetics; (ii) Chain Structure; 2.6 Copolymerization; 2.6.1 Kinetics; 2.6.2 Emulsion Copolymerization of Dienes; (i) Styrene-Butadiene (SBR); (ii) Butadiene-Acrylonitrile (Nitrile Rubber); (iii) Chloroprene; 2.7 Chain Polymerization by Cationic Mechanism 327 $a2.7.1 Mechanism and Kinetics2.7.2 Butyl Rubber; 2.7.3 Living Cationic Polymerizations; 2.7.4 Other Cationic Polymerizations: Heterocyclic Monomers; 2.8 Chain Polymerization by Anionic Mechanism; 2.8.1 Mechanism and Kinetics; 2.8.2 Chain Microstructure of Polydienes; 2.8.3 Copolymers of Butadiene; 2.8.4 Terminally Functional Polydienes; 2.9 Stereospecific Chain Polymerization and Copolymerization by Coordination Catalysts; 2.9.1 Mechanism and Kinetics; 2.9.2 Ethylene-Propylene Rubbers; 2.9.3 Polydienes; 2.9.4 Polyalkenamers; 2.10 Graft and Block Copolymerization * 327 $a2.10.1 Graft Copolymerization by Conventional Free Radical Reactions(i) Chemical Initiation; (ii) Other Methods; 2.10.2 Block Copolymers by Controlled Radical Mechanisms; 2.10.3 Block Copolymers by Anionic Mechanism; 2.10.4 Block Copolymers by Cationic Mechanism; 2.10.5 Block Copolymers by Ziegler-Natta (Insertion) Mechanism; References; Structure Characterization in the Science and Technology of Elastomers; 3.1 Introduction; 3.2 Chemical Composition; 3.3 Sequence Distribution of Repeat Units; 3.4 Chain Architecture; 3.4.1 Molecular Weight and Its Distribution; 3.4.2 Branching; 3.4.3 Gel 327 $a3.5 Glass Transition and Secondary Relaxation Processes 330 $aThe 4e of The Science and Technology of Rubber provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in previous editions, the emphasis remains on a unified treatment of the material, exploring chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Updated material stresses the continuous relationship between ongoing research in synthesis, physics, stru 606 $aRubber 608 $aElectronic books. 615 0$aRubber. 676 $a678/.2 701 $aErman$b Burak$0863318 701 $aMark$b James E$022309 701 $aRoland$b C. Michael$0880037 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910459106203321 996 $aThe science and technology of rubber$91965095 997 $aUNINA