LEADER 05452nam 2200673 a 450 001 9910458227003321 005 20200520144314.0 010 $a1-280-70444-6 010 $a0-19-534645-9 035 $a(CKB)1000000000399273 035 $a(EBL)422517 035 $a(OCoLC)437108759 035 $a(SSID)ssj0000284376 035 $a(PQKBManifestationID)11193714 035 $a(PQKBTitleCode)TC0000284376 035 $a(PQKBWorkID)10261089 035 $a(PQKB)10441088 035 $a(MiAaPQ)EBC422517 035 $a(PPN)140017860 035 $a(Au-PeEL)EBL422517 035 $a(CaPaEBR)ebr10233741 035 $a(CaONFJC)MIL70444 035 $a(EXLCZ)991000000000399273 100 $a20041018d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSpectra of atoms and molecules$b[electronic resource] /$fPeter F. Bernath 205 $a2nd ed. 210 $aNew York $cOxford University Press$dc2005 215 $a1 online resource (454 p.) 300 $aDescription based upon print version of record. 311 $a0-19-517759-2 320 $aIncludes bibliographical references and index. 327 $aContents; 1 Introduction; 1.1 Waves, Particles, and Units; 1.2 The Electromagnetic Spectrum; 1.3 Interaction of Radiation with Matter; Blackbody Radiation; Einstein A and B Coefficients; Absorption and Emission of Radiation; Beer's Law; Lineshape Functions; Natural Lifetime Broadening; Pressure Broadening; Doppler Broadening; Transit-Time Broadening; Power Broadening; 2 Molecular Symmetry; 2.1 Symmetry Operations; Operator Algebra; Symmetry Operator Algebra; 2.2 Groups; Point Groups; Classes; Subgroups; 2.3 Notation for Point Groups; 3 Matrix Representation of Groups; 3.1 Vectors and Matrices 327 $aMatrix Eigenvalue ProblemSimilarity Transformations; 3.2 Symmetry Operations and Position Vectors; Reflection; Rotation; Inversion; Rotation-Reflection; Identity; 3.3 Symmetry Operators and Basis Vectors; 3.4 Symmetry Operators and Basis Functions; Function Spaces; Gram-Schmidt Procedure; Transformation Operators; 3.5 Equivalent, Reducible, and Irreducible Representations; Equivalent Representations; Unitary Representations; Reducible and Irreducible Representations; 3.6 Great Orthogonality Theorem; Characters; 3.7 Character Tables; Mulliken Notation; 4 Quantum Mechanics and Group Theory 327 $a4.1 Matrix Representation of the Schro?dinger Equation4.2 Born-Oppenheimer Approximation; 4.3 Symmetry of the Hamiltonian Operator; 4.4 Projection Operators; 4.5 Direct Product Representations; 4.6 Integrals and Selection Rules; 5 Atomic Spectroscopy; 5.1 Background; 5.2 Angular Momentum; 5.3 The Hydrogen Atom and One-Electron Spectra; Vector Model; Spin-Orbit Coupling; 5.4 Many-Electron Atoms; 5.5 Selection Rules; 5.6 Atomic Spectra; Hyperfine Structure; Hydrogen Atom; 5.7 Intensity of Atomic Lines; 5.8 Zeeman Effect; Paschen-Back Effect; 5.9 Stark Effect; 6 Rotational Spectroscopy 327 $a6.1 Rotation of Rigid Bodies6.2 Diatomic and Linear Molecules; Selection Rules; Centrifugal Distortion; Vibrational Angular Momentum; 6.3 Line Intensities for Diatomic and Linear Molecules; 6.4 Symmetric Tops; Molecule and Space-Fixed Angular Momenta; Rotational Spectra; Centrifugal Distortion; Line Intensity; 6.5 Asymmetric Tops; Selection Rules; Line Intensity; 6.6 Structure Determination; 7 Vibrational Spectroscopy; 7.1 Diatomic Molecules; Wavefunctions for Harmonic and Anharmonic Oscillators; Vibrational Selection Rules for Diatomics; Dissociation Energies from Spectroscopic Data 327 $aVibration-Rotation Transitions of DiatomicsCombination Differences; 7.2 Vibrational Motion of Polyatomic Molecules; Classical Mechanical Description; Quantum Mechanical Description; Internal Coordinates; Symmetry Coordinates; Symmetry of Normal Modes; Selection Rules for Vibrational Transitions; Vibration-Rotation Transitions of Linear Molecules; Nuclear Spin Statistics; Excited Vibrational States of Linear Molecules; 7.3 Vibrational Spectra of Symmetric Tops; Coriolis Interactions in Molecules; 7.4 Infrared Transitions of Spherical Tops; 7.5 Vibrational Spectra of Asymmetric Tops 327 $a7.6 Vibration-Rotation Line Intensities 330 $a1. Introduction. 1.1. Waves, Particles, and Units. 1.2. The Electromagnetic Spectrum. 1.3. Interaction of Radiation with Matter. 1.3a. Blackbody Radiation. 1.3b. Einstein A and B Coefficients. 1.3c. Absorption and Emission of Radiation. 1.3d. Beer's Law. 1.3e. Lineshape Functions. 1.3f. Natural Lifetime Broadening. 1.3g. Pressure Broadening. 1.3h. Doppler Broadening. 1.3i. Transit-Time Broadening. 1.3j. Power Broadening. 2. Molecular Symmetry. 2.1. Symmetry Operations. 2.1a. Operator Algebra. 2.1b. Symmetry Operator Algebra. 2.2. Groups. 2.2a. Point Groups. 2.2b. Classes. 2.2c. Subgroups. 2.3. 606 $aAtomic spectroscopy$vTextbooks 606 $aMolecular spectroscopy$vTextbooks 606 $aSpectrum analysis$vTextbooks 608 $aElectronic books. 615 0$aAtomic spectroscopy 615 0$aMolecular spectroscopy 615 0$aSpectrum analysis 676 $a535.8/4 700 $aBernath$b Peter F$0752594 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910458227003321 996 $aSpectra of atoms and molecules$91513407 997 $aUNINA