LEADER 05430nam 22006973u 450 001 9910458134003321 005 20210114064154.0 010 $a1-281-03846-6 010 $a9786611038465 010 $a0-08-050098-6 035 $a(CKB)1000000000363756 035 $a(EBL)312759 035 $a(OCoLC)476100759 035 $a(SSID)ssj0000120482 035 $a(PQKBManifestationID)11141043 035 $a(PQKBTitleCode)TC0000120482 035 $a(PQKBWorkID)10091778 035 $a(PQKB)11658995 035 $a(MiAaPQ)EBC312759 035 $a(PPN)182568709 035 $a(EXLCZ)991000000000363756 100 $a20140113d2000|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aChemical Thermodynamics$b[electronic resource] $ePrinciples and Applications 210 $aBurlington $cElsevier Science$d2000 215 $a1 online resource (689 p.) 300 $aDescription based upon print version of record. 311 $a0-12-530990-2 327 $aFront Cover; Chemical Thermodynamics: Principles and Applications; Copyright Page; Contents; Preface to the Two-Volume Series; Preface to the First Volume; Chapter 1. Introduction; 1.1 Thermodynamics - A Pre-eminent Example of an Exact Science; 1.2 The Language of Thermodynamics; 1.3 Thermodynamic Variables; 1.4 The Mathematics of Thermodynamics; 1.5 Derivation of Thermodynamic Equations using the Properties of the Exact Differential; 1.6 Calculation of Changes in the Thermodynamic Variable; 1.7 Use of Units; References; Chapter 2. The First and Second Laws of Thermodynamics 327 $a2.1 The First Law of Thermodynamics2.2 The Second Law of Thermodynamics; 2.3 Implications of the Laws; References; Chapter 3. Thermodynamic Relationships and Applications; 3.1 The Gibbs Equations; 3.2 Partial Differential Relationships; 3.3 Applications of the Differential Relationships; 3.4 Relationship Between Free Energy and Work; References; Chapter 4. The Third Law and Absolute Entropy Measurements; 4.1 Verification of the Third Law; 4.2 Exceptions to the Third Law; 4.3 Implications and Applications of the Third Law; 4.4 Production of Low Temperatures and the Inaccessibility of Absolute 327 $a4.5 Thermodynamic Functions References; Chapter 5. The Chemical Potential and Equilibrium; 5.1 Composition as a Variable; 5.2 The Chemical Potential; 5.3 Partial Molar Properties; 5.4 The Gibbs-Duhem Equation; 5.5 Determination of Partial Molar Properties; 5.6 Criteria for Equilibrium; References; Chapter 6. Fugacity, Activity, and Standard States; 6.1 Fugacity; 6.2 The Activity; 6.3 Standard States; 6.4 Activities of Electrolyte Solutions; 6.5 Determination of Activity; References; Chapter 7. The Thermodynamic Properties of Solutions 327 $a7.1 Change in the Thermodynamic Properties of Nonelectrolyte Solutions due to the Mixing Process7.2 Calculation of the Thermodynamic Properties of Strong Electrolyte Solutes: The Debye - Hu?ckel Theory; 7.3 Relative Partial Molar and Apparent Relative Partial Molar Thermal Properties; 7.4 The Osmotic Pressure; References; Chapter 8. The Equilibrium Condition Applied to Phase Equilibria; 8.1 Phase Equilibria for Pure Substances; 8.2 Phase Equilibria for Mixtures; References; Chapter 9. The Equilibrium Condition Applied to Chemical Processes; 9.1 The Equilibrium Constant 327 $a9.2 Enthalpies and Gibbs Free Energies of Formation9.3 Examples of Chemical Equilibrium Calculations; 9.4 Electrochemical Cells; References; Chapter 10. Statistical Thermodynamics; 10.1 Energy Levels of an Ideal Gas Molecule; 10.2 Distribution of Energy Among Energy Levels; 10.3 The Boltzmann Distribution Law; 10.4 The Partition Function; 10.5 Relationship Between the Partition Function and the Thermodynamic Properties; 10.6 Evaluation of the Partition Function for the Ideal Gas; 10.7 Calculation of the Thermodynamic Properties of the Ideal Gas 327 $a10.8 Calculation of the Thermodynamic Properties of Solids 330 $aChemical Thermodynamics: Principles and Applications presents a thorough development of the principles of thermodynamics--an old science to which the authors include the most modern applications, along with those of importance in developing the science and those of historical interest. The text is written in an informal but rigorous style, including anecdotes about some of the great thermodynamicists (with some of whom the authors have had a personal relationship), and focuses on ""real"" systems in the discussion and figures, in contrast to the generic examples that are often use 606 $aChemistry, Physical and theoretical 606 $aThermodynamics 606 $aChemistry$2HILCC 606 $aPhysical Sciences & Mathematics$2HILCC 606 $aPhysical & Theoretical Chemistry$2HILCC 608 $aElectronic books. 615 4$aChemistry, Physical and theoretical. 615 4$aThermodynamics. 615 7$aChemistry 615 7$aPhysical Sciences & Mathematics 615 7$aPhysical & Theoretical Chemistry 676 $a541.3/69 21 676 $a541.369 700 $aOtt$b J. Bevan$0945249 701 $aBoerio-Goates$b Juliana$0945250 801 0$bAU-PeEL 801 1$bAU-PeEL 801 2$bAU-PeEL 906 $aBOOK 912 $a9910458134003321 996 $aChemical Thermodynamics$92133909 997 $aUNINA