LEADER 03414nam 2200613 a 450 001 9910457267503321 005 20200520144314.0 010 $a981-4322-95-4 035 $a(CKB)2550000000087462 035 $a(EBL)846141 035 $a(OCoLC)858227678 035 $a(SSID)ssj0000599563 035 $a(PQKBManifestationID)11399315 035 $a(PQKBTitleCode)TC0000599563 035 $a(PQKBWorkID)10596706 035 $a(PQKB)11383519 035 $a(MiAaPQ)EBC846141 035 $a(WSP)00007902 035 $a(Au-PeEL)EBL846141 035 $a(CaPaEBR)ebr10529373 035 $a(CaONFJC)MIL498448 035 $a(EXLCZ)992550000000087462 100 $a20120209d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMolecular cluster magnets$b[electronic resource] /$feditor, Richard Winpenny 210 $aSingapore ;$aHackensack, N.J. $cWorld Scientific Pub.$dc2012 215 $a1 online resource (312 p.) 225 1 $aWorld Scientific series in nanoscience and nanotechnology ;$vv. 3 300 $aDescription based upon print version of record. 311 $a981-4322-94-6 320 $aIncludes bibliographical references and index. 327 $a3 Further SMMs Based on Mn(III)3.1 The largest SMM; a [Mn84] torus; 3.2 Record spin number, ST = 83/2, but no slow relaxation; 3.3 Record magnetic anisotropy barrier; a Mn6 cluster; 3.4 Quantum entanglement between SMMs; first discovered in a pair of Mn4 clusters; 3.5 [MnIII 3 MnIV] clusters with an S = 9/2 ground state; 3.6 The [MnIII 2 MnII 2 ] family of "rhombic" SMMs; 3.7 Oxime bridged SMMs with the core [MnIII 3 O] and ST = 6; 3.8 Magnetostructural correlations within a family of [MnIII 6 ] SMMs; 4 MMs Based on Fe(III) Ions; 5 New SMMs Based on Divalent 3d-Ions 327 $a6 Slow Relaxation in Complexes Involving 4f-Elements6.1 Single atom magnets; 6.2 Polymetallic 4f-complexes; 6.3 Heterometallic 3d-4f SMMs; 7 Metallocyanate Based SMMs; 8 Conclusions; References; 3. The Nanoscopic V15 Cluster: A Unique Magnetic Polyoxometalate Boris Tsukerblat and Alex Tarantul; 1 The Unique Magnetic Polyoxometalate V15; 2 Structure and Superexchange Pathways; 3 Exchange Interactions within the Triangle Model; 3.1 Isotropic exchange within the triangle model; 3.2 'Accidental' degeneracy and spin-frustration; 3.3 Pseudo-angular momentum representation 327 $a3.4 Antisymmetric exchange, zero-field splitting 330 $aThis work covers new developments in the field of molecular nanomagnetism, complementing previous books in this area (for example the volume by Gatteschi, Sessoli and Villain on Single Molecule Magnets). The book is written by experts in the field and is intended as a compilation of critical reviews of new areas rather than a comprehensive text. 410 0$aWorld Scientific series in nanoscience and nanotechnology ;$vv. 3. 606 $aNanostructured materials$xMagnetic properties 606 $aMagnetochemistry 608 $aElectronic books. 615 0$aNanostructured materials$xMagnetic properties. 615 0$aMagnetochemistry. 676 $a541.378 701 $aWinpenny$b Richard$0868905 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910457267503321 996 $aMolecular cluster magnets$91939798 997 $aUNINA