LEADER 05166nam 22006253u 450 001 9910455102703321 005 20210913130054.0 010 $a1-282-46098-6 010 $a9780470519318 010 $a9786612460982 010 $a0-470-68713-4 035 $a(CKB)1000000000822274 035 $a(EBL)470613 035 $a(OCoLC)501316338 035 $a(MiAaPQ)EBC470613 035 $a(PPN)140799354 035 $a(EXLCZ)991000000000822274 100 $a20131230d2010|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 200 10$aIntroduction to Coordination Chemistry$b[electronic resource] 210 $aHoboken $cWiley$d2010 215 $a1 online resource (306 p.) 225 1 $aInorganic Chemistry: A Textbook Series 300 $aDescription based upon print version of record. 311 $a0-470-51931-2 327 $aIntroduction to Coordination Chemistry; Contents; Preface; Preamble; 1 The Central Atom; 1.1 Key Concepts in Coordination Chemistry; 1.2 A Who's Who of Metal Ions; 1.2.1 Commoners and 'Uncommoners'; 1.2.2 Redefining Commoners; 1.3 Metals in Molecules; 1.3.1 Metals in the Natural World; 1.3.2 Metals in Contrived Environments; 1.3.3 Natural or Made-to-Measure Complexes; 1.4 The Road Ahead; Concept Keys; Further Reading; 2 Ligands; 2.1 Membership: Being a Ligand; 2.1.1 What Makes a Ligand?; 2.1.2 Making Attachments - Coordination; 2.1.3 Putting the Bite on Metals - Chelation 327 $a2.1.4 Do I Look Big on That? - Chelate Ring Size2.1.5 Different Tribes - Donor Group Variation; 2.1.6 Ligands with More Bite - Denticity; 2.2 Monodentate Ligands - The Simple Type; 2.2.1 Basic Binders; 2.2.2 Amines Ain't Ammines - Ligand Families; 2.2.3 Meeting More Metals - Bridging Ligands; 2.3 Greed is Good - Polydentate Ligands; 2.3.1 The Simple Chelate; 2.3.2 More Teeth, Stronger Bite - Polydentates; 2.3.3 Many-Armed Monsters - Introducing Ligand Shape; 2.4 Polynucleating Species - Molecular Bigamists; 2.4.1 When One is Not Enough; 2.4.2 Vive la Difference - Mixed-metal Complexation 327 $a2.4.3 Supersized - Binding to Macromolecules2.5 A Separate Race - Organometallic Species; Concept Keys; Further Reading; 3 Complexes; 3.1 The Central Metal Ion; 3.2 Metal-Ligand Marriage; 3.2.1 The Coordinate Bond; 3.2.2 The Foundation of Coordination Chemistry; 3.2.3 Complex Shape - Not Just Any Which Way; 3.3 Holding On - The Nature of Bonding in Metal Complexes; 3.3.1 An Ionic Bonding Model - Introducing Crystal Field Theory; 3.3.2 A Covalent Bonding Model - Embracing Molecular Orbital Theory; 3.3.3 Ligand Field Theory - Making Compromises; 3.3.4 Bonding Models Extended 327 $a3.4 Coupling - Polymetallic Complexes3.5 Making Choices; 3.5.1 Selectivity - Of all the Molecules in all the World, Why This One?; 3.5.2 Preferences - Do You Like What I Like?; 3.5.3 Complex Lifetimes - Together, Forever?; 3.6 Complexation Consequences; Concept Keys; Further Reading; 4 Shape; 4.1 Getting in Shape; 4.2 Forms of Complex Life - Coordination Number and Shape; 4.2.1 One Coordination (ML); 4.2.2 Two Coordination (ML2); 4.2.3 Three Coordination (ML3); 4.2.4 Four Coordination (ML4); 4.2.5 Five Coordination (ML5); 4.2.6 Six Coordination (ML6) 327 $a4.2.7 Higher Coordination Numbers (ML7 to ML9)4.3 Influencing Shape; 4.3.1 Metallic Genetics - Metal Ion Influences; 4.3.2 Moulding a Relationship - Ligand Influences; 4.3.3 Chameleon Complexes; 4.4 Isomerism - Real 3D Effects; 4.4.1 Introducing Stereoisomers; 4.4.2 Constitutional (Structural) Isomerism; 4.4.3 Stereoisomerism: in Place - Positional Isomers; in Space - Optical Isomers; 4.4.4 What's Best? - Isomer Preferences; 4.5 Sophisticated Shapes; 4.5.1 Compounds of Polydentate Ligands; 4.5.2 Encapsulation Compounds; 4.5.3 Host-Guest Molecular Assemblies; 4.6 Defining Shape; Concept Keys 327 $aFurther Reading 330 $aAt the heart of coordination chemistry lies the coordinate bond, in its simplest sense arising from donation of a pair of electrons from a donor atom to an empty orbital on a central metalloid or metal. Metals overwhelmingly exist as their cations, but these are rarely met 'naked' - they are clothed in an array of other atoms, molecules or ions that involve coordinate covalent bonds (hence the name coordination compounds). These metal ion complexes are ubiquitous in nature, and are central to an array of natural and synthetic reactions. Written in a highly readable, descriptive and access 410 0$aInorganic Chemistry: A Textbook Series 606 $aChemistry 606 $aCoordination 606 $aCoordination compounds 606 $aCoordination compounds 606 $aLigands 608 $aElectronic books. 615 4$aChemistry. 615 4$aCoordination. 615 4$aCoordination compounds. 615 4$aCoordination compounds. 615 4$aLigands. 700 $aLawrance$b Geoffrey A$0861888 801 0$bAU-PeEL 801 1$bAU-PeEL 801 2$bAU-PeEL 801 2$bNUWS:W 801 2$bBUAL 906 $aBOOK 912 $a9910455102703321 996 $aIntroduction to Coordination Chemistry$91923551 997 $aUNINA LEADER 03260nam 2200565 a 450 001 9910781310703321 005 20230725050502.0 010 $a94-012-0053-X 024 7 $a10.1163/9789401200530 035 $a(CKB)2550000000039530 035 $a(EBL)735597 035 $a(OCoLC)741493005 035 $a(SSID)ssj0000525185 035 $a(PQKBManifestationID)12177034 035 $a(PQKBTitleCode)TC0000525185 035 $a(PQKBWorkID)10504095 035 $a(PQKB)10136948 035 $a(MiAaPQ)EBC735597 035 $a(OCoLC)741940776 035 $a(nllekb)BRILL9789401200530 035 $a(Au-PeEL)EBL735597 035 $a(CaPaEBR)ebr10483633 035 $a(EXLCZ)992550000000039530 100 $a20110729d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aRadical visions 1968-2008$b[electronic resource] $ethe impact of the sixties on Australian drama /$fDenise Varney 210 $aAmsterdam $cRodopi$d2011 215 $a1 online resource (293 p.) 225 1 $aAustralian playwrights ;$vv. 13 300 $aDescription based upon print version of record. 311 $a90-420-3354-1 320 $aIncludes bibliographical references and index. 327 $aPreliminary Material -- List of Figures -- Series Editor?s Preface -- Acknowledgements -- Introduction -- The International Generation of 1968: Theatre and Culture -- The Australian Performing Group and Its Legacy, 1968?2008 -- Williamson in the Howard Years -- John Romeril ? The Asian Australian Journey -- A Parallel Forty-Year Female Narrative with Alma De Groen -- Richard Murphet and the Wounded Subject -- Jenny Kemp ? On the Edge -- Stephen Sewell and the State of the Nation -- Conclusion -- Bibliography -- Index. 330 $aRadical Visions 1968-2008: The Impact of the Sixties on Australian Drama is about a generation of Australian playwrights who came of age in the sixties. This important book shows how international trends in youth radicalism and cultural change at the time contributed to the rise of interest in alternative theatre and drama in a number of locations. It follows the career of Australia?s major playwrights ? Alma De Groen, Jenny Kemp, Richard Murphet, John Romeril, Stephen Sewell and David Williamson ? whose early plays were first performed at La Mama and the Pram Factory theatres in Melbourne in the sixties and seventies and who continue to make new work. The book?s dual purpose is to examine the impact of the sixties on playwriting and update the scholarship on the contemporary works with close readings of the plays of the nineties and the first decade of the twenty-first century. By analysing the recent plays, the book traces the continuing impact of left wing politics and cultural change on Australian theatre and society. 410 0$aAustralian playwrights ;$vmonograph no. 13. 606 $aAustralian drama$y20th century 615 0$aAustralian drama 676 $a882/.009 700 $aVarney$b Denise$01463176 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910781310703321 996 $aRadical visions 1968-2008$93672406 997 $aUNINA