LEADER 04829nam 22006855 450 001 9910454960903321 005 20200702204818.0 010 $a9786610204878 010 $a1-59124-820-5 010 $a1-280-20487-7 024 7 $a10.1007/0-306-46945-6 035 $a(CKB)111056485445092 035 $a(EBL)3035341 035 $a(SSID)ssj0000071356 035 $a(PQKBManifestationID)11110004 035 $a(PQKBTitleCode)TC0000071356 035 $a(PQKBWorkID)10090614 035 $a(PQKB)10087242 035 $a(DE-He213)978-0-306-46945-9 035 $a(OCoLC)55663958 035 $a(MiAaPQ)EBC3035341 035 $a(PPN)237935376 035 $a(EXLCZ)99111056485445092 100 $a20100301d2000 u| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aActivation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes$b[electronic resource] /$fby A.E. Shilov, Georgiy B. Shul'pin 205 $a1st ed. 2000. 210 1$aDordrecht :$cSpringer Netherlands :$cImprint: Springer,$d2000. 215 $a1 online resource (551 p.) 225 1 $aCatalysis by Metal Complexes,$x0920-4652 ;$v21 300 $aDescription based upon print version of record. 311 $a0-7923-6101-6 311 $a0-306-46945-6 320 $aIncludes bibliographical references and index. 327 $aProcesses of C-H Bond Activation -- Hydrocarbon Transformations That do not Involve Metals or Their Compounds -- Heterogeneous Hydrocarbon Reactions with Participation of Solid Metals and Metal Oxides -- Activation of C-H Bonds by Low-valent Metal Complexes (?The Organometallic Chemistry?) -- Hydrocarbon Activation by Metal Ions, Atoms, and Complexes in the Gas Phase and in a Matrix -- Mechanisms of C-H Bond Splitting by Low-valent Metal Complexes -- Activation of Hydrocarbons by Platinum Complexes -- Hydrocarbon Reactions with High-valent Metal Complexes -- Homogeneous Catalytic Oxidation of Hydrocarbons by Molecular Oxygen -- Homogeneous Catalytic Oxidation of Hydrocarbons by Peroxides and Other Oxygen Atom Donors -- Oxidation in Living Cells and its Chemical Models. 330 $ahemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C?H, as well as C?C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the ?noble gases of organic chemistry? and, if so, the first representative of their family ? methane ? may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning ? the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300?500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process ? but not from a chemist viewpoint. 410 0$aCatalysis by Metal Complexes,$x0920-4652 ;$v21 606 $aPhysical chemistry 606 $aInorganic chemistry 606 $aOrganic chemistry 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aInorganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C16008 606 $aOrganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19007 615 0$aPhysical chemistry. 615 0$aInorganic chemistry. 615 0$aOrganic chemistry. 615 14$aPhysical Chemistry. 615 24$aInorganic Chemistry. 615 24$aOrganic Chemistry. 676 $a547/.4110459 700 $aShilov$b A.E$4aut$4http://id.loc.gov/vocabulary/relators/aut$0851089 702 $aShul'pin$b Georgiy B$4aut$4http://id.loc.gov/vocabulary/relators/aut 906 $aBOOK 912 $a9910454960903321 996 $aActivation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes$91900232 997 $aUNINA LEADER 02860nam 2200625 450 001 9910453108303321 005 20200903223051.0 010 $a1-61499-244-4 035 $a(CKB)2550000001115658 035 $a(EBL)1441797 035 $a(OCoLC)859343457 035 $a(SSID)ssj0000967841 035 $a(PQKBManifestationID)12374380 035 $a(PQKBTitleCode)TC0000967841 035 $a(PQKBWorkID)10977090 035 $a(PQKB)11172444 035 $a(MiAaPQ)EBC1441797 035 $a(Au-PeEL)EBL1441797 035 $a(CaPaEBR)ebr10767162 035 $a(CaONFJC)MIL515993 035 $a(EXLCZ)992550000001115658 100 $a20130405h20132013 uy| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt 182 $cc 183 $acr 200 00$aICT, public administration and democracy in the coming decade /$fedited by Albert J. Meijer, Frank Bannister, Marcel Thaens 210 1$aWashington, DC :$cIOS Press,$d[2013] 210 4$d©2013 215 $a1 online resource (164 p.) 225 1 $aInnovation and the public sector,$x1871-1073 ;$vvolume 20 300 $aDescription based upon print version of record. 311 $a1-61499-243-6 311 $a1-299-84742-0 320 $aIncludes bibliographical references and indexes. 327 $asection 1. The past and the present situation as starting point for thinking about the future -- section 2. The future implications of e-government for government institutions -- section 3. The future implications for our e-government research and practice. 330 $aThe physicist Neils Bohr allegedly wrote that "Prediction is very difficult, especially about the future". Many academics believe that serious scholars should never attempt to write about the future, but some awareness of the ways in which the future of e-government may evolve is needed if well-grounded long-term decisions about issues such as infrastructures, institutions and educational programs are to be made. In addition, future-oriented research is of the utmost importance for informed public debate about technological developments with far reaching societal implications. This book marks 410 0$aInnovation and the public sector ;$vv. 20. 606 $aGovernment communication systems 606 $aInformation technology$xPolitical aspects 608 $aElectronic books. 615 0$aGovernment communication systems. 615 0$aInformation technology$xPolitical aspects. 676 $a352.3802854678 701 $aMeijer$b Albert$0951279 701 $aBannister$b Frank$0876184 701 $aThaens$b Marcel$0915078 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910453108303321 996 $aICT, public administration and democracy in the coming decade$92296467 997 $aUNINA LEADER 01537nam a22002651i 4500 001 991001331829707536 005 20030226150342.0 008 021212s1976 xxc|||||||||||||||||fre 035 $ab12132433-39ule_inst 035 $aARCHE-022223$9ExL 040 $aDip.to Filologia Ling. e Lett.$bita$cA.t.i. Arché s.c.r.l. Pandora Sicilia s.r.l. 111 2 $aCongrès international de linguistique et philologie romanes$n<13. ;$d1971 ;$cQuebec>$0450604 245 10$aActes du 13. 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