LEADER 05307nam 2200685Ia 450 001 9910454282303321 005 20200520144314.0 010 $a1-281-93470-4 010 $a9786611934705 010 $a981-279-481-6 035 $a(CKB)1000000000537790 035 $a(EBL)1681634 035 $a(OCoLC)815752366 035 $a(SSID)ssj0000201652 035 $a(PQKBManifestationID)11184564 035 $a(PQKBTitleCode)TC0000201652 035 $a(PQKBWorkID)10245676 035 $a(PQKB)11578183 035 $a(MiAaPQ)EBC1681634 035 $a(WSP)00005515 035 $a(Au-PeEL)EBL1681634 035 $a(CaPaEBR)ebr10255525 035 $a(CaONFJC)MIL193470 035 $a(EXLCZ)991000000000537790 100 $a20040816d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMetal mediated template synthesis of ligands$b[electronic resource] /$fOtilia Costisor, Wolfgang Linert 210 $aSingapore ;$aRiver Edge, NJ $cWorld Scientific Pub. Co.$dc2004 215 $a1 online resource (307 p.) 300 $aDescription based upon print version of record 311 $a981-238-813-3 320 $aIncludes bibliographical references (p. 257-294) and index. 327 $aContents ; Preface ; The Template Effect ; 1.1. Types of Template Effects ; 1.2. The Template Effect as a Molecular Organizer Effect ; 1.3. Factors Affecting the Product of a Template Reaction ; 1.3.1. Coordination of ligands ; 1.3.2. The chelate effect ; 1.3.3. Macrocyclic effect 327 $a1.4. The Negative Template Effect 1.5. Advantages of Metal Template Reaction ; Alkylation Reactions ; 2.1. Alkylation of the Nitrogen Atom ; 2.2. Alkylation of the Sulfur Atom ; 2.2.1. Open chain systems ; 2.2.2. Macrocyclic ligands ; Schiff Condensation ; 3.1. Mechanistic Aspects 327 $a3.2. Open-chain Ligands 3.3. Macrocyclic Ligands ; 3.3.1 Diimine macrocycles ; 3.3.2. Tetraimine macrocycles ; 3.4. Cage Ligands ; 3.5 Compartmental Ligands ; 3.5.1. Closed-chain ligands ; 3.5.2. Open chain ligands ; Mannich Condensation ; 4.1. Mechanistic Aspects 327 $a4.2 Acyclic Ligands 4.2.1. Polyamine ligands ; 4.2.2. NO donor ligands ; 4.2.3. SN donor ligands ; 4.3. Monocyclic Ligands ; 4.3.1. Tetraaza macrocycles ; 4.3.2. Pentaaza macrocycles ; 4.3.3. Hexaaza macrocycles ; 4.3.4. Octaaza macrocycles ; 4.3.5. Azaether macrocycle 327 $a4.3.6. Azathioether macrocycle 4.3.7. Reinforced macrocycles ; 4.3.8. Macromonocyclic dicompartmental ligands ; 4.4. Isolated Dimacrocycles ; 4.5.Condensed Polymacrocyclic Ligands ; 4.5.1. Carbon and nitrogen caped amine ligands ; 4.5.2. P- As amine cage ligands 327 $a4.5.3. Thioamine cage ligands 330 $aThis book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role 606 $aOrganometallic compounds$xSynthesis 606 $aOrganic compounds$xSynthesis 608 $aElectronic books. 615 0$aOrganometallic compounds$xSynthesis. 615 0$aOrganic compounds$xSynthesis. 676 $a541.2242 676 $a547.05 676 $a547/.05 700 $aCostisor$b Otilia$0997103 701 $aLinert$b W$0997104 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910454282303321 996 $aMetal mediated template synthesis of ligands$92286600 997 $aUNINA