LEADER 04454nam 22006731 450 001 9910453729503321 005 20200520144314.0 010 $a1-78326-431-4 010 $a1-84816-306-1 035 $a(CKB)2550000001168283 035 $a(EBL)1578313 035 $a(SSID)ssj0001001004 035 $a(PQKBManifestationID)11640073 035 $a(PQKBTitleCode)TC0001001004 035 $a(PQKBWorkID)10962202 035 $a(PQKB)10145431 035 $a(MiAaPQ)EBC1578313 035 $a(WSP)0000P603 035 $a(Au-PeEL)EBL1578313 035 $a(CaPaEBR)ebr10813518 035 $a(CaONFJC)MIL549549 035 $a(OCoLC)865335040 035 $a(EXLCZ)992550000001168283 100 $a20131212h20142014 uy 0 101 0 $aeng 135 $aur|n||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMaterials under extreme conditions $emolecular crystals at high pressure /$fRoberto Bini, Vincenzo Schettino 210 1$aLondon :$cImperial College Press,$d[2014] 210 4$dİ2014 215 $a1 online resource (373 p.) 300 $aDescription based upon print version of record. 311 $a1-84816-305-3 311 $a1-306-18298-0 320 $aIncludes bibliographical references and index. 327 $aPreface; Foreword; Acknowledgments; Contents; 1. Introduction; 2. Historical Survey; 3. Elasticity and Equation of State; 3.1 Stress and strain; 3.2 Elasticity and anisotropy in molecular crystals; 3.2.1 Elastic constants; 3.2.2 Temperature and pressure dependence of the elastic constants; 3.2.3 Single crystals and polycrystals; 3.2.4 Variation of crystal parameters with pressure; 3.3 Parametric equations of state; 4. High-pressure Technical Survey; 4.1 The piston-cylinder device; 4.1.1 Large volume piston-cylinder apparatus; 4.2 The opposed anvil devices; 4.3 Multi-anvil devices 327 $a4.4 The diamond anvil cell4.4.1 Diamonds; 4.4.2 Gasket; 4.4.3 Loading techniques; 4.4.4 Compression media; 4.5 High- and low-temperature techniques; 4.5.1 Low-temperature devices; 4.5.2 Resistive heating; 4.5.3 Laser heating; 4.6 Pressure measurement; 4.7 Probing techniques based on electromagnetic radiation; 4.7.1 Optical spectroscopy; 4.7.1.1 Infrared spectroscopy; 4.7.1.2 Raman and Brillouin spectroscopy; 4.7.1.3 Non-linear optical techniques; 4.7.2 X-ray diffraction; 4.7.3 Neutron diffraction; 4.7.4 Nuclear magnetic resonance; 5. Principles of Chemical Reactivity Under Pressure 327 $a5.1 Pressure effects on chemical equilibria5.2 Pressure effects on reaction rates; 5.3 Environmental effects at high pressure; 5.4 Effects of high pressure on the electronic structure; 6. Chemical Reactions in Molecular Crystals; 6.1 Reversible reactions; 6.1.1 Solid nitrogen at high pressure: the archetypal energetic material; 6.1.2 Red oxygen; 6.1.3 Carbon dioxide: a multiform solid; 6.1.4 Formic acid; 6.1.5 Sulphur. Polymeric and molecular phases; 6.1.6 Symmetry breaking and ionization at high pressures; 6.1.7 Metallization at high pressures; 6.2 Irreversible reactions 327 $a6.2.1 Unsaturated hydrocarbons6.2.2 Aromatics and heteroaromatics; 6.2.3 Miscellanea; 6.2.4 Energetic materials; 6.2.5 Photochemistry at high pressures; Bibliography; Appendix A; Index 330 $aHigh-pressure materials research has been revolutionized in the past few years due to technological breakthroughs in the diamond anvil cell (DAC), shock wave compression and molecular dynamic simulation (MD) methods. The application of high pressure, especially together with high temperature, has revealed exciting modifications of physical and chemical properties even in the simplest molecular materials. Besides the fundamental importance of these studies to understand the composition and the dynamics of heart and planets' interior, new materials possessing peculiar characteristics of hardness 606 $aHigh pressure chemistry 606 $aMaterials at high pressures 606 $aMolecular crystals 608 $aElectronic books. 615 0$aHigh pressure chemistry. 615 0$aMaterials at high pressures. 615 0$aMolecular crystals. 676 $a543 700 $aBini$b Roberto$0862073 701 $aSchettino$b Vincenzo$046808 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910453729503321 996 $aMaterials under extreme conditions$91924322 997 $aUNINA