LEADER 05560nam 2200685Ia 450 001 9910453203803321 005 20200520144314.0 010 $a1-281-93795-9 010 $a9786611937959 010 $a981-277-914-0 035 $a(CKB)1000000000538162 035 $a(EBL)1679520 035 $a(OCoLC)879023628 035 $a(SSID)ssj0000211826 035 $a(PQKBManifestationID)11174596 035 $a(PQKBTitleCode)TC0000211826 035 $a(PQKBWorkID)10135750 035 $a(PQKB)11580384 035 $a(MiAaPQ)EBC1679520 035 $a(WSP)00001855 035 $a(Au-PeEL)EBL1679520 035 $a(CaPaEBR)ebr10255981 035 $a(CaONFJC)MIL193795 035 $a(EXLCZ)991000000000538162 100 $a20080128d2008 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aNon-equilibrium thermodynamics of heterogeneous systems$b[electronic resource] /$fSigne Kjelstrup, Dick Bedeaux 210 $aHackensack, NJ $cWorld Scientific$dc2008 215 $a1 online resource (451 p.) 225 1 $aSeries on advances in statistical mechanics ;$vv. 16 300 $aDescription based upon print version of record. 311 $a981-277-913-2 320 $aIncludes bibliographical references (p. 393-413) and index. 327 $aContents; Preface; 1 Scope; 1.1 What is non-equilibrium thermodynamics?; 1.2 Non-equilibrium thermodynamics in the context of other theories; 1.3 The purpose of this book; 2 Why Non-Equilibrium Thermodynamics?; 2.1 Simple flux equations; 2.2 Flux equations with coupling terms; 2.3 Experimental designs and controls; 2.4 Entropy production, work and lost work; 2.5 Consistent thermodynamic models; 3 Thermodynamic Relations for Heterogeneous Systems; 3.1 Two homogeneous phases separated by a surface in global equilibrium; 3.2 The contact line in global equilibrium 327 $a3.3 Defining thermodynamic variables for the surface 3.4 Local thermodynamic identities; 3.5 Defining local equilibrium; 3.A Appendix: Partial molar properties; 3.A.1 Homogeneous phases; 3.A.2 The surface; 3.A.3 The standard state; Part A: General Theory; 4 The Entropy Production for a Homogeneous Phase; 4.1 Balance equations; 4.2 The entropy production; 4.2.1 Why one should not use the dissipation function; 4.2.2 States with minimum entropy production; 4.3 Examples; 4.4 Frames of reference for fluxes in homogeneous systems; 4.4.1 Definitions of frames of reference 327 $a4.4.2 Transformations between the frames of reference 4.A Appendix: The first law and the heat flux; 5 The Excess Entropy Production for the Surface; 5.1 The discrete nature of the surface; 5.2 The behavior of the electric fields and potential through the surface; 5.3 Balance equations; 5.4 The excess entropy production; 5.4.1 Reversible processes at the interface and the Nernst equation; 5.4.2 The surface potential jump at the hydrogen electrode; 5.5 Examples; 6 The Excess Entropy Production for a Three Phase Contact Line; 6.1 The discrete nature of the contact line; 6.2 Balance equations 327 $a6.3 The excess entropy production 6.4 Stationary states; 6.5 Concluding comment; 7 Flux Equations and Onsager Relations; 7.1 Flux-force relations; 7.2 Onsager's reciprocal relations; 7.3 Relaxation to equilibrium. Consequences of violating Onsager relations; 7.4 Force-flux relations; 7.5 Coefficient bounds; 7.6 The Curie principle applied to surfaces and contact lines; 8 Transport of Heat and Mass; 8.1 The homogeneous phases; 8.2 Coefficient values for homogeneous phases; 8.3 The surface; 8.3.1 Heats of transfer for the surface; 8.4 Solution for the heterogeneous system 327 $a8.5 Scaling relations between surface and bulk resistivities 9 Transport of Heat and Charg; 9.1 The homogeneous phases; 9.2 The surface; 9.3 Thermoelectric coolers; 9.4 Thermoelectric generators; 9.5 Solution for the heterogeneous system; 10 Transport of Mass and Charge; 10.1 The electrolyte; 10.2 The electrode surfaces; 10.3 Solution for the heterogeneous system; 10.4 A salt power plant; 10.5 Electric power from volume flow; 10.6 Ionic mobility model for the electrolyte; 10.7 Ionic and electronic model for the surface; Part B: Applications; 11 Evaporation and Condensation 327 $a11.1 Evaporation and condensation in a pure fluid 330 $aThe purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems. The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilib 410 0$aSeries on advances in statistical mechanics ;$vv. 16. 606 $aNonequilibrium thermodynamics 606 $aThermodynamics 608 $aElectronic books. 615 0$aNonequilibrium thermodynamics. 615 0$aThermodynamics. 676 $a536.7 700 $aKjelstrup$b Signe$0903219 701 $aBedeaux$b Dick$0771328 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910453203803321 996 $aNon-equilibrium thermodynamics of heterogeneous systems$92019052 997 $aUNINA