LEADER 04943nam 2200577 a 450 001 9910450780803321 005 20200520144314.0 010 $a981-277-840-3 035 $a(CKB)1000000000407622 035 $a(StDuBDS)AH24684815 035 $a(SSID)ssj0000211777 035 $a(PQKBManifestationID)11174594 035 $a(PQKBTitleCode)TC0000211777 035 $a(PQKBWorkID)10135823 035 $a(PQKB)11175594 035 $a(MiAaPQ)EBC1681264 035 $a(WSP)00004783 035 $a(Au-PeEL)EBL1681264 035 $a(CaPaEBR)ebr10201251 035 $a(CaONFJC)MIL505463 035 $a(OCoLC)879025085 035 $a(EXLCZ)991000000000407622 100 $a20020722d2002 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aNonadiabatic transition$b[electronic resource] $econcepts, basic theories and applications /$fby Hiroki Nakamura 210 $aRiver Edge, NJ $cWorld Scientific$dc2002 215 $a1 online resource (xi, 376 p. ) $cill 300 $aBibliographic Level Mode of Issuance: Monograph 311 $a981-02-4719-2 320 $aIncludes bibliographical references (p. 361-370) and index. 327 $ach. 1. Introduction: what is "nonadiabatic transition"? -- ch. 2. Multi-disciplinarity. 2.1. Physics. 2.2. Chemistry. 2.3. Biology. 2.4. Economics -- ch. 3. Historical survey of theoretical studies. 3.1. Landau-Zener-Stueckelberg theory. 3.2. Rosen-Zener-Demkov theory. 3.3. Nikitin's exponential model. 3.4. Nonadiabatic transition due to Coriolis coupling and dynamical state representation -- ch. 4. Background mathematics. 4.1. Wentzel-Kramers-Brillouin semiclassical theory. 4.2. Stokes phenomenon -- ch. 5. Basic two-state theory for time-independent processes. 5.1. Exact solutions of the linear curve crossing problems. 5.2. Complete semiclassical solutions of general curve crossing problems. 5.3. Non-curve-crossing case. 5.4. Exponential potential model. 5.5. Mathematical implications -- ch. 6. Basic two-state theory for time-dependent processes. 6.1. Exact solution of quadratic potential problem. 6.2. Semiclassical solution in general case. 6.3. Other exactly solvable models -- ch. 7. Two-state problems. 7.1. Diagrammatic technique. 7.2. Inelastic scattering. 7.3. Elastic scattering with resonances and predissociation. 7.4. Perturbed bound states. 7.5. Time-dependent periodic crossing problems -- ch. 8. Effects of dissipation and fluctuation -- ch. 9. Multi-channel problems. 9.1. Exactly solvable models. 9.2. Semiclassical theory of time-independent multi-channel problems. 9.3. Time-dependent problems -- ch. 10. Multi-dimensional problems. 10.1. Classification of surface crossing. 10.2. Reduction to one-dimensional multi-channel problem. 10.3. Semiclassical propagation method -- ch. 11. Complete reflection and bound states in the continuum. 11.1. One NT-type crossing case. 11.2. Diabatically avoided crossing (DAC) case. 11.3. Two NT-type crossings case -- ch. 12. New mechanism of molecular switching. 12.1. Basic idea. 12.2. One-dimensional model. 12.3. Two-dimensional model. 12.4. Numerical examples -- ch. 13. Control of nonadiabatic processes by an external field. 13.1. Control of nonadiabatic transitions by periodically sweeping external field. 13.2. Basic theory. 13.3. Numerical examples. 13.4. Laser control of photodissociation with use of the complete reflection phenomenon -- ch. 14. Conclusions: future perspectives. 330 $aAn exploration of the concepts, basic theories and applications of nonadiabatic transition. Nonadiabatic transition is a multidisciplinary concept and phenomenon, constituting a fundamental mechanism of state and phase changes in various dynamical processes of physics, chemistry and biology. 330 $bNonadiabatic transition is a highly multidisciplinary concept and phenomenon, constituting a fundamental mechanism of state and phase changes in various dynamical processes of physics, chemistry and biology, such as molecular dynamics, energy relaxation, chemical reaction, and electron and proton transfer. Control of molecular processes by laser fields is also an example of time-dependent nonadiabatic transition. Thus, nonadiabatic transition represents one of the very basic mechanisms of the mutability of the world. This work has been written because the complete analytical solutions to the basic problem have recently been formulated by the author. 606 $aCharge exchange 606 $aPhase transformations (Statistical physics) 608 $aElectronic books. 615 0$aCharge exchange. 615 0$aPhase transformations (Statistical physics) 676 $a530.4/74 700 $aNakamura$b Hiroki$0882209 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910450780803321 996 $aNonadiabatic transition$91970552 997 $aUNINA