LEADER 02741nam 2200577 a 450 001 9910437821503321 005 20200520144314.0 010 $a1-283-91033-0 010 $a3-642-33173-4 024 7 $a10.1007/978-3-642-33173-2 035 $a(CKB)2670000000279498 035 $a(EBL)1082659 035 $a(OCoLC)820861755 035 $a(SSID)ssj0000798965 035 $a(PQKBManifestationID)11462947 035 $a(PQKBTitleCode)TC0000798965 035 $a(PQKBWorkID)10755547 035 $a(PQKB)10593882 035 $a(DE-He213)978-3-642-33173-2 035 $a(MiAaPQ)EBC1082659 035 $a(PPN)168323745 035 $a(EXLCZ)992670000000279498 100 $a20120820d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aNovel selenium-mediated rearrangements and cyclisations /$fSohail Anjum Shahzad 205 $a1st ed. 2013. 210 $aNew York $cSpringer$d2013 215 $a1 online resource (207 p.) 225 1 $aSpringer theses : recognizing outstanding Ph.D. research,$x2190-5053 300 $aDescription based upon print version of record. 311 $a3-642-42874-6 311 $a3-642-33172-6 320 $aIncludes bibliographical references. 327 $aGeneral Introduction on Selenium.- The Synthesis of Novel Dihydronaphthalenes and Benzofluorenes -- The Synthesis of Naphthalenes and Biaryls -- Synthesis of Isocoumarins and Dihydroisocoumarins.- Experimental Section. 330 $aIn his thesis, Sohail Shahzad carefully investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. After a comprehensive introduction to the element selenium, the author goes on to report the synthesis of several substrates for carbocyclisation reactions and the use of selenium reagents for the preparation of dihydronaphthalenes. Further chapters detail electrophilic selenium-mediated reactions, and novel strategies using selenium catalysts together with stoichiometric amounts of hypervalent iodine reagents as oxidants to convert stilbene carbosylic acids into the corresponding isocoumarins. This thesis outlines some excellent new synthetic routes which will be useful tools for synthetic organic chemistry in the future. 410 0$aSpringer theses. 606 $aOrganic compounds$xSynthesis 615 0$aOrganic compounds$xSynthesis. 676 $a547.05724 700 $aShahzad$b Sohail Anjum$01063515 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910437821503321 996 $aNovel Selenium-Mediated Rearrangements and Cyclisations$92532850 997 $aUNINA