LEADER 05313nam 22007335 450 001 9910437813103321 005 20200704222508.0 010 $a1-283-93564-3 010 $a3-7091-1317-2 024 7 $a10.1007/978-3-7091-1317-2 035 $a(CKB)2670000000317279 035 $a(EBL)1030790 035 $a(OCoLC)827616964 035 $a(SSID)ssj0000879268 035 $a(PQKBManifestationID)11461448 035 $a(PQKBTitleCode)TC0000879268 035 $a(PQKBWorkID)10852949 035 $a(PQKB)10881127 035 $a(DE-He213)978-3-7091-1317-2 035 $a(MiAaPQ)EBC1030790 035 $a(PPN)168331454 035 $a(EXLCZ)992670000000317279 100 $a20121213d2013 u| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMaterial Designs and New Physical Properties in MX- and MMX-Chain Compounds /$fedited by Masahiro Yamashita, Hiroshi Okamoto 205 $a1st ed. 2013. 210 1$aVienna :$cSpringer Vienna :$cImprint: Springer,$d2013. 215 $a1 online resource (274 p.) 300 $aDescription based upon print version of record. 311 $a3-7091-1735-6 311 $a3-7091-1316-4 320 $aIncludes bibliographical references and index. 327 $a1 General Intoruduction S. Takaishi and M. Yamashita -- 2 MX-Chain Compounds -- 2.1 Pt(II)-Pt(IV) and Pd(II)-Pd(IV) Mixed-Valence Compounds H. Matsuzaki and H. Okamoto -- 2.2 Ni(III) Mott-Hubbard Compounds S. Takaishi and M. Yamashita -- 2.3 Pd(III) Mott-Hubbard Compounds S. Takaishi and M. Yamashita -- 2.4 Photoinduced Phase Transitions in MX-Chain Compounds H. Matsuzaki and H. Okamoto -- 2.5 Nonlinear Electrical Conductivity, Current Oscillation and Its Control in Halogen-Bridged Nickel(III) Compounds H. Kishida and A. Nakamura -- 2.6 Gigantic Third-Order Optical Nonlinearity of Halogen-Bridged Nickel(III) Compounds H. Kishida and H. Okamoto -- 2.7 Theory of MX-Chain Compounds K. Iwano -- 3 MMX-Chain Compounds -- 3.1 Crystal Structures and Properties of MMX-Chain Compounds Based on Dithiocarboxylato-Bridged Dinuclear Complexes M. Mitsumi -- 3.2 POP-Type MMX-Chain Compounds with Binary Counter-Cations and Vapochromism H. Iguchi, S. Takaishi and M. Yamashita -- 3.3 Photoinduced Phase Transitions in MMX-Chain Compounds H. Matsuzaki and H. Okamoto -- 3.4 Theory of MMX-Chain Compounds K. Yonemitsu. 330 $aThis is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically. 606 $aOrganometallic chemistry  606 $aOptical materials 606 $aElectronic materials 606 $aMedicinal chemistry 606 $aInorganic chemistry 606 $aOrganometallic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19020 606 $aOptical and Electronic Materials$3https://scigraph.springernature.com/ontologies/product-market-codes/Z12000 606 $aMedicinal Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C28000 606 $aInorganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C16008 615 0$aOrganometallic chemistry . 615 0$aOptical materials. 615 0$aElectronic materials. 615 0$aMedicinal chemistry. 615 0$aInorganic chemistry. 615 14$aOrganometallic Chemistry. 615 24$aOptical and Electronic Materials. 615 24$aMedicinal Chemistry. 615 24$aInorganic Chemistry. 676 $a541/.36 676 $a620.11299 702 $aYamashita$b Masahiro$4edt$4http://id.loc.gov/vocabulary/relators/edt 702 $aOkamoto$b Hiroshi$4edt$4http://id.loc.gov/vocabulary/relators/edt 906 $aBOOK 912 $a9910437813103321 996 $aMaterial Designs and New Physical Properties in MX- and MMX-Chain Compounds$92510933 997 $aUNINA