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010   $a1-283-93564-3
010   $a3-7091-1317-2
024 7 $a10.1007/978-3-7091-1317-2
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035   $a(EBL)1030790
035   $a(OCoLC)827616964
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035   $a(PQKBTitleCode)TC0000879268
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035   $a(DE-He213)978-3-7091-1317-2
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035   $a(PPN)168331454
035   $a(EXLCZ)992670000000317279
100   $a20130108d2013      uy         0
101 0 $aeng
135   $aur|n|---|||||
181   $ctxt
182   $cc
183   $acr
200 00$aMaterial designs and new physical properties in MX- and MMX-chain compounds /$fMasahiro Yamashita, Hiroshi Okamoto, editors
205   $a1st ed. 2013.
210   $aWien ;$aNew York $cSpringer$dc2013
215   $a1 online resource (274 p.)
300   $aDescription based upon print version of record.
311   $a3-7091-1735-6 
311   $a3-7091-1316-4 
320   $aIncludes bibliographical references and index.
327   $apt. 1. MX-chain compounds -- pt. 2. MMX-chain compounds.
330   $aThis is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.
606   $aMaterials$xDesign
615  0$aMaterials$xDesign.
676   $a541/.36
676   $a620.11299
701   $aYamashita$b Masahiro$01758197
701   $aOkamoto$b Hiroshi$0666163
801  0$bMiAaPQ
801  1$bMiAaPQ
801  2$bMiAaPQ
906   $aBOOK
912   $a9910437813103321
996   $aMaterial designs and new physical properties in MX- and MMX-chain compounds$94196356
997   $aUNINA