LEADER 04363oam 2200481 450 001 9910437781203321 005 20190911103511.0 010 $a1-4471-5307-3 024 7 $a10.1007/978-1-4471-5307-8 035 $a(OCoLC)858913167 035 $a(MiFhGG)GVRL6XON 035 $a(EXLCZ)993710000000019009 100 $a20130716d2013 uy 0 101 0 $aeng 135 $aurun|---uuuua 181 $ctxt 182 $cc 183 $acr 200 00$aCleaner combustion $edeveloping detailed chemical kinetic models /$fFrederique Battin-Leclerc, John M. Simmie, Edward Blurock, editors 205 $a1st ed. 2013. 210 1$aLondon :$cSpringer,$d2013. 215 $a1 online resource (xiii, 658 pages) $cillustrations (some color) 225 1 $aGreen Energy and Technology,$x1865-3529 300 $a"ISSN: 1865-3529." 311 $a1-4471-5306-5 320 $aIncludes bibliographical references and index. 327 $a1.Introduction,- PART I -- 2.Modeling combustion with detailed kinetic mechanisms -- 3.Automatic generation of detailed mechanisms -- 4.Specificities related to detailed kinetic models for the combustion of oxygenated fuel components -- 5.Multistep kinetic model of biomass pyrolysis -- PART II -- 6.Speciation in shock tubes -- 7.Rapid compression machines -- 8.Jet-stirred reactors -- 9.Tubular flow reactors -- 10.Flame studies of oxygenated hydrocarbons -- PART III -- 11.Formation and characterization of polyaromatic hydrocarbons -- 12.Laser diagnostics for selective and quantitative measurement of PAHs and soot -- 13.Characterization of soot -- 14.An Advanced Multi-Sectional Method for Particulate Matter Modeling in Flames -- 15.Modelling soot formation: model of particle formation -- PART IV -- 16.Investigation and improvement of reaction mechanisms using sensitivity analysis and optimization -- 17.Mechanism reduction to skeletal form and species lumping -- 18.Time Scale Splitting Based Mechanism Reduction -- 19.Storage of chemical kinetic information -- PART V -- 20.Calculation of molecular thermochemical data and their availability in databases -- 21.Statistical rate theory in combustion: An operational approach -- 22.Primary products and branching ratios for combustion multi-channel bimolecular reactions from crossed molecular beam studies -- 23.Kinetic studies of elementary chemical steps with relevance in combustion and environmental chemistry -- 24.Shock-tube studies of combustion-relevant elementary chemical steps and sub-Mechanisms. 330 $aThis overview compiles the on-going research in Europe to enlarge and deepen the understanding of the reaction mechanisms and pathways associated with the combustion of an increased range of fuels. Focus is given to the formation of a large number of hazardous minor pollutants and the inability of current combustion models to predict the  formation of minor products such as alkenes, dienes, aromatics, aldehydes and soot nano-particles which have a deleterious impact on both the environment and on human health. Cleaner Combustion describes, at a fundamental level, the reactive chemistry of minor pollutants within extensively validated detailed mechanisms for traditional fuels, but also innovative surrogates, describing the complex chemistry of new environmentally important bio-fuels. Divided into five sections, a broad yet detailed coverage of related research is provided. Beginning with the development of detailed kinetic mechanisms, chapters go on to explore techniques to obtain reliable experimental data, soot and polycyclic aromatic hydrocarbons,  mechanism reduction and uncertainty analysis, and elementary reactions.   This comprehensive coverage of current research provides a solid foundation for researchers, managers, policy makers and industry operators working in or developing this innovative and globally relevant field. 410 0$aGreen energy and technology. 606 $aFossil fuels$xCombustion 606 $aChemical kinetics 615 0$aFossil fuels$xCombustion. 615 0$aChemical kinetics. 676 $a621.042 702 $aBattin-Leclerc$b Frederique 702 $aSimmie$b John 702 $aBlurock$b Edward 801 0$bMiFhGG 801 1$bMiFhGG 906 $aBOOK 912 $a9910437781203321 996 $aCleaner Combustion$92188080 997 $aUNINA