LEADER 01161nam a2200313 i 4500 001 991002462489707536 008 070523s2006 enka f b 001 0 eng d 020 $a0521853370 024 3 $a9780521853378 035 $ab13530847-39ule_inst 040 $aDip.to Matematica$beng 082 0 $a512.4$222 084 $aAMS 16E60 084 $aLC QA247.C636 100 1 $aCohn, P. M.$045807 245 10$aFree ideal rings and localization in general rings /$cP. M. Cohn 260 $aCambridge, UK ;$aNew York :$bCambridge University Press,$c2006 300 $axxii, 572 p. :$bill. ;$c24 cm 440 0$aNew mathematical monographs ;$v3 504 $aIncludes bibliographical references (p. 540-565) and indexes 650 0$aRings (Algebra) 650 0$aIdeals (Algebra) 650 0$aAssociative algebras 907 $a.b13530847$b28-01-14$c23-05-07 912 $a991002462489707536 945 $aLE013 16E COH11 (2006)$g1$i2013000205816$lle013$op$pE110.84$q-$rl$s- $t0$u2$v0$w2$x0$y.i14501703$z03-07-07 996 $aFree ideal rings and localization in general rings$9846585 997 $aUNISALENTO 998 $ale013$b23-05-07$cm$da $e-$feng$genk$h0$i0 LEADER 03021oam 2200481 450 001 9910418316603321 005 20230621140211.0 010 $a9783832550714 024 8 $ahttps://doi.org/10.30819/5071 035 $a(CKB)4100000011479717 035 $a(oapen)https://directory.doabooks.org/handle/20.500.12854/64438 035 $a(OCoLC)1202548664 035 $a(ScCtBLL)9b39cb67-152c-4f37-b6af-d2bee244f94b 035 $a(EXLCZ)994100000011479717 100 $a20210223h20202020 fy 0 101 0 $aeng 135 $aur||#|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aHeterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis /$fDaniel Knoll 210 $aBerlin/Germany$cLogos Verlag Berlin$d2020 210 1$aBerlin, Germany :$cLogos Verlag Berlin GmbH,$d[2020] 210 4$d©2020 215 $a1 online resource (xiii, 212 pages) $cillustrations; digital file(s) 225 1 $aBeiträge zur organischen Synthese$v85 300 $aAuthor's doctoral thesis, Karlsruher Institut für Technologie (KIT) -- title-page recto. 311 08$aPrint version: 3832550712 320 $aIncludes bibliographical references. 330 $aThe most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes. In this work, [2.2]paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability. To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. 606 $aHeterobimetallic complexes 610 $aParacyclophane 610 $aCatalysis 610 $aHeterobimetallic Complexes 610 $aPhotocatalysis 610 $aCooperative Effects 615 0$aHeterobimetallic complexes. 700 $aKnoll$b Daniel$0893374 712 02$aKarlsruher Institut für Technologie, 801 0$bUkMaJRU 912 $a9910418316603321 996 $aHeterobimetallic paracyclophane complexes and their application in photoredox catalysis$91995663 997 $aUNINA