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010   $a3-030-00997-1
024 7 $a10.1007/978-3-030-00997-7
035   $a(CKB)4100000007110539
035   $a(MiAaPQ)EBC5583556
035   $a(DE-He213)978-3-030-00997-7
035   $a(PPN)232468834
035   $a(EXLCZ)994100000007110539
100   $a20181102d2018      u|         0
101 0 $aeng
135   $aurcnu||||||||
181   $ctxt$2rdacontent
182   $cc$2rdamedia
183   $acr$2rdacarrier
200 10$aAlkyne?Based Nanostructures on Silver Substrates      /$fby Raphael Hellwig
205   $a1st ed. 2018.
210  1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2018.
215   $a1 online resource (132 pages)
225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
311   $a3-030-00996-3 
327   $aIntroduction -- Experimental Methods -- Silver-bis-acetylide Wires -- Fabrication of Graphdiyne Nanowires -- Metal Alkynyl 22/7 Complexes -- Ho-Catalyzed Cyclotrimerization -- Conclusion and Outlook.
330   $aAcetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the author establishes protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions.
410  0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
606   $aNanoscale science
606   $aNanoscience
606   $aNanostructures
606   $aOrganometallic chemistry 
606   $aMaterials?Surfaces
606   $aThin films
606   $aNanoscale Science and Technology$3https://scigraph.springernature.com/ontologies/product-market-codes/P25140
606   $aOrganometallic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19020
606   $aSurfaces and Interfaces, Thin Films$3https://scigraph.springernature.com/ontologies/product-market-codes/Z19000
615  0$aNanoscale science.
615  0$aNanoscience.
615  0$aNanostructures.
615  0$aOrganometallic chemistry .
615  0$aMaterials?Surfaces.
615  0$aThin films.
615 14$aNanoscale Science and Technology.
615 24$aOrganometallic Chemistry.
615 24$aSurfaces and Interfaces, Thin Films.
676   $a620.115
700   $aHellwig$b Raphael$4aut$4http://id.loc.gov/vocabulary/relators/aut$0833850
906   $aBOOK
912   $a9910392720803321
996   $aAlkyne?Based Nanostructures on Silver Substrates$91864301
997   $aUNINA