LEADER 03775nam 22006375 450 001 9910373933903321 005 20200706054341.0 010 $a3-030-26822-5 024 7 $a10.1007/978-3-030-26822-0 035 $a(CKB)4100000009844883 035 $a(DE-He213)978-3-030-26822-0 035 $a(MiAaPQ)EBC5977076 035 $a(PPN)258876271 035 $a(EXLCZ)994100000009844883 100 $a20191111d2019 u| 0 101 0 $aeng 135 $aurnn#008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aFundamentals of Spin Exchange $eStory of a Paradigm Shift /$fby Kev M. Salikhov 205 $a1st ed. 2019. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2019. 215 $a1 online resource (XIII, 265 p. 47 illus.) 311 $a3-030-26821-7 327 $aIntroduction -- Theory of spin exchange in dilute solutions -- Paramagnetic relaxation caused by spin-spin dipole-dipole interaction of paramagnetic particles in a liquid -- Modified Bloch equations for dilute solutions of free radicals taking into account exchange and dipole-dipole interactions -- Manifestation of exchange and dipole-dipole interaction in the form of EPR spectra of paramagnetic particles in solutions in linear response case -- Experimental determination of the spin exchange rate from the analysis of the EPR spectrum shape -- Other methods of measuring the spin exchange rate constants -- In Conclusion. 330 $aThis book is a comprehensive summary of 50 years of research from theoretical predictions to experimental confirmation of the manifestation of spin exchange in EPR spectroscopy. The author unfolds the details of comprehensive state of the art of theoretical calculations, which have been proven to become the core of the paradigm shift in spin exchange and set the direction for the future of spin exchange research. The book refers to important experimental data that confirms the theory. It describes the modern protocol for determining the bi-molecular spin exchange rate from the EPR spectra, which will be especially interesting for experimentalists. Given its scope, the book will benefit all researchers engaged in theory and experiments in the area of spin exchange and its manifestations in EPR spectroscopy, where many remarkable applications of the spin probe have been developed. . 606 $aSpectrum analysis 606 $aMicroscopy 606 $aChemistry, Physical and theoretical 606 $aCondensed matter 606 $aBiophysics 606 $aBiophysics 606 $aSpectroscopy and Microscopy$3https://scigraph.springernature.com/ontologies/product-market-codes/P31090 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aCondensed Matter Physics$3https://scigraph.springernature.com/ontologies/product-market-codes/P25005 606 $aBiological and Medical Physics, Biophysics$3https://scigraph.springernature.com/ontologies/product-market-codes/P27008 615 0$aSpectrum analysis. 615 0$aMicroscopy. 615 0$aChemistry, Physical and theoretical. 615 0$aCondensed matter. 615 0$aBiophysics. 615 0$aBiophysics. 615 14$aSpectroscopy and Microscopy. 615 24$aPhysical Chemistry. 615 24$aCondensed Matter Physics. 615 24$aBiological and Medical Physics, Biophysics. 676 $a621.36 700 $aSalikhov$b Kev M$4aut$4http://id.loc.gov/vocabulary/relators/aut$0837240 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910373933903321 996 $aFundamentals of Spin Exchange$92527168 997 $aUNINA