LEADER 04324nam 22006975 450 001 9910373931703321 005 20200704142925.0 010 $a3-030-33574-7 024 7 $a10.1007/978-3-030-33574-8 035 $a(CKB)4100000009939761 035 $a(MiAaPQ)EBC5986788 035 $a(DE-He213)978-3-030-33574-8 035 $a(PPN)258304790 035 $a(EXLCZ)994100000009939761 100 $a20191126d2019 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aTheory of Thermodynamic Measurements of Quantum Systems Far from Equilibrium /$fby Abhay Shastry 205 $a1st ed. 2019. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2019. 215 $a1 online resource (152 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 311 $a3-030-33573-9 320 $aIncludes bibliographical references. 327 $aChapter1. Introduction -- Chapter2. Temperature and Voltage -- Chapter3. Coldest Measurable Temperature -- Chapter4. STM as a Thermometer -- Chapter5. Entropy -- Chapter6. Concluding Remarks. 330 $aThis thesis presents several related advances in the field of nonequilibrium quantum thermodynamics. The central result is an ingenious proof that the local temperature and voltage measurement in a nonequilibrium system of fermions exists and is unique, placing the concept of local temperature on a rigorous mathematical footing for the first time. As an intermediate step, a proof of the positivity of the Onsager matrix of linear response theory is given -- a statement of the second law of thermodynamics that had lacked an independent proof for 85 years. A new experimental method to measure the local temperature of an electron system using purely electrical techniques is also proposed, which could enable improvements to the spatial resolution of thermometry by several orders of magnitude. Finally, a new mathematically-exact definition for the local entropy of a quantum system in a nonequilibrium steady state is derived. Several different measures of the local entropy are discussed, relating to the thermodynamics of processes that a local observer with varying degrees of information about the microstates of the system could carry out, and it is shown that they satisfy a hierarchy of inequalities. Proofs of the third law of thermodynamics for generic open quantum systems are presented, taking into account the entropic contribution due to localized states. Appropriately normalized (per-state) local entropies are defined and are used to quantify the departure from local equilibrium. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aQuantum theory 606 $aThermodynamics 606 $aChemistry, Physical and theoretical 606 $aMathematical physics 606 $aSpectrum analysis 606 $aMicroscopy 606 $aQuantum Physics$3https://scigraph.springernature.com/ontologies/product-market-codes/P19080 606 $aThermodynamics$3https://scigraph.springernature.com/ontologies/product-market-codes/P21050 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aMathematical Physics$3https://scigraph.springernature.com/ontologies/product-market-codes/M35000 606 $aSpectroscopy and Microscopy$3https://scigraph.springernature.com/ontologies/product-market-codes/P31090 615 0$aQuantum theory. 615 0$aThermodynamics. 615 0$aChemistry, Physical and theoretical. 615 0$aMathematical physics. 615 0$aSpectrum analysis. 615 0$aMicroscopy. 615 14$aQuantum Physics. 615 24$aThermodynamics. 615 24$aPhysical Chemistry. 615 24$aMathematical Physics. 615 24$aSpectroscopy and Microscopy. 676 $a530.12011 700 $aShastry$b Abhay$4aut$4http://id.loc.gov/vocabulary/relators/aut$0838600 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910373931703321 996 $aTheory of Thermodynamic Measurements of Quantum Systems Far from Equilibrium$91873098 997 $aUNINA