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010   $a981-13-6049-9
024 7 $a10.1007/978-981-13-6049-7
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035   $a(MiAaPQ)EBC5638854
035   $a(DE-He213)978-981-13-6049-7
035   $a(EXLCZ)994100000007522482
100   $a20190117d2019      u|             0
101 0 $aeng
135   $aurcnu||||||||
181   $ctxt$2rdacontent
182   $cc$2rdamedia
183   $acr$2rdacarrier
200 10$aEnergy Transfer Processes in Polynuclear Lanthanide Complexes$b[electronic resource] /$fby Shun Omagari
205   $a1st ed. 2019.
210  1$aSingapore :$cSpringer Singapore :$cImprint: Springer,$d2019.
215   $a1 online resource (153 pages)
225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
311   $a981-13-6048-0 
327   $aGeneral Introduction -- Theory -- Concentration Quenching in Ytterbium Coordination Polymers -- Spin-orbit Coupling and Energy Transfer in Nonanuclear Lanthanide Clusters -- Back Energy Transfer in Terbium Clusters -- Suppression of Back Energy Transfer by Energy Transfer between Terbium Ions -- Summary and Outlook -- Acknowledgements.
330   $aThis book describes the luminescence mechanism of polynuclear lanthanide complexes, focusing on energy transfer processes using a combination of experimental and theoretical approaches. Lanthanide complexes show intense luminescence from the lanthanide ion through sensitization by the organic ligands. The high chromaticity of the emission and the long lifetimes of the complexes are particularly attractive for applications such as organic light-emitting diodes and bioprobes. Polynuclear lanthanide complexes (coordination polymers and clusters) have attracted considerable interest for functionalization by energy transfer between lanthanide ions. At the same time, such extra processes complicate the luminescence mechanism, hindering the rational design of functional polynuclear lanthanide complexes. Firstly, the book explains the principle of the theoretical methods, and then describes the concentration-quenching mechanism in coordination polymers. It also examines the effect of intrinsic spin?orbit coupling arising from lanthanide ions on the ligand-to-lanthanide energy transfer efficiency and the mechanism of back energy transfer (the opposite of sensitizing energy transfer) in lanthanide clusters. This sets the stage for the final topic: the suppression of back energy transfer by energy transfer between lanthanide ions in lanthanide clusters, which is of critical importance, showing that the lanthanide clusters can be considered a new generation of functional and efficient luminescent material and could also provide a breakthrough in lanthanide photophysics.
410  0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
606   $aChemistry, Organic
606   $aChemistry
606   $aChemistry, inorganic
606   $aPolymers
606   $aChemistry, Physical organic
606   $aOrganometallic Chemistry$3http://scigraph.springernature.com/things/product-market-codes/C19020
606   $aTheoretical and Computational Chemistry$3http://scigraph.springernature.com/things/product-market-codes/C25007
606   $aInorganic Chemistry$3http://scigraph.springernature.com/things/product-market-codes/C16008
606   $aPolymer Sciences$3http://scigraph.springernature.com/things/product-market-codes/C22008
606   $aPhysical Chemistry$3http://scigraph.springernature.com/things/product-market-codes/C21001
615  0$aChemistry, Organic.
615  0$aChemistry.
615  0$aChemistry, inorganic.
615  0$aPolymers.
615  0$aChemistry, Physical organic.
615 14$aOrganometallic Chemistry.
615 24$aTheoretical and Computational Chemistry.
615 24$aInorganic Chemistry.
615 24$aPolymer Sciences.
615 24$aPhysical Chemistry.
676   $a546.41
700   $aOmagari$b Shun$4aut$4http://id.loc.gov/vocabulary/relators/aut$0769880
906   $aBOOK
912   $a9910350339503321
996   $aEnergy Transfer Processes in Polynuclear Lanthanide Complexes$91570046
997   $aUNINA