LEADER 03876nam 22006495 450 001 9910349507003321 005 20200630165025.0 010 $a3-030-31087-6 024 7 $a10.1007/978-3-030-31087-5 035 $a(CKB)4100000009382516 035 $a(DE-He213)978-3-030-31087-5 035 $a(MiAaPQ)EBC5909873 035 $a(PPN)248601032 035 $a(EXLCZ)994100000009382516 100 $a20190927d2019 u| 0 101 0 $aeng 135 $aurnn|008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aAngle Resolved Photoemission Spectroscopy of Delafossite Metals$b[electronic resource] /$fby Veronika Sunko 205 $a1st ed. 2019. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2019. 215 $a1 online resource (XVII, 198 p. 122 illus., 104 illus. in color.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 300 $aDoctoral thesis accepted by the Max Planck Institute for chemical physics of solids, Dresden, Germany. 311 $a3-030-31086-8 327 $aIntroduction -- Angle Resolved Photoemission -- Theory and Models -- Bulk States in PtCoO2 and PdCoO2 -- Coupling of Metallic and Mott-insulating states in PdCrO2 -- Rashba-like Spin-Split Surface States -- Conclusions and Outlook -- Appendices. 330 $aThis thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aSolid state physics 606 $aSpectroscopy 606 $aMicroscopy 606 $aMaterials?Surfaces 606 $aThin films 606 $aSolid State Physics$3https://scigraph.springernature.com/ontologies/product-market-codes/P25013 606 $aSpectroscopy and Microscopy$3https://scigraph.springernature.com/ontologies/product-market-codes/P31090 606 $aSurfaces and Interfaces, Thin Films$3https://scigraph.springernature.com/ontologies/product-market-codes/Z19000 606 $aSpectroscopy/Spectrometry$3https://scigraph.springernature.com/ontologies/product-market-codes/C11020 615 0$aSolid state physics. 615 0$aSpectroscopy. 615 0$aMicroscopy. 615 0$aMaterials?Surfaces. 615 0$aThin films. 615 14$aSolid State Physics. 615 24$aSpectroscopy and Microscopy. 615 24$aSurfaces and Interfaces, Thin Films. 615 24$aSpectroscopy/Spectrometry. 676 $a530.41 700 $aSunko$b Veronika$4aut$4http://id.loc.gov/vocabulary/relators/aut$01064762 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910349507003321 996 $aAngle Resolved Photoemission Spectroscopy of Delafossite Metals$92540570 997 $aUNINA