LEADER 03697nam 22006855 450 001 9910349473603321 005 20200706093527.0 010 $a9789811316630 010 $a981-13-1663-5 024 7 $a10.1007/978-981-13-1663-0 035 $a(CKB)4100000009757204 035 $a(MiAaPQ)EBC5455705 035 $a(DE-He213)978-981-13-1663-0 035 $a(PPN)229503632 035 $a(EXLCZ)994100000009757204 100 $a20180716d2018 u| 0 101 0 $aeng 135 $aurnn|008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aHigh Resolution Imaging, Spectroscopy and Nuclear Quantum Effects of Interfacial Water /$fby Jing Guo 205 $a1st ed. 2018. 210 1$aSingapore :$cSpringer Singapore :$cImprint: Springer,$d2018. 215 $a1 online resource (XVIII, 115 p. 49 illus., 48 illus. in color.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 311 $a981-13-1662-7 327 $aIntroduction -- Submolecular resolution imaging of interfacial water -- Vibrational spectroscopy of interfacial water -- Nuclear quantum effects of interfacial water -- Summary and outlook. 330 $aThis thesis presents a series of experimental techniques based on scanning probe microscopy, which make it possible access the degree of freedom of protons both in real and energy space. These novel techniques and methods allow direct visualization of the concerted quantum tunneling of protons within the hydrogen-bonded network and quantification of the quantum component of a single hydrogen bond at a water?solid interface for the first time. Furthermore, the thesis demonstrates that the anharmonic quantum fluctuations of hydrogen nuclei further weaken the weak hydrogen bonds and strengthen the strong ones. However, this trend was reversed when the hydrogen bond coupled to the local environment. These pioneering findings substantially advance our understanding of the quantum nature of H bonds at the molecular level. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aSpectrum analysis 606 $aMicroscopy 606 $aAtomic structure 606 $aMolecular structure 606 $aSurfaces (Physics) 606 $aInterfaces (Physical sciences) 606 $aThin films 606 $aChemistry, Physical and theoretical 606 $aSpectroscopy and Microscopy$3https://scigraph.springernature.com/ontologies/product-market-codes/P31090 606 $aAtomic/Molecular Structure and Spectra$3https://scigraph.springernature.com/ontologies/product-market-codes/P24017 606 $aSurface and Interface Science, Thin Films$3https://scigraph.springernature.com/ontologies/product-market-codes/P25160 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 615 0$aSpectrum analysis. 615 0$aMicroscopy. 615 0$aAtomic structure. 615 0$aMolecular structure. 615 0$aSurfaces (Physics) 615 0$aInterfaces (Physical sciences) 615 0$aThin films. 615 0$aChemistry, Physical and theoretical. 615 14$aSpectroscopy and Microscopy. 615 24$aAtomic/Molecular Structure and Spectra. 615 24$aSurface and Interface Science, Thin Films. 615 24$aPhysical Chemistry. 676 $a621.36 700 $aGuo$b Jing$4aut$4http://id.loc.gov/vocabulary/relators/aut$0325589 906 $aBOOK 912 $a9910349473603321 996 $aHigh Resolution Imaging, Spectroscopy and Nuclear Quantum Effects of Interfacial Water$91867861 997 $aUNINA